全文获取类型
收费全文 | 344篇 |
免费 | 1篇 |
国内免费 | 1篇 |
专业分类
化学 | 149篇 |
晶体学 | 1篇 |
力学 | 18篇 |
数学 | 37篇 |
物理学 | 141篇 |
出版年
2016年 | 3篇 |
2013年 | 12篇 |
2012年 | 10篇 |
2011年 | 8篇 |
2010年 | 12篇 |
2009年 | 6篇 |
2008年 | 16篇 |
2007年 | 6篇 |
2006年 | 5篇 |
2005年 | 7篇 |
2004年 | 9篇 |
2003年 | 7篇 |
2002年 | 10篇 |
2001年 | 5篇 |
2000年 | 10篇 |
1999年 | 9篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 9篇 |
1995年 | 13篇 |
1994年 | 11篇 |
1993年 | 10篇 |
1992年 | 5篇 |
1991年 | 5篇 |
1989年 | 3篇 |
1988年 | 6篇 |
1987年 | 5篇 |
1985年 | 11篇 |
1984年 | 5篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1977年 | 6篇 |
1976年 | 5篇 |
1975年 | 5篇 |
1974年 | 5篇 |
1966年 | 2篇 |
1920年 | 2篇 |
1910年 | 5篇 |
1909年 | 8篇 |
1908年 | 2篇 |
1907年 | 4篇 |
1906年 | 4篇 |
1905年 | 2篇 |
1904年 | 9篇 |
1900年 | 2篇 |
1892年 | 2篇 |
1888年 | 5篇 |
排序方式: 共有346条查询结果,搜索用时 0 毫秒
11.
12.
MJ Briones R Bol D Sleep L Sampedro D Allen 《Rapid communications in mass spectrometry : RCM》1999,13(13):1300-1304
Changes in the specific diet of earthworms with time in relation to landuse changes and two different climates were studied by analysing (13)C and (15)N natural abundance in soils and animals. Soil samples from three depths (0-10, 10-20 and 20-30 cm) and earthworms were collected from two sites: Santiago (Northwest Spain) and North Wyke (Southwest England) both consisting of replicated long-term grasslands and recently converted to maize plots. Earthworms were hand-sorted in the field at the peak of the maize growth and after harvesting at both sites. In the Spanish plots, nine and eight earthworm species, all belonging to the three ecological categories (epigeic, anecic and endogeic), were found under maize and permanent pasture, whereas at the English site five and seven different species were, respectively, identified. At both sites (13)C isotopic values of the earthworm tissues reflected changes in diet from C(3) to C(4) with epigeic and epi/anecic worms in the maize plots showing one delta unit difference in relation to the ones found in the grassland plots. Anecic worms seemed to be less responsive to landuse changes. The higher (13)C values of the Spanish soils were also reflected in the earthworm tissues when compared with the English samples. (15)N values showed no clear relationship with the cropping treatments but were clearly related to the ecological grouping, with endogeic worms reaching the highest values whereas for the epigeic and epi/anecic species the lowest values were obtained. This finding was also previously recorded by other authors1 and suggests that, in the future, stable isotope techniques could also be a useful tool in taxonomic studies. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
13.
RD Harris WS Baker Van Stipdonk MJ RM Crooks EA Schweikert 《Rapid communications in mass spectrometry : RCM》1999,13(14):1374-1380
A suite of keV polyatomic or 'cluster' projectiles was used to bombard unoxidized and oxidized self-assembled monolayer surfaces. Negative secondary ion yields, collected at the limit of single ion impacts, were measured and compared for both molecular and fragment ions. In contrast to targets that are orders of magnitude thicker than the penetration range of the primary ions, secondary ion yields from polyatomic projectile impacts on self-assembled monolayers show little to no enhancement when compared with monatomic projectiles at the same velocity. This unusual trend is most likely due to the structural arrangement and bonding characteristics of the monolayer molecules with the Au(111). Copyright 1999 John Wiley & Sons, Ltd. 相似文献
14.
Bogert D Burnstein R Fisk R Fuess S Morfin J Ohska Stutte L Walker JK Bofill J Busza W Eldridge T Friedman JI Goodman MC Kendall HW Kostoulas IG Lyons T Magahiz R Mattison T Mukherjee A Osborne L Pitt R Rosenson L Sandacz A Tartaglia M Taylor FE Verdier R Whitaker S Yeh GP Abolins M Brock R Cohen A Ernwein J Owen D Slate J Weerts H 《Physical review letters》1985,55(6):574-577
15.
Osborne TJ 《Physical review letters》2008,101(14):140503
In this Letter we make progress on a long-standing open problem of Aaronson and Ambainis [Theory Comput. 1, 47 (2005)]: we show that if U is a sparse unitary operator with a gap Delta in its spectrum, then there exists an approximate logarithm H of U which is also sparse. The sparsity pattern of H gets more dense as 1/Delta increases. This result can be interpreted as a way to convert between local continuous-time and local discrete-time quantum processes. As an example we show that the discrete-time coined quantum walk can be realized stroboscopically from an approximately local continuous-time quantum walk. 相似文献
16.
CV Tomy D Pal SS Banerjee S Ramakrishnan AK Grover S Bhattacharya MJ Higgins G Balakrishnan McK Paul 《Pramana》2002,58(5-6):925-935
The weakly pinned single crystals of the hexagonal 2H-NbSe2 compound have emerged as prototypes for determining and characterizing the phase boundaries of the possible order-disorder
transformations in the vortex matter. We present here a status report based on the ac and dc magnetization measurements of
the peak effect phenomenon in three crystals of 2H-NbSe2, in which the critical current densities vary over two orders of magnitude. We sketch the generic vortex phase diagram of
a weakly pinned superconductor, which also utilizes theoretical proposals. We also establish the connection between the metastability
effects and pinning. 相似文献
17.
We study the class \({\mathcal{M}}\) of functions meromorphic outside a countable closed set of essential singularities. We show that if a function in \({\mathcal{M}}\), with at least one essential singularity, permutes with a non-constant rational map g, then g is a Möbius map that is not conjugate to an irrational rotation. For a given function \({f \in\mathcal{M}}\) which is not a Möbius map, we show that the set of functions in \({\mathcal{M}}\) that permute with f is countably infinite. Finally, we show that there exist transcendental meromorphic functions \({f : \mathbb{C} \to \mathbb{C}}\) such that, among functions meromorphic in the plane, f permutes only with itself and with the identity map. 相似文献
18.
This paper is concerned with the implementation and testing of an algorithm for solving constrained least-squares problems. The algorithm is an adaptation to the least-squares case of sequential quadratic programming (SQP) trust-region methods for solving general constrained optimization problems. At each iteration, our local quadratic subproblem includes the use of the Gauss–Newton approximation but also encompasses a structured secant approximation along with tests of when to use this approximation. This method has been tested on a selection of standard problems. The results indicate that, for least-squares problems, the approach taken here is a viable alternative to standard general optimization methods such as the Byrd–Omojokun trust-region method and the Powell damped BFGS line search method. 相似文献
19.
Alberti G Brunet E Dionigi C Juanes O de La Mata MJ Rodríguez-Ubis JC Vivani R 《Angewandte Chemie (International ed. in English)》1999,38(22):3351-3353
The hydrophilic oxygen atoms of polyethylenoxide chains inserted as pillars in gamma-zirconium phosphate form hydrogen bonds with the acid groups of the host. As a result the pillars are almost perpendicular to the gamma layers. Upon changing the pH level of the supernatant solution the hydrogen bonds are broken and the pillars become almost perpendicular to the layers (shown schematically). Thus there is a reversible enlargement-shortening of the interlayer space. 相似文献
20.
A.G. Osborne A.J. Blake R.E. Hollands R.F. Bryan S. Lockhart 《Journal of organometallic chemistry》1985,287(1):39-47
A series of [3]ferrocenophanes of general formula Fe(C5H4X)2YCl2 and the spiro compounds [Fe(C5H4X)2]2Ge (X = S, Se; Y = Ge, Sn) have been prepared by the reaction of ferrocene 1,1′-dithiol and ferrocene 1,1′-diselenol with tetrahalides of germanium and tin. Spectroscopic properties of the compounds are reported. In solution, the compounds are fluxional by a bridge reversal process. The crystal structure of 1,3-diselena-2,2-dichlorogermyl-[3]ferrocenophane at 163 K. has been determined by X-ray diffraction methods. At that temperature, crystals have space group P21/n with a 6.222(3), b 16.156(13), c 12.968(4) Å, β 97.53(1)° and Z = 4. Least-squares refinement gave R = 0.033 for 2834 unique significant reflections whose intensities were measured by counter diffractometry. The two SeGe bond lengths are 2.323 and 2.325(1) Å, with GeCl 2.148 and 2.161(1) Å. The SeGeSe bond angle is 118.2(1)°, ClGeCl 104.7(1)°, and SeGeCl angles range from 106.2 to 109.8(1)°. The SeC bond lengths are 1.901 and 1.904(5) Å, with CSeGe angles of 95.8 and 96.5(2)°. The cyclopentadienyl rings are in an eclipsed conformation with a mean twist angle of 2.7°, and are inclined to one another at 6.1°. The Se atoms are displaced from the ring planes by 0.17 and 0.20 Å yielding a non-bonded intramolecular Se…Se contact of 3.99 Å. 相似文献