全文获取类型
收费全文 | 5047篇 |
免费 | 207篇 |
国内免费 | 33篇 |
专业分类
化学 | 3597篇 |
晶体学 | 20篇 |
力学 | 134篇 |
数学 | 865篇 |
物理学 | 671篇 |
出版年
2023年 | 41篇 |
2022年 | 52篇 |
2021年 | 91篇 |
2020年 | 116篇 |
2019年 | 110篇 |
2018年 | 68篇 |
2017年 | 55篇 |
2016年 | 154篇 |
2015年 | 139篇 |
2014年 | 177篇 |
2013年 | 277篇 |
2012年 | 312篇 |
2011年 | 359篇 |
2010年 | 253篇 |
2009年 | 201篇 |
2008年 | 314篇 |
2007年 | 315篇 |
2006年 | 301篇 |
2005年 | 301篇 |
2004年 | 236篇 |
2003年 | 207篇 |
2002年 | 212篇 |
2001年 | 82篇 |
2000年 | 70篇 |
1999年 | 71篇 |
1998年 | 59篇 |
1997年 | 64篇 |
1996年 | 69篇 |
1995年 | 45篇 |
1994年 | 39篇 |
1993年 | 23篇 |
1992年 | 19篇 |
1991年 | 32篇 |
1990年 | 19篇 |
1989年 | 30篇 |
1988年 | 18篇 |
1986年 | 21篇 |
1985年 | 28篇 |
1984年 | 30篇 |
1983年 | 27篇 |
1982年 | 33篇 |
1981年 | 23篇 |
1980年 | 25篇 |
1979年 | 18篇 |
1978年 | 33篇 |
1977年 | 20篇 |
1976年 | 15篇 |
1975年 | 12篇 |
1974年 | 18篇 |
1973年 | 11篇 |
排序方式: 共有5287条查询结果,搜索用时 0 毫秒
61.
Transport in Porous Media - We develop an analytical model describing the flow of NaCl– $$\hbox {H}_2\hbox {O}$$ in a saturated porous medium adjacent to a hot vertical wall and apply the... 相似文献
62.
Raluca Pele Gabriel Marc Anca Stana Ioana Ionu Cristina Nastas Brîndua Tiperciuc Ilioara Oniga Adrian Pîrnu Laurian Vlase Ovidiu Oniga 《Molecules (Basel, Switzerland)》2022,27(8)
Considering the important damage caused by the reactive oxygen (ROS) and nitrogen (RNS) species in the human organism, the need for new therapeutic agents, with superior efficacy to the known natural and synthetic antioxidants, is crucial. Quinazolin-4-ones are known for their wide range of biological activities, and phenolic compounds display an important antioxidant effect. Linking the two active pharmacophores may lead to an increase of the antioxidant activity. Therefore, we synthesized four series of new hybrid molecules bearing the quinazolin-4-one and phenol scaffolds. Their antioxidant potential was evaluated in vitro, considering different possible mechanisms of action: hydrogen atom transfer, ability to donate electrons and metal ions chelation. Theoretical quantum and thermodynamical calculations were also performed. Some compounds, especially the ortho diphenolic ones, exerted a stronger antioxidant effect than ascorbic acid and Trolox. 相似文献
63.
Benjamin D. Leonard Arnab Ghosh Farshid Sadeghi Sachin Shinde Marc Mittelbach 《International Journal of Solids and Structures》2014
A new approach was developed for modeling the effect of the third body on fretting. This was accomplished using the combined finite-discrete element method (FDEM) in which the third body is analyzed as discrete elements while the first bodies are modeled using finite elements. This approach provides a link between large scale models which treat the mass of wear debris as a single or small number of bodies and small scale models which only study a control volume. The FDEM was used to analyze the behavior of third body particles between flat sliding surfaces. When the third body mass is composed of unconnected particles, it behaves as a Newtonian fluid, but this behavior ceases when the particles are connected into platelets. The FDEM was also used to study the behavior of third body particles inside a Hertzian line contact. As the number of particles and platelet size increase the load carried by the worn slip zone grows larger in relationship to the unworn stick zone. 相似文献
64.
Payment data is one of the most valuable assets that retail banks can leverage as the major competitive advantage with respect to new entrants such as Fintech companies or giant internet companies. In marketing, the value behind data relates to the power of encoding customer preferences: the better you know your customer, the better your marketing strategy. In this paper, we present a B2B2C lead generation application based on payment transaction data within the online banking system. In this approach, the bank is an intermediary between its private customers and merchants. The bank uses its competence in Machine Learning driven marketing to build a lead generation application that helps merchants run data driven campaigns through the banking channels to reach retail customers. The bank’s retail customers trade the utility hidden in its payment transaction data for special offers and discounts offered by merchants. During the entire process banks protects the privacy of the retail customer. 相似文献
65.
We compare the Q parameter obtained from scalar, semi-analytical and full vector models for realistic transmission systems. One set of systems is operated in the linear regime, while another is using solitons at high peak power. We report in detail on the different results obtained for the same system using different models. Polarisation mode dispersion is also taken into account and a novel method to average Q parameters over several independent simulation runs is described. 相似文献
66.
Clement Levard F. Marc Michel Yingge Wang Yongseong Choi Peter Eng Gordon E. Brown Jr 《Journal of synchrotron radiation》2011,18(6):871-878
Characterizing interfacial reactions is a crucial part of understanding the behavior of nanoparticles in nature and for unlocking their functional potential. Here, an advanced nanostructure characterization approach to study the corrosion processes of silver nanoparticles (Ag‐Nps), currently the most highly produced nanoparticle for nanotechnology, is presented. Corrosion of Ag‐Nps under aqueous conditions, in particular in the presence of organic matter and halide species common to many natural environments, is of particular importance because the release of toxic Ag+ from oxidation/dissolution of Ag‐Nps may strongly impact ecosystems. In this context, Ag‐Nps capped with polyvinolpyrrolidone (PVP) in contact with a simple proxy of organic matter in natural waters [polyacrylic acid (PAA) and Cl? in solution] has been investigated. A combination of synchrotron‐based X‐ray standing‐wave fluorescence yield‐ and X‐ray diffraction‐based experiments on a sample consisting of an approximately single‐particle layer of Ag‐Nps deposited on a silicon substrate and coated by a thin film of PAA containing Cl revealed the formation of a stable AgCl corrosion product despite the presence of potential surface stabilizers (PVP and PAA). Diffusion and precipitation processes at the Ag‐Nps–PAA interface were characterized with a high spatial resolution using this new approach. 相似文献
67.
We have observed phase defects in quasi-2D Bose-Einstein condensates close to the condensation temperature. Either a single or several equally spaced condensates are produced by selectively evaporating the sites of a 1D optical lattice. When several clouds are released from the lattice and allowed to overlap, dislocation lines in the interference patterns reveal nontrivial phase defects. 相似文献
68.
In two papers Franz et al. proved bounds for the free energy of diluted random constraints satisfaction problems, for a Poisson degree distribution (Franz and Leone in J Stat Phys 111(3–4):535–564, 2003) and a general distribution (Franz et al. in J Phys A 36(43), 10967, 2003). Panchenko and Talagrand (Probab Theo Relat Fields 130(3):319–336, 2004) simplified the proof and generalized the result of Franz and Leone (J Stat Phys 111(3–4):535–564, 2003) for the Poisson case. We provide a new proof for the general degree distribution case and as a corollary, we obtain new bounds for the size of the largest independent set (also known as hard core model) in a large random regular graph. Our proof uses a combinatorial interpolation based on biased random walks (Salez in Combin Probab Comput 25(03):436–447, 2016) and allows to bypass the arguments in Franz et al. (J Phys A 36(43):10967, 2003) based on the study of the Sherrington–Kirkpatrick (SK) model. 相似文献
69.
Durand M 《Physical review letters》2007,98(8):088701
The structure of pipe networks minimizing the total energy dissipation rate is studied analytically. Among all the possible pipe networks that can be built with a given total pipe volume (or pipe lateral surface area), the network which minimizes the dissipation rate is shown to be loopless. Furthermore, such an optimal network is shown to contain at most N-2 nodes in addition to the N sources plus sinks that it connects. These results are valid whether the possible locations for the additional nodes are chosen freely or from a set of nodes (such as points of a grid). Applications of these results to various physical situations and to the efficient computation of optimal pipe networks are also discussed. 相似文献
70.
This article is concerned with Markov chains on m constructed by randomly choosing an affine map at each stage, and then making the transition from the current point to its image under this map. The distribution of the random affine map can depend on the current point (i.e., state of the chain). Sufficient conditions are given under which this chain is ergodic. 相似文献