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11.
Mahsa Kiani Mojtaba Bagherzadeh Soraia Meghdadi Farzaneh Fadaei-Tirani Maryam Babaie Kurt Schenk-Joß 《应用有机金属化学》2020,34(11):e5911
The new Co(II) - carboxamide complex ( 1 ) and Co3O4 nanoparticles ( 2 ), by way of thermal decomposition of ( 1 ) have been efficiently synthesised in the environment-friendly. X-ray diffraction reveals a slightly distorted octahedral coordination of cobalt (four nitrogens and two oxygens) in ( 1 ) and regular octahedral or tetrahedral ones (oxygens only) in ( 2 ). The investigation of ( 1 ) and ( 2 ) in the Mizoroki-Heck and epoxidation of alkens reactions showed them both to be powerful, green and inexpensive catalysts. 相似文献
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Ardeshir Khazaei Mahsa Tavasoli Vahid Jamshidi Fatemeh Gohari Ghalil Ahmad Reza Moosavi‐Zare 《应用有机金属化学》2018,32(7)
Cu ( II ) supported on poly(8‐hydroxyquinoline‐p‐styrenesulfonate) (Cu ( II )@PHQSS) was prepared and fully characterized by the different techniques including fourier transform infrared spectroscopy (FT‐IR), 1H NMR, 13C NMR, thermal gravimetric analysis (TGA), differential thermal gravimetric (DTG), differential thermal analysis (DTA), scanning electron microscope (SEM) and energy dispersive X‐ray analysis (EDS). Afterward, the Cu ( II )@PHQSS as nanostructured catalyst was used as catalyst for the synthesis of hexahydroquinolines. 相似文献
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A topological index for a molecular graph G is a numeric quantity invariant under automorphisms of G. A dendrimer is an artificially manufactured or synthesized molecule built up from branched units called monomers. In this article an infinite class of dendrimer nanostars is investigated under three topological indices containing PI, Szeged and edge Szeged. 相似文献
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Structure–Activity Studies of Cysteine‐Rich α‐Conotoxins that Inhibit High‐Voltage‐Activated Calcium Channels via GABAB Receptor Activation Reveal a Minimal Functional Motif 下载免费PDF全文
Dr. Bodil B. Carstens Dr. Géza Berecki James T. Daniel Han Siean Lee Kathryn A. V. Jackson Dr. Han‐Shen Tae Dr. Mahsa Sadeghi Dr. Joel Castro Tracy O'Donnell Dr. Annemie Deiteren Prof. Stuart M. Brierley Prof. David J. Craik Prof. David J. Adams Dr. Richard J. Clark 《Angewandte Chemie (International ed. in English)》2016,55(15):4692-4696
α‐Conotoxins are disulfide‐rich peptides that target nicotinic acetylcholine receptors. Recently we identified several α‐conotoxins that also modulate voltage‐gated calcium channels by acting as G protein‐coupled GABAB receptor (GABABR) agonists. These α‐conotoxins are promising drug leads for the treatment of chronic pain. To elucidate the diversity of α‐conotoxins that act through this mechanism, we synthesized and characterized a set of peptides with homology to α‐conotoxins known to inhibit high voltage‐activated calcium channels via GABABR activation. Remarkably, all disulfide isomers of the active α‐conotoxins Pu1.2 and Pn1.2, and the previously studied Vc1.1 showed similar levels of biological activity. Structure determination by NMR spectroscopy helped us identify a simplified biologically active eight residue peptide motif containing a single disulfide bond that is an excellent lead molecule for developing a new generation of analgesic peptide drugs. 相似文献
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Sanati MH Torkaman G Hedayati M Dizaji MM 《Journal of photochemistry and photobiology. B, Biology》2011,103(2):180-185
Injury potential may have a triggering biological role in wound healing. In this study, the effect of photostimulation to promote wound healing and its effect on injury potential was investigated using the Ga-As and He-Ne lasers. In this study, 30 healthy male Sprague-Dawley rats were randomly divided into a control and two laser groups, He-Ne and Ga-As laser. A 2.5 cm craniocaudal full-thickness skin incision was made on each animal's dorsal region. Differential skin surface potential was measured before and immediately after the injury and also up to the 21st day, every other day. Wound surface area was also measured. Immediately after injury, wound potential significantly increased in all three groups. Maximum positive peak of injury potential was greater in Ga-As group compared to He-Ne laser and control groups (P<0.05) and lasting period of maximum positive potential in two laser groups was longer than that in the control group. There were no significant differences between the mean potential of before wounding and after the 15th, 17th, and 19th day in Ga-As, He-Ne, and control group, respectively (P>0.05). On the other hand, Ga-As and He-Ne laser facilitated the normal distribution of skin potential after wounding. These findings demonstrate that Ga-As laser may be more effective on wound closure and on returning the injury potential to normal level than the He-Ne laser. 相似文献
16.
Steffen Reich Patrick Kaiser Mahsa Mafi Holger Schmalz Daniel Rhinow Ruth Freitag Andreas Greiner 《Macromolecular bioscience》2019,19(5)
Living Micrococcus luteus (M. luteus) and Escherichia coli (E. coli) are encapsulated in poly(vinyl alcohol), poly(vinylpyrrolidone), hydroxypropyl cellulose, and gelatin by high‐temperature spray drying. The challenge is the survival of the bacteria during the standard spray‐drying process at temperatures of 150 °C (M. luteus) and 120 °C (E. coli). Raman imaging and transmission electron microscopy indicate encapsulated bacteria in hollow composite microparticles. The versatility of the spray‐dried polymer bacteria microparticles is successfully proved by standard polymer solution–processing techniques such as electrospinning, even with harmful solvents, to water‐insoluble polyacrylonitrile, polystyrene, poly(methyl methacrylate), and poly(vinyl butyrate) nanofiber nonwovens, which opens numerous new opportunities for novel applications. 相似文献
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Seyedeh Mahsa Kamali Ehsan Arbabi Amir Arbabi Yu Horie Andrei Faraon 《Laser \u0026amp; Photonics Reviews》2016,10(6):1002-1008
Dielectric metasurfaces are two‐dimensional structures composed of nano‐scatterers that manipulate the phase and polarization of optical waves with subwavelength spatial resolution, thus enabling ultra‐thin components for free‐space optics. While high performance devices with various functionalities, including some that are difficult to achieve using conventional optical setups have been shown, most demonstrated components have fixed parameters. Here, we demonstrate highly tunable dielectric metasurface devices based on subwavelength thick silicon nano‐posts encapsulated in a thin transparent elastic polymer. As proof of concept, we demonstrate a metasurface microlens operating at 915 nm, with focal distance tuning from 600 μm to 1400 μm (over 952 diopters change in optical power) through radial strain, while maintaining a diffraction limited focus and a focusing efficiency above 50%. The demonstrated tunable metasurface concept is highly versatile for developing ultra‐slim, multi‐functional and tunable optical devices with widespread applications ranging from consumer electronics to medical devices and optical communications.
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Mahsa Yarhosseini Shahrzad Javanshir Zahra Dolatkhah Mohammad G. Dekamin 《Chemistry Central journal》2017,11(1):124
A simple solvent-free protocol for the preparation of flunixin, a potent non-narcotic, non-steroidal anti-inflammatory drugs is reported using boric acid as catalyst. Its salt, flunixin meglumine are then prepared under reflux in EtOH. This sustainable method are then extended for the synthesis of a series of 2-(arylamino) nicotinic acid derivatives. The present protocol combines non-hazardous neat conditions with associated benefits like excellent yield, straightforward workup, and use of readily available and safe catalyst in the absence of any solvent, which are important factors in the pharmaceutical industry. The pathway for catalytic activation of 2-chloronicotic acid with boric acid was also investigated using Gaussian 03 program package.
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