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81.
Arijit Ghorai Arun Kumar Mandal Susanta Banerjee 《Journal of polymer science. Part A, Polymer chemistry》2020,58(2):263-279
Sulfonated polytriazoles have drawn a great attention as high performance polymers and their good film forming ability. In the present study, a phosphorus containing new diazide monomer namely, bis-[4-(4′-aminophenoxy)phenyl]phenylphosphine was synthesized and accordingly, a series of phosphorus containing sulfonated polytriazoles (PTPBSH-XX) was synthesized by reacting equimolar amount of this diazide monomer (PAZ) in combination with another sulfonated diazide monomer (DSAZ) and a terminal bis-alkyne (BPALK) by the Cu (I) catalyzed azide–alkyne click polymerization. The polymers were characterized by nuclear magnetic resonance (1H, 13C, 31P NMR) and Fourier transform infrared spectroscopic techniques. The sulfonic acid content of the copolymers also determined from the different integral values obtained from the 1H NMR signals. The small-angle X-ray scattering results unfolded the well-separated dispersion of the hydrophilic and hydrophobic domains of the polymers. As a whole, the copolymer membranes displayed sufficient thermal, mechanical, and oxidative stabilities high with high proton conductivity and low water uptake that are essential for proton exchange membrane applications. The copolymers exhibited oxidative stability in the range of 15–24 h and had proton conductivity values were found as high as 38–110 mS cm−1 at 80 °C in completely hydrated condition. Among the all copolytriazoles, PTPBSH-90 (BPALK:DSAZ:PAZ = 100:90:10) having IECW = 2.44 mequiv g−1, showed proton conductivity as high as 119 mS cm−1 at 90 °C with an activation energy of 10.40 kJ mol−1 for the proton conduction. © 2020 Wiley Periodicals, Inc. J. Polym. Sci. 2020 , 58, 263–279 相似文献
82.
Johannes Maschita Dr. Tanmay Banerjee Gökcen Savasci Dr. Frederik Haase Prof. Christian Ochsenfeld Prof. Bettina V. Lotsch 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(36):15880-15888
Covalent organic frameworks (COFs) are an extensively studied class of porous materials, which distinguish themselves from other porous polymers in their crystallinity and high degree of modularity, enabling a wide range of applications. COFs are most commonly synthesized solvothermally, which is often a time-consuming process and restricted to well-soluble precursor molecules. Synthesis of polyimide-linked COFs (PI-COFs) is further complicated by the poor reversibility of the ring-closing reaction under solvothermal conditions. Herein, we report the ionothermal synthesis of crystalline and porous PI-COFs in zinc chloride and eutectic salt mixtures. This synthesis does not require soluble precursors and the reaction time is significantly reduced as compared to standard solvothermal synthesis methods. In addition to applying the synthesis to previously reported imide COFs, a new perylene-based COF was also synthesized, which could not be obtained by the classical solvothermal route. In situ high-temperature XRPD analysis hints to the formation of precursor–salt adducts as crystalline intermediates, which then react with each other to form the COF. 相似文献
83.
Dey Chaudhuri S. Banerjee D. Bhattacharjee T. Wasim Raja Sk Acharya R. Pujari P. K. 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(2):829-835
Journal of Radioanalytical and Nuclear Chemistry - Performance of 1″?×?1″ LaBr3 (5% Ce) scintillator coupled to Hamamatsu R2083 PM Tube has been investigated for the... 相似文献
84.
Manas Mahapatra Arnab Dutta Joy Sankar Deb Roy Ujjal Das Dr. Snehasis Banerjee Prof. Sanjit Dey Dr. Pijush Kanti Chattopadhyay Prof. Dilip K. Maiti Dr. Nayan Ranjan Singha 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(2):502-516
To circumvent costly fluorescent labeling, five nonconventional, multifunctional, intrinsically fluorescent aliphatic terpolymers ( 1 – 5 ) have been synthesized by C−C/C−N-coupled, solution polymerization of two non-emissive monomers with protrusions of fluorophore monomers generated in situ. These scalable terpolymers were suitable for sensing and high-performance exclusion of CuII, logic function, and bioimaging. The structures of the terpolymers, in situ attachment of fluorescent monomers, aggregation-induced enhanced emission, bioimaging ability, and super adsorption were investigated by 1H and 13C NMR, EPR, FTIR, X-ray photoelectron, UV/Vis, and atomic absorption spectroscopy, thermogravimetric analysis, high-resolution transmission electron microscopy, dynamic light scattering, solid-state fluorescence, fluorescence imaging, and fluorescence lifetime measurements, as well as by isotherm, kinetics, and thermodynamic studies. The geometries and electronic structures of the fluorophores and the absorption and emission properties of the terpolymers were examined by DFT, time-dependent DFT, and natural transition orbital analyses. For 1 , 2 , and 5 , the limits of detection were determined to be 1.03×10−7, 1.65×10−7, and 1.77×10−7 m , respectively, and the maximum adsorption capacities are 1575.21, 1433.70, and 1472.21 mg g−1, respectively. 相似文献
85.
A simple, efficient, and facile heterogeneous multi-walled carbon nanotubes-zirconia nanocomposite (MWCNTs-ZrO2) has been synthesized using natural feedstock coconut juice (água-de-coco do Ceará). The synthesized catalyst was characterized by Fourier transform infrared spectroscopy, X-ray diffraction, field emission scanning electron microscopy, and X-ray photoelectron spectroscopy analysis. The heterogeneous nanocomposite has been used for one-pot synthesis of various N-heterocyclic compounds like pyrazoles, 1,2-disubstituted benzimidazoles, 2-arylbenzazoles, and 2,3-dihydroquinazolin-4(1H)-ones under green reaction medium at room temperature. This novel method has several advantages, such as short reaction time, simple work-up, excellent yield, and green reaction conditions. The catalyst was recycled up to four times without significant loss in catalytic activity. 相似文献
86.
The present work deals with the late time evolution of the linear density contrast in the dark energy models reconstructed from the jerk parameter. It is found that the non-interacting models are favoured compared to the models where an interaction is allowed in the dark sector. 相似文献
87.
It is proved that the most general conformally flat singularity-free solution for charged dust in static equilibrium must be spherically symmetric and the solution is unique. It matches with exterior Reissner-Nordström metric. The manifest form of the metric conformal to Minkowskian metric is also given.On study leave from Jadavpur University, Calcutta-700032, India. 相似文献
88.
A. Banerjee S. B. Dutta Choudhury S. Chatterjee 《General Relativity and Gravitation》1992,24(9):991-999
It is shown that in the case of a spherical nonstatic fluid distribution undergoing shear-free motion the field equations in higher dimensional space-time can be reduced to a single second-order differential equation involving an arbitrary function of the radial co-ordinate. This result extends to higher dimensions a similar one obtained by Wyman and Faulkes earlier for 4D space-time. Solving this differential equation a number of new solutions is found, and the dynamical behaviour of one of the models is briefly discussed. The ansatz is later generalised to include the electromagnetic field as well. 相似文献
89.
On a question of Gross 总被引:1,自引:0,他引:1
Abhijit Banerjee 《Journal of Mathematical Analysis and Applications》2007,327(2):1273-1283
Using the notion of weighted sharing of sets we prove two uniqueness theorems which improve the results proved by Fang and Qiu [H. Qiu, M. Fang, A unicity theorem for meromorphic functions, Bull. Malaysian Math. Sci. Soc. 25 (2002) 31-38], Lahiri and Banerjee [I. Lahiri, A. Banerjee, Uniqueness of meromorphic functions with deficient poles, Kyungpook Math. J. 44 (2004) 575-584] and Yi and Lin [H.X. Yi, W.C. Lin, Uniqueness theorems concerning a question of Gross, Proc. Japan Acad. Ser. A 80 (2004) 136-140] and thus provide an answer to the question of Gross [F. Gross, Factorization of meromorphic functions and some open problems, in: Proc. Conf. Univ. Kentucky, Lexington, KY, 1976, in: Lecture Notes in Math., vol. 599, Springer, Berlin, 1977, pp. 51-69], under a weaker hypothesis. 相似文献
90.
Self-injection length in La0.7Ca0.3MnO3-YBa2Cu3O7-δ ferromagnet-superconductor multilayer thin films
We have carried out extensive studies on the self-injection problem in barrierless heterojunctions between La0.7Ca0.3MnO3 (LCMO) and YBa2Cu3O7-δ (YBCO) thin films. The heterojunctions were formed in situ by sequentially growing LCMO and YBCO films on 〈100〉 LaAlO3 (LAO) substrate using a pulsed laser deposition (PLD) system. YBCO micro-bridges with 64 μm width were patterned both on
the LAO (control) and LCMO side of the substrate. Critical current, I
c, was measured at 77 K on both the control side as well as the LCMO side for different YBCO film thickness. It was observed
that while the control side showed a J
c of ∼ 2 × 106 A/cm2, the LCMO side showed about half the value for the same thickness (1800 ?). The difference in J
c indicates that a certain thickness of YBCO has become ‘effectively’ normal due to self-injection. From the measurement of
J
c at two different thicknesses (1800 ? and 1500 ?) of YBCO films both on the LAO as well as the LCMO side, the value of self-injection
length (at 77 K) was estimated to be ∼ 900 ?. To the authors’ best knowledge, this is the first time that self-injection length
has been quantified. A control experiment carried out with LaNiO3 deposited by PLD on YBCO did not show any evidence of self-injection. 相似文献