Synthesis and Characterization of CdCO3 Nanostructures via Simple Hydrothermal Method

CdCO₃ nanostructures were synthesized via simple hydrothermal method by Cd(NO₃)₂, ethylenediamine and hydrazine as reagents. The products were characterized with X-ray diffraction scanning electron microscopy, energy-dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy. Different parameter’s effect on product size and morphology were investigated.     

Convenient Ultrasound-Promoted Regioselective Synthesis of Fused 6-Amino-3-methyl-4-aryl-1H-pyrazolo[3,4-b]pyridine-5-carbonitrile

A multicomponent, catalyst-free reaction for the synthesis of fused 6-amino-3-methyl-4-aryl-1H-pyrazolo [3,4-b] pyridine-5-carbonitrile from 3-amino-5-methylpyrazole, malononitrile, and substituted aldehydes under ultrasound irradiation in short reaction times (8–10 min) with good yields (85–98%) is reported.

Bilipschitz homogeneous Jordan curves

We characterize bilipschitz homogeneous Jordan curves by utilizing quasihomogeneous parameterizations. We verify that rectifiable bilipschitz homogeneous Jordan curves satisfy a chordarc condition. We exhibit numerous examples including a bilipschitz homogeneous quasicircle which has lower Hausdorff density zero. We examine homeomorphisms between Jordan curves.

     

Generation of a Novel High-Affinity Monoclonal Antibody with Conformational Recognition Epitope on Human IgM

As IgM is the first isotype of antibody which appears in blood after initial exposure to a foreign antigen in the pattern of primary response, detection, and quantification of this molecule in blood seems invaluable. To approach these goals, generation, and characterization of a highly specific mAb (monoclonal antibody) against human IgM were investigated. Human IgM immunoglobulins were used to immunize Balb/c mice. Spleen cells taken from the immunized animals were fused with SP2/O myeloma cells using PEG (polyethylene glycol, MW 1450) as fusogen. The hybridomas were cultured in HAT containing medium and supernatants from the growing hybrids were screened by enzyme-linked immunosorbent assay (ELISA) using plates coated with pure human IgM and the positive wells were then cloned at limiting dilutions. The best clone designated as MAN-1, was injected intraperitoneally to some Pristane-injected mice. Anti-IgM mAb was purified from the animals’ ascitic fluid by protein-G sepharose followed by DEAE-cellulose ion exchange chromatography. MAN-1 interacted with human IgM with a very high specificity and affinity. The purity of the sample was tested by SDS-PAGE and the affinity constant was measured ( K_\texta = \text3.\text5 ×\text10^\text9\textM^{\text - 1} ) \left( {{K_{\text{a}}} = {\text{3}}.{\text{5}} \times {\text{1}}{0^{\text{9}}}{{\text{M}}^{{\text{ - 1}}}}} \right) . Immunoblotting and competitive ELISA were done and the results showed that the harvested antibody recognizes a conformational epitope on the μ chain of human IgM and there was no cross-reactivity with other subclasses of immunoglobulins. Furthermore, isotyping test was done and the results showed the subclass of the obtained mAb which was IgG₁κ.     

SILICA SULFURIC ACID; AN EFFICIENT AND REUSABLE CATALYST FOR REGIOSELECTIVE RING OPENING OF EPOXIDES BY ALCOHOLS AND WATER

The nucleophilic ring opening reactions of epoxides by aliphatic alcohols and water are achieved efficiently in the presence of catalytic amounts of silica sulfuric acid with high degree of regioselectivity. The catalyst is reusable and can be applied several times without any decrease in the yield of reactions.     

Results on the Grundy chromatic number of graphs

Given a graph G, by a Grundy k-coloring of G we mean any proper k-vertex coloring of G such that for each two colors i and j, i<j, every vertex of G colored by j has a neighbor with color i. The maximum k for which there exists a Grundy k-coloring is denoted by Γ(G) and called Grundy (chromatic) number of G. We first discuss the fixed-parameter complexity of determining Γ(G)?k, for any fixed integer k and show that it is a polynomial time problem. But in general, Grundy number is an NP-complete problem. We show that it is NP-complete even for the complement of bipartite graphs and describe the Grundy number of these graphs in terms of the minimum edge dominating number of their complements. Next we obtain some additive Nordhaus-Gaddum-type inequalities concerning Γ(G) and Γ(G^c), for a few family of graphs. We introduce well-colored graphs, which are graphs G for which applying every greedy coloring results in a coloring of G with χ(G) colors. Equivalently G is well colored if Γ(G)=χ(G). We prove that the recognition problem of well-colored graphs is a coNP-complete problem.     

A convenient ultrasound-promoted regioselective synthesis of fused polycyclic 4-aryl-3-methyl-4,7-dihydro-1H-pyrazolo[3,4-b]pyridines

Fused polycyclic 4-aryl-3-methyl-4,7-dihydro-1H-pyrazolo[3,4-b]pyridines were obtained in a three-component regioselective reaction of 5-amino-3-methyl-1H-pyrazole, 2H-indene-1,3-dione and arylaldehydes in ethanol under ultrasound irradiation. This rapid method produced the products in short reaction times (4–5 min) and excellent yields (88–97%).     

A novel dispersion-shifted single mode optical fiber design with ultra-high-bit-rate and very low loss for long-haul communications

In this paper, a novel dispersion-shifted multi-clad optical fiber with very small bending loss and ultra-high bit-rate applicable for large capacity information transmission systems is presented. To decrease dispersion and higher-order dispersion effects at λ = 1.55 μm, a weighted pulse broadening factor and genetic algorithm (GA) optimization technique is used. Compared to the works reported previously, this method can precisely set the zero-dispersion wavelength. This kind of dispersion-shifted fibers has dispersion, dispersion slope, mode field diameter (MFD), effective area and quality factor within −1.40 × 10⁻⁴ to −8.44 × 10⁻² ps/km nm, 3.06 × 10⁻² to −4.07 × 10⁻² ps/km nm², 5.56−5.85 μm, 119.25−176.42 μm² and 3.49-5.27 at λ = 1.55 μm, respectively. Besides, by applying dispersion at λ = 1.55 μm as the cost function, dispersion of about 1.31 × 10⁻⁸ ps/km nm is obtained. Thus, this novel optical fiber can be used in long-haul high information-transmission capacity communication systems.