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81.
Masood Parvez Jehan Ara Viqar Sultana Rashida Qasim Viqar Uddin Ahmad 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(3):e96-e97
The crystal structure of caulerpin (dimethyl 6,13‐dihydrodibenzo[b,i]phenazine‐5,12‐dicarboxylate, C24H18N2O4), an indole alkaloid, reported in space group Cc with an acute β angle, has been redetermined in the correct space group, C2/c. The molecule has twofold crystallographic symmetry and is composed of two essentially planar indole groups fused to an eight‐membered cyclooctatetraene ring which adopts a boat conformation. The molecular dimensions are normal. The structure is stabilized by intermolecular and intramolecular interactions involving the indole N—H atom and carbonyl O atom [N?O 3.211 (4) and 2.836 (4) Å]. 相似文献
82.
We classify all Noether point symmetries of the Lane-Emden-type equation x y ″ + n y ′ + xνf (y) = 0 with respect to the standard Lagrangian L = 1/2 xny ′2 – xn +ν –1 ∫ f (y)dy for various functions f (y). We then obtain first integrals of the various cases which admit Noether point symmetries and obtain reduction to quadratures for these cases. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
83.
Masood Parvez Govindaraji Senthil Veejendra K. Yadav 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(5):577-579
The stereoisomers of 7‐phenyl‐1‐oxa‐4‐thiaspiro[4.5]decan‐7‐ol, C14H18O2S, have the same stereochemistry at the C atom bearing an OH group, i.e. axial OH and equatorial phenyl groups. However, the acetal S and O atoms are axial and equatorial, respectively, in one isomer and reversed in the second. Furthermore, the crystals of one isomer are composed of hydrogen‐bonded molecules involving the hydroxyl H atom and the O atom of the five‐membered heterocyclic ring, with an O?O distance of 2.962 (3) Å, forming a polymeric chain along the b axis. The asymmetric unit of the other isomer is composed of two molecules, wherein hydroxyl H atoms and the O atoms of the five‐membered heterocyclic rings display intramolecular O—H?O hydrogen bonds with O?O separations of 2.820 (2) and 2.834 (2) Å. 相似文献
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88.
Two diastereomeric alcohols are formed from the reaction of 1-oxa-4-thiaspiro[4.5]decan-7-one with PhLi as against the single diastereomer reported earlier. The diastereoselectivity achieved from PhMgBr is significantly higher than with PhLi. The use of Et(2)O/hexane = 2:1 as the solvent for the reaction with PhMgBr offered the highest (14:1) diastereocontrol. 相似文献
89.
Copper(II) complexes were prepared with the new N(2)S(thioether) ligand 2-methylthio-N-(2-pyridylmethyl)acetamide (2-HL(N2S)). [Cu(2-L(N2S))Cl(MeOH)], which formed in the presence of excess triethylamine, is a distorted square pyramidal complex containing the ligand with the amide nitrogen deprotonated. The structurally analogous complex, [Cu(2-HL(N2S))Cl(2)], which formed in the absence of triethylamine, contains 2-HL(N2S) in the tautomeric imidic acid form. Neutral copper(II) N(2)S(thioether)S(thiolate) species were generated by addition of alkyl or aromatic thiolates to [Cu(2-L(N2S))Cl(MeOH)] and an unusual decomposition pathway was discovered. 相似文献
90.
The preparation and isolation in the solid state of five aryl 1,2,3,5-dithia- and diselenadiazolyls is reported. The structure of the dimer of 4-Cl? C6H4? CN2S2 in the solid state was obtained: monoclinic, C2/c with Z = 8, a = 20.982(10), b = 10.058(3), c = 15.867(6) Å, β = 93.34(4)°, R = 0.066, Rw = 0.053 for 1 099 data. Cyclic voltammetry shows reversible oxidation to a 6π cation for all 10 compounds in both CH2Cl2 and CH3CN; reversible reduction to an 8π anion is observed in CH2Cl2 for all except X = CF3, E = S. The reductions are only quasi-reversible in CH3CN for E = Se. The oxidation process is independent of chalcogen type; the reduction process is found to be about 0.2 V more negative for E = S vs E = Se. 相似文献