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921.
We consider models of accelerated cosmological expansion described by the Einstein equations coupled to a nonlinear scalar field with a suitable exponential potential. We show that homogeneous and isotropic solutions are stable under small nonlinear perturbations without any symmetry assumptions. Our proof is based on results on the nonlinear stability of de Sitter spacetime and Kaluza-Klein reduction techniques. 相似文献
922.
Jing Jin Mark Prochaska Dominic Rochefort David K. Kim Lin Zhuang Francis J. DiSalvo R.B. van Dover Héctor D. Abruña 《Applied Surface Science》2007,254(3):653-661
We used a high-throughput method to screen for direct methanol fuel cell anode electrocatalysts in the Pt-Bi-Pb system. Previous studies showed that PtBi and PtPb (both NiAs structure type) were active electrocatalysts for the oxidation of formic acid, but only PtPb was active in oxidizing methanol. We synthesized thin films with continuous composition spreads of the three elements by magnetron sputtering at deposition temperatures from ambient to 510 °C. A fluorescence method was then used to identify compositions that were active toward methanol oxidation. Only films deposited between temperatures of 160 and 400 °C showed electrocatalytic activity. The areas that were active for methanol oxidation showed predominantly the NiAs structure type according to XRD, with optimal activity for compositions near PtBi0.01Pb0.53. 相似文献
923.
Measuring particle size-dependent physicochemical structure in airborne
single walled carbon nanotube agglomerates 总被引:1,自引:1,他引:1
Andrew D. Maynard Bon Ki Ku Mark Emery Mark Stolzenburg Peter H. McMurry 《Journal of nanoparticle research》2007,9(1):85-92
As-produced single-walled carbon nanotube (SWCNT) material is a complex matrix of carbon nanotubes, bundles of nanotubes (nanoropes),
non-tubular carbon and metal catalyst nanoparticles. The pulmonary toxicity of material released during manufacture and handling
will depend on the partitioning and arrangement of these components within airborne particles. To probe the physicochemical
structure of airborne SWCNT aggregates, a new technique was developed and applied to aerosolized as-produced material. Differential
Mobility Analysis-classified aggregates were analyzed using an Aerosol Particle Mass Monitor, and a structural parameter Γ
(proportional to the square of particle mobility diameter, divided by APM voltage) derived. Using information on the constituent
components of the SWCNT, modal values of Γ were estimated for specific particle compositions and structures, and compared
against measured values. Measured modal values of Γ for 150 nm mobility diameter aggregates suggested they were primarily
composed of non-tubular carbon from one batch of material, and thin nanoropes from a second batch of material – these findings
were confirmed using Transmission Electron Microscopy. Measured modal values of Γ for 31 nm mobility diameter aggregates indicated
that they were comprised predominantly of thin carbon nanoropes with associated nanometer-diameter metal catalyst particles;
there was no indication that either catalyst particles or non-tubular carbon particles were being preferentially released
into the air. These results indicate that the physicochemistry of aerosol particles released while handling as-produced SWCNT
may vary significantly by particle size and production batch, and that evaluations of potential health hazards need to account
for this.
Disclaimer: The mention of any company or product does not constitute an endorsement by the Centers for Disease Control and
Prevention. The findings and conclusions in this paper are those of the authors and do not necessarily represent the views
of the National Institute for Occupational Safety and Health. 相似文献
924.
A second-order accurate numerical method for the two-dimensional fractional diffusion equation 总被引:1,自引:0,他引:1
Spatially fractional order diffusion equations are generalizations of classical diffusion equations which are used in modeling practical superdiffusive problems in fluid flow, finance and others. In this paper, we present an accurate and efficient numerical method to solve a fractional superdiffusive differential equation. This numerical method combines the alternating directions implicit (ADI) approach with a Crank–Nicolson discretization and a Richardson extrapolation to obtain an unconditionally stable second-order accurate finite difference method. The stability and the consistency of the method are established. Numerical solutions for an example super-diffusion equation with a known analytic solution are obtained and the behavior of the errors are analyzed to demonstrate the order of convergence of the method. 相似文献
925.
Gareth AD Hardy Nesrina Imami Mark R Nelson Ann K Sullivan Ron Moss Marlén MI Aasa-Chapman Brian Gazzard Frances M Gotch 《Journal of immune based therapies and vaccines》2007,5(1):6-12
Background
Fully functional HIV-1-specific CD8 and CD4 effector T-cell responses are vital to the containment of viral activity and disease progression. These responses are lacking in HIV-1-infected patients with progressive disease. We attempted to augment fully functional HIV-1-specific CD8 and CD4 effector T-cell responses in patients with advanced chronic HIV-1 infection. 相似文献926.
927.
Liquid-liquid phase transfer conditions have been found to provide highly selective monoalkylation of tert-butyl 3,4-dihydroxy-4-phenylpiperidine-1-carboxylate, a transformation for which many other common alkylation protocols proved inadequate. The high preference for 3-O-alkylation in the phase transfer alkylation is emphasised by the absence of diether formation even in the presence of a large excess of reagents. 相似文献
928.
Samarium(II) diiodide mediated intramolecular cyclisation of mixed enone-enoate substrates in THF/MeOH is described. Spirocyclic ethers are obtained, and the stereodefined preparation of 1-oxaspiro[4.4]nonan-7-one products is included. 相似文献
929.
Mark Krusemeyer 《代数通讯》2013,41(7):657-663
930.