全文获取类型
收费全文 | 868篇 |
免费 | 25篇 |
国内免费 | 3篇 |
专业分类
化学 | 699篇 |
晶体学 | 14篇 |
力学 | 19篇 |
数学 | 46篇 |
物理学 | 118篇 |
出版年
2023年 | 5篇 |
2021年 | 5篇 |
2020年 | 7篇 |
2019年 | 13篇 |
2018年 | 9篇 |
2017年 | 9篇 |
2016年 | 14篇 |
2015年 | 16篇 |
2014年 | 14篇 |
2013年 | 42篇 |
2012年 | 36篇 |
2011年 | 42篇 |
2010年 | 23篇 |
2009年 | 30篇 |
2008年 | 48篇 |
2007年 | 60篇 |
2006年 | 61篇 |
2005年 | 49篇 |
2004年 | 51篇 |
2003年 | 50篇 |
2002年 | 36篇 |
2001年 | 13篇 |
2000年 | 16篇 |
1999年 | 9篇 |
1998年 | 15篇 |
1997年 | 11篇 |
1996年 | 11篇 |
1995年 | 8篇 |
1994年 | 6篇 |
1993年 | 7篇 |
1992年 | 5篇 |
1991年 | 5篇 |
1990年 | 8篇 |
1989年 | 9篇 |
1988年 | 10篇 |
1986年 | 5篇 |
1985年 | 16篇 |
1984年 | 17篇 |
1982年 | 12篇 |
1981年 | 13篇 |
1980年 | 5篇 |
1979年 | 7篇 |
1978年 | 11篇 |
1977年 | 14篇 |
1976年 | 9篇 |
1975年 | 4篇 |
1974年 | 5篇 |
1973年 | 3篇 |
1972年 | 3篇 |
1967年 | 3篇 |
排序方式: 共有896条查询结果,搜索用时 31 毫秒
81.
82.
Masaru Ogura 《Catalysis Surveys from Asia》2008,12(1):16-27
A composite silicate material, which possesses the characteristics of both microporous zeolite and mesoporous silica materials,
is developed by top–down and bottom–up synthesis techniques. In order to realize a micro- and mesoporous composite material,
several essential points must be clarified, since each porous material is synthesized under very different metastable conditions:
zeolite is a silicate crystal, while the wall of mesoporous material is composed of amorphous silicate. Here, some aspects
of the realization of a micro- and mesocomposite porous material are described, as are our experimental results regarding
the successful production of composite catalyst. 相似文献
83.
We discuss the universal version of the Schwinger terms of current algebra (we call it the universal Schwinger cocycle) forp=3 (herep denotes the class of the Schatten idealI
p
, which is related to the (D+1) space-time dimensions byp=(D+1)/2) in detail, and give a conjecture of the general form of the cocycle for anyp. We also discuss the infinite charge renormalizations, the highest weight vector and state vectors forp=3. Last, we give brief comments on the problems caused by the difficulties to construct the measure of infinite-dimensional Grassmann manifolds. 相似文献
84.
Koshi Imami Naoyuki Sugiyama Yutaka Kyono Masaru Tomita Yasushi Ishihama 《Analytical sciences》2008,24(1):161-166
We have developed an on-line automated system for phosphoproteome analysis using titania-based phosphopeptide enrichment followed by nanoLC-MS/MS. Titania beads were prepared by calcination of commercial chromatographic titania beads at 800 degrees C to convert the crystalline structure. The obtained rutile-form titania exhibited higher selectivity in phosphopeptide enrichment than commercial titania, even in the absence of a competitive chelating reagent for non-phosphopeptides. For phosphoproteome analysis of human cervical cancer HeLa cells, tryptic digests of the cell extracts were directly injected into this on-line system, and 696 non-redundant phosphopeptides with 671 unambiguously determined phosphorylation sites, derived from 512 phosphoproteins, were successfully identified. This is the first successful application of an on-line automated phosphoproteome analysis system to complex biological samples. 相似文献
85.
Ru Chen Yuezhen Bin Yumiko Nakano Naoko Kurata Masaru Matsuo 《Colloid and polymer science》2010,288(3):307-316
In an attempt to improve the mechanical property of polyethylene composite at high temperature, crosslinking of ultrahigh-molecular-weight
polyethylene (UHMWPE) and carbon fiber (CF) blends was carried out by using dicumyl peroxide (DCP). The specimens were prepared
by gelation/crystallization from solutions. The effect of chemical crosslinking on mechanical and electrical properties of
UHMWPE/CF blends with composition of 1/0, 1/0.25, and 1/1 (w/w) were investigated in detail. Electrical conductivity and thermal mechanical properties of the blends with the 1/1 composition
were greatly improved by incorporation of enough content of CF and adequate crosslinking network formation. Surprisingly,
the Young’s modulus of the 1/1 blend reached 20 GPa at room temperature (20 °C). On the other hand, heat treatment at 135 °C
played an important role for obtaining a high PTC effect for the UHMWPE-CF blend in which the PTC intensity reached 107. 相似文献
86.
Tanaka H Sudo M Hirata M Etoh H Sato M Yamaguchi R Sakai E Chen IS Fukai T 《Natural product communications》2010,5(11):1781-1784
A new biisoflavonoid, biseryvarin A (1a), together with two known compounds were isolated from the roots of Erythrina variegata. The structure of biseryvarin A was established on the basis of spectroscopic evidence. Biseryvarin A is the first dimeric isoflavonoid possessing isoprenoid groups from the genus Erythrina. Biseryvarin A showed low activity against methicillin-resistant Staphylococcus aureus (MRSA). 相似文献
87.
88.
Numerical simulations for the merger of binary neutron stars are performed in full general relativity incorporating both nucleonic and hyperonic finite-temperature equations of state (EOS) and neutrino cooling. It is found that even for the hyperonic EOS, a hypermassive neutron star is first formed after the merger for the typical total mass ≈2.7M(⊙), and subsequently collapses to a black hole (BH). It is shown that hyperons play a substantial role in the postmerger dynamics, torus formation around the BH, and emission of gravitational waves (GWs). In particular, the existence of hyperons is imprinted in GWs. Therefore, GW observations will provide a potential opportunity to explore the composition of neutron star matter. 相似文献
89.
We present an efficient self-consistent method for approaching quantum transport through atomic-scale structures. Using the recursion-transfer-matrix (RTM) method with a separable form of nonlocal pseudopotentials, scattering waves propagating between metallic electrodes through nano-bridged structures are efficiently calculated on the basis of the density-functional formalism. We performed calculations with this method of the conductance of Al atomic wires with various kinds of single atoms mixed at the contact to one electrode. We found that the transport properties are considerably affected by the bonding nature of the atom at the contact. The conductance is largely determined by the atomic species at the contact and does not change much as the length of the atomic wire increases. 相似文献
90.
Jun Zhe Min Toshimasa Toyooka Hiroki Kawanishi Takeshi Fukushima Masaru Kato 《Analytica chimica acta》2005,550(1-2):173-181
Several fluorescent asparaginyl-N-acetyl-d-glucosamines (Asn-GlcNAcs), i.e., DBD-Asn-GlcNAc, NBD-Asn-GlcNAc, NDA-Asn-GlcNAc, PS-Asn-GlcNAc, FITC-Asn-GlcNAc, DMEQ-Asn-GlcNAc and DBD-PZ-Boc-Asn-GlcNAc, were synthesized as the acceptors for the resolution of oligosaccharides in glycopeptides. The resolution of oligosaccharides is based on the transglycosylation reaction with end-β-N-acetylglucosaminidase (Endo-M), isolated from Mucor hiemalis. The synthesis of each fluorescent acceptor was carried out in a one-pot reaction of Asn-GlcNAc and the corresponding fluorescent tagging reagent. The transglycosylation reaction using Endo-M proceeds at RT in neutral phosphate buffer (pH 6.0) and reached maxima at around 30 min. When Fmoc-Asn-GlcNAc (acceptor) was enzymatically reacted with Disialo-Asn (donor) in the presence of Endo-M, the ratio of Disialo-Asn-Fmoc (transglycosylation product) was almost comparable with the decreasing ratio of Fmoc-Asn-GlcNAc. Therefore, the transglycosylation activity of Endo-M from Disialo-Asn (donor) and fluorescent-Asn-GlcNAc (acceptor) was calculated from the decreasing ratio of fluorescent-Asn-GlcNAc. The order was NDA-Asn-GlcNAc > DBD-Asn-GlcNAc Fmoc-Asn-GlcNAc > NBD-Asn-GlcNAc DMEQ-Asn-GlcNAc > DNS-Asn-GlcNAc > PS-Asn-GlcNAc > FITC-Asn-GlcNAc. On the other hand, the activity with a fluorescent acceptor (DBD-PZ-Boc-Asn-GlcNAc), labeled to a carboxylic acid group in the Asn residue, was the strongest among the synthesized acceptors. 相似文献