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71.
The rotational time correlation function (RTCF) of solute benzene molecules in the ionic liquid (1-butyl-3-methylimidazolium chloride) has been studied using classical molecular dynamics simulation. The effect of solvent charge on the functional form of RTCF was investigated by comparing four force fields for the solvent where the total charge on the anion and the cation was set to ±1e, ±0.7e, ±0.5e, and 0, respectively. For all three charged solvent models, the RTCF exhibits a long-time tail where the relaxation rate exhibits a significant slowdown. This feature is strengthened by higher solvent charges as well as lower temperatures, indicating the influence of the strong Coulombic fields arising from the solvent charges. The long-time tail is caused by the extraordinarily slow solvent structural relaxation of ionic liquids compared to the time scale of their local vibrational and librational dynamics. 相似文献
72.
Petronela Drambei Yumiko Nakano Yuezhen Bin Tsumuko Okuno Masaru Matsuo 《Macromolecular Symposia》2006,242(1):146-156
Uniplaner orientation of a particular crystal plane along the surface of a film was investigated for poly (vinyl alcohol) (PVA) film prepared by a coagulation bath with concentrated aqueous solution containing 100 ∼ 300g of Na2SO4 against 1 ℓ of water. The orientation distribution functions of the three crystallographic principal axes of the dried films were obtained by the X-ray diffraction technique. The same treatment was carried out for the films prepared by stretching biaxially of the fresh gel and then by drying the resultant fresh gel. The very high preferential orientation of the crystal chain axes and amorphous chain segments could be realized by the biaxially elongation. Accordingly, the techniques were applied to the biaxially stretching of chitosan and PVA blend films with high Young's modulus. The planer orientation of the chain axes of chitosan and PVA crystallites could be confirmed. The morphology of the film surface was estimated by measurements of contact angle and electron spectroscopy for chemical analysis. The results suggested that the admixture of chitosan decreases wet ability of the specimen and this tendency was slightly enhanced by the biaxially elongation. 相似文献
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Catalytic Enantioselective Reaction of α‐Phenylthioacetonitriles with Imines Using Chiral Bis(imidazoline)–Palladium Catalysts 下载免费PDF全文
Masaru Kondo Natsumi Kobayashi Prof. Dr. Tsubasa Hatanaka Prof. Dr. Yasuhiro Funahashi Prof. Dr. Shuichi Nakamura 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(25):9066-9070
The catalytic enantioselective reaction of α‐phenylthioacetonitriles with imines has been developed. The reaction of various imines proceeds in good yields and diastereo‐ and enantioselectivities in the presence of chiral bis(imidazoline)–palladium catalysts. The obtained products can be converted into β‐aminonitrile or β‐aminoamide compounds without loss of enantiopurity. 相似文献
75.
The potassium-selective PVC membrane electrodes based on naphtho-15-crown-5 have rapid, stable and Nernstian response in the range 10-1–10-5 M. The selectivity coefficient for potassium over sodium is 4 × 10-4. 相似文献
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Vlad Bacauanu Sébastien Cardinal Motoshi Yamauchi Masaru Kondo David F. Fernández Richard Remy Prof. Dr. David W. C. MacMillan 《Angewandte Chemie (International ed. in English)》2018,57(38):12543-12548
Herein, we report a convenient and broadly applicable strategy for the difluoromethylation of aryl bromides by metallaphotoredox catalysis. Bromodifluoromethane, a simple and commercially available alkyl halide, is harnessed as an effective source of difluoromethyl radical by silyl‐radical‐mediated halogen abstraction. The merger of this fluoroalkyl electrophile activation pathway with a dual nickel/photoredox catalytic platform enables the difluoromethylation of a diverse array of aryl and heteroaryl bromides under mild conditions. The utility of this procedure is showcased in the late‐stage functionalization of several drug analogues. 相似文献
78.
Sophisticated catchment runoff problems necessitate conjunctive modeling of overland flow and sub‐surface flow. In this paper, finite difference numerical methods are studied for simulation of catchment runoff of two‐dimensional surface flow interacting with three‐dimensional unsaturated and saturated sub‐surface flows. The equations representing the flows are mathematically classified as a type of heat diffusion equation. Therefore, two‐ and three‐dimensional numerical methods for heat diffusion equations were investigated for applications to the surface and sub‐surface flow sub‐models in terms of accuracy, stability, and calculation time. The methods are the purely explicit method, Saul'yev's methods, the alternating direction explicit (ADE) methods, and the alternating direction implicit (ADI) methods. The methods are first examined on surface and sub‐surface flows separately; subsequently, 12 selected combinations of methods were investigated for modeling the conjunctive flows. Saul'yev's downstream (S‐d) method was found to be the preferred method for two‐dimensional surface flow modeling, whereas the ADE method of Barakat and Clark is a less accurate, stable alternative. For the three‐dimensional sub‐surface flow model, the ADE method of Larkin (ADE‐L) and Brian's ADI method are unconditionally stable and more accurate than the other methods. The calculations of the conjunctive models utilizing the S‐d surface flow sub‐model give excellent results and confirm the expectation that the errors of the surface and sub‐surface sub‐models interact. The surface sub‐model dominates the accuracy and stability of the conjunctive model, whereas the sub‐surface sub‐model dominates the calculation time, suggesting the desirability of using a smaller time increment for the surface sub‐model. Copyright © 2000 John Wiley & Sons, Ltd. 相似文献
79.
Glass bead/x‐ray fluorescence spectrometry of the sludge incineration ashes generated in sewage processing was developed for the determination of ten major components (Na2O, MgO, Al2O3, SiO2, P2O5, K2O, CaO, TiO2, MnO, Fe2O3) and five minor elements (Zn, Cu, Cr, As, Pb). Sewage sludge ashes consisted of rock‐forming minerals and phosphate crystals that had been used for phosphorus removal. Ash samples were melted and molded with lithium tetraborate to 35 mm diameter glass disks in a Pt–Au crucible. Analytical results of ten major components and five minor elements agreed well with the recommended values of a phosphate rock standard reference material (NIST SRM 694). Elemental compositions of sewage sludge ash from seven sewage‐processing plants in Japan were determined using this method. Concentrations of Fe2O3, SiO2, and CaO, along with loss of ignition in sewage sludge ash mutually differed among the sewage‐processing plant products. Seasonal variations in concentrations of ten major components and five minor components of ash samples produced from October 2001 to September 2002 were determined using the proposed method. Concentrations of SiO2increased with the inflow of gravel by rainfall, thereby decreasing concentrations of P2O5 originating from excreta and microorganisms. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
80.