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排序方式: 共有170条查询结果,搜索用时 765 毫秒
81.
Hamid Khanmohammadi Hassan Keypour Mehdi Salehei Fard Mohammad H. Abnosi 《Journal of inclusion phenomena and macrocyclic chemistry》2009,63(1-2):97-108
Two new pendant armed Schiff base macrocyclic complexes, [MgL1](ClO4)2 (1), and [MgL2](ClO4)2 (2), have been prepared via cyclocondensation of 2,6-diformylpyridine and 2,6-diacetylpyridine with two hexadentate hexaamines, ten and tmen, in the presence of Mg(II) ion. The ligands are 15-membered pentaaza macrocycles having two 2-aminoethyl pendant arms. The newly prepared complexes are investigated by IR, 1H NMR, 13C{1H} NMR, DEPT(135), COSY(H, H) and HMQC spectroscopic methods. The antimicrobial screening of newly prepared complexes, 1 and 2, as well as previously prepared similar complexes, [MgL3](ClO4)2 (3) and [MgL4](ClO4)2 (4), against Escherichia coli, Staphylococcus aureus and candidia albicans showed that the macrocyclic complexes of Mg(II) containing 15-membered pentaaza ring (1, 2 and 3) have no activity. Where as the compound 4, which contain 16-membered pentaaza ring, had remarkable inhibition zone on the culture of S. aureus and E. coli as compared with standard drugs. The 1H and 13C chemical shieldings of gas phase complexes were also studied by the gauge independent atomic orbital (GIAO) and continuous set of gauge transformations (CSGT) methods at the level of density functional theory (DFT). The computed 13C chemical shifts are in reasonably good agreement with the experimental data. 相似文献
82.
Linear-dendritic copolymers containing hyperbranched poly(citric acid) and linear poly(ethylene glycol) blocks (PCA-PEG-PCA) were used as reducing and capping agents to synthesize and support gold nanoparticles (AuNPs). PCA-PEG-PCA copolymers with 1758, 1889 and 3446 molecular weights, called A1, A2 and A3 through this work, respectively, were synthesized using 2, 5, and 10 citric acid/PEG molar ratios. The diameter of A1, A2 and A3 in a fresh water solution was investigated using dynamic light scattering (DLS) and it was between 1.8 and 2.8 nm. AuNPs were simply synthesized and supported by addition a boiling aqueous solution of HAuCl4 to aqueous solutions of A1, A2 and A3. Supported AuNPs were stable in water for several months and agglomeration was not occurred. The loading capacity of A1, A2 and A3 and the size of synthesized AuNPs were investigated using UV spectroscopy and transmission electron microscopy (TEM). It was found that the loading capacity of PCA-PEG-PCA copolymers depend on the concentration of copolymers and the size of their poly(citric acid) parts directly. For example average loading capacities for 400 μM concentration of A1, A2 and A3 were 32.24, 37.4 and 41.52 μM, respectively, and average loading capacities for 400, 200 and 100 μM concentration of A1 were 32.24, 20.28 and 9.1 μM, respectively. Interestingly there was a reverse relation between the size of synthesized AuNPs and size of poly(citric acid) parts of PCA-PEG-PCA copolymers. 相似文献
83.
Y Abdollahi A Zakaria AH Abdullah HR Masoumi H Jahangirian K Shameli M Rezayi S Banerjee T Abdollahi 《Chemistry Central journal》2012,6(1):88
ABSTRACT: The optimization processes of photo degradation are complicated and expensive when it is performed with traditional methods such as one variable at a time. In this research, the condition of ortho-cresol (o-cresol) photo degradation was optimized by using a semi empirical method. First of all, the experiments were designed with four effective factors including irradiation time, pH, photo catalyst's amount, o-cresol concentration and photo degradation % as response by response surface methodology (RSM). The RSM used central composite design (CCD) method consists of 30 runs to obtain the actual responses. The actual responses were fitted with the second order algebraic polynomial equation to select a model (suggested model). The suggested model was validated by a few numbers of excellent statistical evidences in analysis of variance (ANOVA). The used evidences include high Fvalue (143.12), very low P-value (<0.0001), non-significant lack of fit, the determination coefficient (R2 = 0.99) and the adequate precision (47.067). To visualize the optimum, the validated model simulated the condition of variables and response (photo degradation %) by a few number of three dimensional plots (3D). To confirm the model, the optimums were performed in laboratory. The results of performed experiments were quite close to the predicted values. In conclusion, the study indicated that the model is successful to simulate the optimum condition of o-cresol photo degradation under visible-light irradiation by manganese doped ZnO nanoparticles. 相似文献
84.
Mehdi Shakourian‐Fard Alireza Fattahi Zahra Jamshidi 《Journal of Physical Organic Chemistry》2012,25(2):153-161
Binding of Mg2+, Ca2+, Zn2+, and Cu+ metal ions with 2′‐deoxythymidine (dT) nucleoside was studied using a density functional theory method and a 6‐311++G(d,p) basis set. This work demonstrated that the interaction of dT with these cations is tri‐coordinated η (O2, O4′, O5′). Among the four types of cations, Zn2+ cation exhibited the most tendency to interact with the dT. Cations via their interaction with dT can affect the N‐glycosidic bond length, the values of pseudorotation of the sugar ring, the orientation of the base unit with respect to the sugar ring, and the acidity of the O5′H, O3′H, and N3H groups in the dT nucleoside. Natural bond orbital analysis was performed to calculate the charge transfer and natural population analysis of the complexes. Quantum theory of atoms in molecules was also applied to determine the nature of interactions. It was shown that in dT–Mg2+ and dT–Ca2+ complexes, the bonds are electrostatic (closed‐shell) interactions, although they are partially covalent and partially electrostatic interactions in dT–Zn2+ and dT–Cu+ complexes. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
85.
Mir Nabi Pirouzi Fard 《Computational Statistics》2010,25(2):257-267
A comparison between the ordinary least-squares estimator and the weighted least-squares estimator when the data set arises
from the standard extreme value distribution is provided. Probability plot of the extreme value distribution is applied. A
goodness-of-fit test of the standard extreme value distribution is introduced. The percentage points of the test statistic
are investigated. The results of power study for the test statistic under various alternatives show that in most situations
the proposed test statistic serves as well as do competing alternatives. 相似文献
86.
Let(M,ω)be a symplectic manifold.In this paper,the authors consider the notions of musical(bemolle and diesis)isomorphisms ω~b:T M→T~*M and ω~?:T~*M→TM between tangent and cotangent bundles.The authors prove that the complete lifts of symplectic vector field to tangent and cotangent bundles is ω~b-related.As consequence of analyze of connections between the complete lift ~cω_(T M )of symplectic 2-form ω to tangent bundle and the natural symplectic 2-form dp on cotangent bundle,the authors proved that dp is a pullback o f~cω_(TM)by ω~?.Also,the authors investigate the complete lift ~cφ_T~*_M )of almost complex structure φ to cotangent bundle and prove that it is a transform by ω~?of complete lift~cφ_(T M )to tangent bundle if the triple(M,ω,φ)is an almost holomorphic A-manifold.The transform of complete lifts of vector-valued 2-form is also studied. 相似文献
87.
Manouchehr Mamaghani Abed Badrian 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6):1181-1186
The hydroxy group of the Baylis-Hillman adducts was protected with trimethylsilyl (TMS) group using the reaction of adducts 1a–h with hexamethyldisilazane (HMDS) catalyzed by iodine under nearly neutral reaction conditions. 相似文献
88.
Manouchehr Mamaghani Khalil Tabatabaeian Abed Badrian 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1347-1353
A new, universal, and versatile method has been developed for the synthesis of the chiral α,β-unsaturated N-acyl-oxazolidin-2-ones 4 based on the Wittig reaction of the triphenylphosphonium salt 7 derived from the (R)-3-(2-Chloro-acetyl)-5,5-dimethyl-4-phenyl-oxazolidin-2-one 6. 相似文献
89.
Russian Journal of Applied Chemistry - In this study, Ni/TiO2/NaX zeolite nanoparticles were synthesized by hydrothermal and wet inoculation methods and characterized by XRD, FTIR, SEM, EDXA, TEM,... 相似文献
90.