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901.
D. B. Kayumova Yu. P. Syrnikov N. V. Penkina M. N. Rodnikova 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(10):1634-1635
The structural relaxation time for series of various liquids (alkanes, aliphatic alcohols, and diols) are calculated from published data on the shear viscosity and the heat of evaporation per unit volume. Liquids having a 3D H-bond network (diols) are characterized by relaxation times one to two orders of magnitudes longer than those typical of liquids without such a network (alkanes and aliphatic alcohols). 相似文献
902.
Flávio A. Pavan Yoshitaka Gushikem Celso C. Moro Tania M. Costa Edilson V. Benvenutti 《Colloid and polymer science》2003,281(2):173-177
Anilinepropylsilica xerogel was obtained by using an appropriate organosilane and tetraethyl orthosilicate as precursor reagents. The gelation was carried out using HF and NaF as catalysts. The presence of Na+ (when NaF was used) resulted in a decrease in the final organic content of the materials. This effect was interpreted as an inhibition of the organosilane polycondensation possibly due to the Na+ interaction with the SiO- groups of the hydrolyzed organosilane. The presence of Na+ also results in morphological changes in the xerogels. 相似文献
903.
Thermodynamic fluctuations in systems that are in nonequilibrium steady states are always spatially long ranged, in contrast to fluctuations in thermodynamic equilibrium. In the present paper we consider a fluid subjected to a stationary temperature gradient. Two different physical mechanisms have been identified by which the temperature gradient causes long-ranged fluctuations. One cause is the presence of couplings between fluctuating fields. Secondly, spatial variation of the strength of random forces, resulting from the local version of the fluctuation-dissipation theorem, has also been shown to generate long-ranged fluctuations. We evaluate the contributions to the long-ranged temperature fluctuations due to both mechanisms. While the inhomogeneously correlated Langevin noise does lead to long-ranged fluctuations, in practice, they turn out to be negligible as compared to nonequilibrium temperature fluctuations resulting from the coupling between temperature and velocity fluctuations. 相似文献
904.
We prove some new evaluations for multiple polylogarithms of arbitrary depth. The simplest of our results is a multiple zeta evaluation one order of complexity beyond the well-known Broadhurst–Zagier formula. Other results we provide settle three of the remaining outstanding conjectures of Borwein, Bradley, and Broadhurst. A complete treatment of a certain arbitrary depth class of periodic alternating unit Euler sums is also given. 相似文献
905.
A method of solving the problem of sound radiation from a plate with elements of different thickness in its plane is proposed, and the results obtained with this method are presented. It is shown that the main sources of sound radiation are the inhomogeneous flexural fields formed in the elements on both sides of their joint. 相似文献
906.
Modification of Paving Asphalts with Sulfur 总被引:2,自引:0,他引:2
Syroezhko A. M. Begak O. Yu. Fedorov V. V. Gusarova E. N. 《Russian Journal of Applied Chemistry》2003,76(3):491-496
Sulfur dissolved in oil components of asphalt is a binder, filler, and chemical co-reagent at once. The structure of sulfur-extended asphalt depends on its formula and heating temperature. Road pavement based on sulfur-extended asphalt demonstrates higher durability as compared to that with the conventional binders. 相似文献
907.
Amplitude equations, as well as the effective dispersion and nonlinearity parameters, which define the dynamics of a wave
packet formed by two strongly coupled modes, are derived with allowance for the frequency dependence of the linear mode coupling
coefficient. These equations are used to study the onset of the modulation instability of the two-mode wave packet, soliton-like
pulses, and compression modes. Unlike single-mode systems, the last two effects in optical waveguides may arise for both a
negative and positive disper-sion of the waveguide material. 相似文献
908.
G. Lujanienë 《Czechoslovak Journal of Physics》2003,53(1):A57-A65
In order to understand better the way in which radioactive contamination may be transferred from the atmosphere to other ecological compartments it is necessary to obtain information of the deposition mechanisms of radionuclides. Concentration and speciation of 137Cs and 7Be in the atmospheric aerosol and deposition were studied. The mixed deposition velocities of water-soluble and insoluble 137Cs and 7Be were determined. The relation between activity concentrations of insoluble 7Be in the atmosphere and its amount in deposition was observed. It is supposed that in the deposition process of radiocesium the precipitation plays an important role in scavenging of water-soluble radiocesium by falling raindrops, in contrast to insoluble 137Cs where the dry deposition becomes predominant. 相似文献
909.
The method of nonlinear moments, when used to solve the Boltzmann equation, necessitates the calculation of collision integral
matrix elements. The matrix elements are hard to calculate numerically, especially at large indices. The asymptotics of the
matrix elements are constructed. In terms of the model of pseudopower particle interaction, a formula free of summation is
derived. This makes it possible to find the asymptotic behavior of linear and nonlinear elements when two indices are large.
For an arbitrary interaction cross section, asymptotic expansions of linear and nonlinear matrix elements in one index are
obtained. For Maxwellian molecules, asymptotic formulas are derived for three large indices. 相似文献
910.
O. V. Sizova E. P. Sokolova V. I. Baranovskii D. A. Rozmanov O. A. Tomashenko 《Journal of Structural Chemistry》2004,45(5):762-770
Ab initio MP2 calculations with several basis sets proved the existence of a stable benzonitrile dimer with a planar structure and a short contact between the H atom of one molecule and the N atom of another. The structure is greatly stabilized by attraction between the neighboring oppositely directed dipoles and donor-acceptor interaction between the orbital of the lone electron pair of the N′ atom and the vacant antibonding orbital localized on the C-H bond.Original Russian Text Copyright © 2004 by O. V. Sizova, E. P. Sokolova, V. I. Baranovskii, D. A. Rozmanov, and O. A. Tomashenko__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 807–815, September–October, 2004. 相似文献