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991.
Jonathan M. Borwein 《Optimization Letters》2007,1(1):21-32
This paper is a companion to a lecture given at the Prague Spring School in Analysis in April 2006. It highlights four distinct variational methods of proving that a finite dimensional Chebyshev set is convex and hopes to inspire renewed work on the open question of whether every Chebyshev set in Hilbert space is convex. 相似文献
992.
A. A. Solov’ev M. A. Pashina O. E. Lebedeva 《Russian Journal of Applied Chemistry》2007,80(2):275-278
The influence of inorganic salts on the kinetics of oxidation of 2,4-and 2,6-dinitrophenols by Fenton’s reagent, hydrogen peroxide, in the presence of iron(II) ions was studied. 相似文献
993.
994.
L. V. Giurgiu M. N. Grecu X. Filip O. Raita Al. Darabont D. Gavre J. Blasco 《Applied magnetic resonance》2003,24(3-4):351-360
We report an electron paramagnetic resonance (EPR) investigation of the spin dynamics in the paramagnetic regime of the colossal magnetoresistive manganites La2/3Ca1/3Mn1?x Me x O3 (Me=Al, In;x≤0.05). The temperature dependences of the EPR linewidth and integral intensity have been analyzed in terms of the bottleneck spin relaxation and small-polaron hopping models. The exchange coupling integral between Mn3+ and Mn4+ ions and the polaron activation energy decrease with increasing doping level. A discussion is given concerning the factors which could explain the observed changes. 相似文献
995.
Translated from Matematicheskie Zametki, Vol. 49, No. 5, pp. 37–44, May, 1991. 相似文献
996.
E. Beinrohr M. Németh P. Tsch?pel G. T?lg 《Fresenius' Journal of Analytical Chemistry》1992,344(3):93-99
Summary Flow-through electrochemical cells with porous working electrodes made of crushed reticulated vitreous carbon and plated with mercury were used for absolute analysis of trace amounts of lead by anodic stripping coulometry with collection (ASCWC) in a flow system. The role of mercury coating, flow rate and pH were investigated. The coulombic content of the collection peak corresponded to the theoretical values calculated by Faraday's law in a concentration range from about 10–9 to 10–6 mol/l. The relative error and the relative standard deviation was +0.15% and 0.8%, respectively for 2×10–6 mol/l analyte concentration. The absolute detection limit (3 s) was 0.1 ng of Pb, the linear response range 7×104.
One leave from: Department of Analytical Chemistry, Slovak Technical University, CS-812 37 Bratislava, Czechoslovakia 相似文献
997.
G M Beijersbergen van Henegouwen 《Journal of photochemistry and photobiology. B, Biology》1991,10(3):183-210
Xenobiotics extensively used in drugs, cosmetics, food and agricultural chemicals can produce adverse biological effects. These toxic effects are separated into classes, e.g. hepatotoxicity, genotoxicity and neurotoxicity. Skin allergy, part of immunotoxicity, is also a subdivision of toxicology. When light is an essential condition for toxicity, the xenobiotic is called phototoxic. Thus it fits into the logic of toxicology that photoallergic compounds are a subdivision of phototoxic compounds. Phototoxicons as a group do not differ from the group of phototherapeutics with regard to their eventual biological effects. The primary photoreactions, secondary molecular processes, biomolecules involved and cellular and tissue damage are similar. The difference between the two groups is in the appreciation of the photobiological effects: adverse vs. desired. The aim of research is to determine the part of the molecular structure which makes a given compound phototoxic. With that knowledge the structure of the phototoxicon can be changed. This can result in a derivative which still has the desired properties of the parent compound, but is no longer phototoxic. This aim can be reached by combining data from both in vitro and in vivo research. The variety and number of phototoxic compounds is large. This, together with the limited research effort devoted to this subject so far, means that for most phototoxic xenobiotics a relationship between structure and in vivo photoreactivity is not available. In this review, emphasis is placed on xenobiotics whose in vitro and in vivo photochemistry have been studied. Furthermore, possible phototoxic effects which do not concern the skin but involve inner organs (systemic effects) are considered. References in this review mostly concern investigations over the last 10 years. For older literature or for additional information, references to other reviews are given. Important groups of phototoxic xenobiotics not dealt with in this article were already sufficiently covered in the reviews referred to. 相似文献
998.
999.
1000.
E. S. Moskalenko M. Larsson K. F. Karlsson P. O. Holtz B. Monemar W. V. Schoenfeld P. M. Petroff 《Physics of the Solid State》2007,49(10):1995-1998
We report on low-temperature microphotoluminescence (μ-PL) measurements of InAs/GaAs quantum dots (QDs) exposed to a lateral
external electric field. It is demonstrated that the QDs’ PL signal could be increased severalfold by altering the external
and/or the internal electric field, which could be changed by an additional infrared laser. A model which accounts for a substantially
faster lateral transport of the photoexcited carriers achieved in an external electric field is employed to explain the observed
effects. The results obtained suggest that the lateral electric fields play a major role for the dot luminescence intensity
measured in our experiment—a finding which could be used to tailor the properties of QD-based optoelectronic applications.
The text was submitted by the authors in English. 相似文献