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951.
We report the implementation of projective measurement on a single 1/2 nuclear spin of the (171)Yb atom by measuring the polarization of cavity-enhanced fluorescence. To obtain cavity-enhanced fluorescence having a nuclear-spin-dependent polarization, we construct a two-mode cavity QED system, in which two cyclic transitions are independently coupled to each of the orthogonally polarized cavity modes, by manipulating the energy level of (171)Yb. This system can associate the nuclear spin degrees of freedom with the polarization of photons, which will facilitate the development of hybrid quantum systems. 相似文献
952.
Masayuki Kirihara Katsumi Yoshida Takuya Noguchi Sayuri Naito Nobuchika Matsumoto Yukinori Ema Motoya Torii Yuki Ishizuka Ikuo Souta 《Tetrahedron letters》2010,51(28):3619-3622
The aerobic oxidation of ditertiary glycols catalyzed by oxytrichlorovanadium resulted in carbon-carbon bonds cleavage producing the ketones efficiently. 相似文献
953.
Masanori Otsuka 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2007,83(2):47-64
Part I describes important contributions made by some Japanese pioneers in the field of neurotransmitters: (their achievements in parentheses) J. Takamine (isolation and crystallization of adrenaline); K. Shimidzu (early hint for acetylcholine as a neurotransmitter); F. Kanematsu (donation of the Kanematsu Memorial Institute in Sydney); T. Hayashi (discovery of the excitatory action of glutamate and the inhibitory action of GABA); and I. Sano (discovery of a high concentration of dopamine in striatum, its reduction in a patient with Parkinson’s disease and the treatment with DOPA). In Part II, I present some of my reflections on my research on neurotransmitters. The work of my colleagues and myself has made some significant contributions to the establishment of neurotransmitter roles played by GABA and substance P, the first amino acid and the first peptide neurotransmitters, respectively. By the early 1960s, 3 substances, i.e., acetylcholine, noradrenaline, and adrenaline, had been established as neurotransmitters. Now the number of neurotransmitters is believed to be as many as 50 or even more mainly due to the inclusion of several amino acids and a large number of peptide transmitters. 相似文献
954.
Hiroki Sakagami Masanori Tachikawa Takayoshi Ishimoto 《International journal of quantum chemistry》2020,120(16):e26275
Detailed information on the H/D isotope effects for adsorption on the surface and absorption in the bulk is important for understanding the nuclear quantum effect. To achieve this, we developed a new theoretical approach, namely, the combined plane wave and localized basis set (CPLB) method. By using the multicomponent quantum chemical method, which takes into account the quantum effect of a proton or deuteron, with the localized part of the CPLB method, direct analysis of the H/D isotope effect about adsorption and absorption is carried out. In this study, we performed a theoretical investigation of the H/D isotope effects for adsorption on a Pd(111) surface and absorption in bulk Pd. We clearly showed an H/D isotope effect on geometry during adsorption and absorption. Our developed CPLB approach is a powerful tool for analyzing the quantum nature of H/D in surface, bulk, and inhomogeneous systems. 相似文献
955.
Noboru Matsumura Tsunao Konishi Hirokazu Hayashi Kazuhiko Mizuno Masanori Yasui Fujiko Iwasaki 《Journal of heterocyclic chemistry》2002,39(1):189-202
Macrocyclic compounds 5a‐i bearing two tetraazathiapentalene frameworks were synthesized by the reaction of 10‐S‐3 tetraazathiapentalene derivatives 3a‐f with compounds having various diisothiocyanate functions 4a‐e. The reduction of the macrocyclic compounds with NaBH4 afforded the ring‐opened macrocyclic compounds 11a‐b and 11e‐h by elimination of the hypervalent sulfur. The structures of these compounds were established by their spectral data and also by the X‐ray crystallographic analysis of lla. The other ring‐opened macrocyclic compounds 14a and 14e‐h that bear four thiourea groups were synthesized by alkaline hydrolysis of 5a and 5e‐h in that elimination of the C=SIV moiety in the tetraazathiapentalene rings occurred. 相似文献
956.
The J-PARC linac has three DTL tanks to accelerate the negative hydrogen ions from 3 MeV to 50 MeV. The RF phase and amplitude are adjusted for each cavity with a phase scan method within the accuracy of 1°in phase and 1% in amplitude. The experimental results show a remarkable agreement with the numerical model within a sufficient margin in the tuning of the last two DTL tanks. However, a notable discrepancy between the experiment and the numerical model is seen in the tuning of the first DTL tank. After studying with a three-dimensional multi-particle simulation, the generation of the low energy component and the pronounced filamentation are identified as the main causes of the discrepancy. The optimization of the tuning scheme is also discussed to attain the tuning goal accuracy for the first DTL tank. 相似文献
957.
Arsenic contamination of groundwater has long been reported in the Mushidabad district of West Bengal, India. We visited 13 arsenic‐affected families in the Makrampur village of the Beldanga block in Mushidabad during 18–21 December 2001 and collected five shallow tubewell‐water samples used general household purposes, four deep tubewell‐water samples used for drinking and cooking purposes, and 44 urine samples from those families. The arsenic concentrations in the five shallow tubewell‐water samples ranged from 18.0 to 408.4 ppb and those in the four deep tubewell‐water samples were from 5.2 to 9.6 ppb. The average arsenite (arsenic(III)), dimethylarsinic acid (DMA), monomethylarsonic acid (MMA) and arsenate (arsenic(V)) in urine were 28.7 ng mg?1, 168.6 ng mg?1, 25.0 ng mg?1 and 4.6 ng mg?1 creatinine respectively. The average total arsenic was 227.0 ng mg?1 creatinine. On comparison of the ratio of (MMA + DMA) to total arsenic, the average proportion was 86.7 ± 9.2% (mean plus/minus to residual standard deviation, n = 43). The exception was data for one boy, whose proportion was 8.0%. One woman excreted the highest total arsenic, at 2890.0 ng mg?1 creatinine. When using 43 of the urine samples (the exception being the one sample obtained from the boy) there were significantly positive correlations (p < 0.01) between arsenic(III) and MMA, between arsenic(III) and DMA and between MMA and DMA. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
958.
Stereospecific synthesis of a family of novel (E)‐2‐aryl‐1‐silylalka‐1,4‐dienes or (E)‐4‐aryl‐5‐silylpenta‐1,2,4‐trienes via a cross‐coupling of (Z)‐silyl(stannyl)ethenes with allyl halides or propargyl bromide is described. In the reaction with allyl bromide, either a Pd(dba)2? CuI combination (dba, dibenzylideneacetone) in DMF or copper(I) iodide in DMSO–THF readily catalyzes or mediates the coupling reaction of (Z)‐silyl(stannyl)ethenes at room temperature, producing novel vinylsilanes bearing an allyl group β to silicon with cis ‐disposition in good yields. Allyl chlorides as halides can be used in the CuI‐mediated reaction. CuI alone much more effectively mediates the cross‐coupling reaction with propargyl bromide in DMSO–THF at room temperature compared with a Pd(dba)2? CuI combination catalysis in DMF, providing novel stereodefined vinylsilanes bearing an allenyl group β to silicon with cis ‐disposition in good yields. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
959.
960.
Jiro Motoyoshiya Kazuya Yokota Takuro Fukami Shoji Konno Aya Yamamoto Masanori Hotta Ryu Koike Sachiko Yoshioka Yoshinori Nishi Hiromu Aoyama 《Journal of heterocyclic chemistry》2005,42(6):1063-1068
A series of 4‐styrylphthalhydrazides were synthesized and their chemiluminescence reactions were investigated. The chemiluminescence quantum yields as well as the emitters were variable depending on the electronic nature of the terminal substituents attached on the styryl groups. It was revealed that the excited phtha‐late ions were the emitters when they were highly fluorescent, while the energy transfer chemiluminescence from the excited phthalate ions to the phthalhydrazide anions took place when the fluorescence of the corresponding phthalate ions were very weakly fluorescent. 相似文献