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141.
本文将基本的谱编辑脉冲序列与消旋转边带的TOSS脉冲序列联用,可以实现强磁场下13C CP/MAS谱编辑.通常,固体中非质子化碳与甲基碳的自旋晶格弛豫时间差别很大,此差别可作为谱编辑过程中区分它们的一条附加判据.对具有复杂分子结构的体系,此判据的作用尤其重要.文中的实例将表明:一个完整的13C CP/MAS谱编辑一般可通过SCPTOSS谱(短接触时间交叉极化谱);SCPPITOSS (短接触时间交叉极化极化反转)谱,LCPDTOSS (长接触时间交叉极化及去极化)谱及部分弛豫的LCPDTOSS谱适当组合而得到. 相似文献
142.
模压全息图母版的拍摄研究 总被引:3,自引:1,他引:2
目前拍摄模压全息母版用的记录材料都是光刻胶.本文从它本身的特点(灵敏度低,浮雕型相位光栅和拍摄对象是散射物体等)出发,指出要拍摄出质量好的光刻胶母版应当注意到的问题.诸如拍摄参数的选择应同时考虑到衍射效率和信噪比、照明的均匀性问题、逆共轭光再现、消偏振、相干长度、外界振动对拍摄的影响问题.通过分析表明高质量的全息图不可能靠延长曝光时间来获得,使用相干性好的大功率激光束来拍摄,是非常有必要的. 相似文献
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Recognition imaging microscopy is an analytical technique used to map the topography and chemical identity of specific protein molecules present in complex biological samples. The technique relies on the use of antibodies tethered to the cantilever tip of an AFM probe to detect cognate antigens deposited onto a mica surface. Despite the power of this technique to resolve single molecules with nanometer-scale spacing, the recognition step remains limited by the availability of suitable quality antibodies. Here we report the in vitro selection and recognition imaging of anti-histone H4 aptamers. In addition to identifying aptamers to highly basic proteins, these results suggest that aptamers provide an efficient, cost-effective route to highly selective affinity reagents for recognition imaging microscopy. 相似文献
147.
压实粉土非线性应力-应变关系的试验研究 总被引:1,自引:0,他引:1
对京九线路基粉土用GDS三轴仪进行固结不排水剪试验,研究不同围压、含水量、压实度下压实粉土样的应力-应变关系。结果表明:压实粉土在低围压下为应变软化,高围压下为应变硬化,存在一个屈服应力;含水量和压实度对粉土强度和应力-应变关系影响显著,随着含水量的减小、压实度的增大,压实粉土样强度增大,应力-应变曲线上升。对围压小于屈服应力的应变软化曲线,用常规的土的软化关系式进行拟和;对围压大于屈服应力的应变硬化曲线,用邓肯-张模型进行拟和;这二者的结合能描述压实粉土的应力-应变关系曲线,效果良好。 相似文献
148.
Cucurbit(6)uril immobilized on silica: A novel high‐performance liquid chromatographic stationary phase
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In the present study, one of the new generation of host molecules, cucurbit(6)uril (CB(6)), was immobilized onto silica (CB(6)/SiO2) by a sol–gel approach. CB(6)/SiO2 was characterized by NMR spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis, and elemental analysis. It was used as a high‐performance liquid chromatographic stationary phase and its chromatographic performance was systematically investigated with different types of analytes as probes. The results revealed that the CB(6)/SiO2 stationary phase exhibited weak hydrophobic and strong hydrophilic properties. Hence, the variables for hydrophilic interaction liquid chromatography, including components and pH of the mobile phase, were further investigated to explore the retention mechanism of this CB(6)/SiO2 stationary phase. For less polar analytes, both hydrophobic and hydrophilic interactions could contribute to the retention, while for polar analytes, hydrophilic interaction may be predominant. Compared to the tetraethoxylsilane‐coated SiO2 stationary phases, the CB(6)/SiO2 stationary phase exhibited a different retention behavior toward basic analytes with excellent stability. It is a novel promising hydrophilic interaction liquid chromatography stationary phase. 相似文献
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Xiaowei Lv Jianling Zhao Xixin Wang Xingru Xu Liyun Bai Buxue Wang 《Journal of Solid State Electrochemistry》2013,17(4):1215-1219
Novel bismuth oxide (Bi2O3) nanoporous films were fabricated through anodization of bismuth foil in electrolytes containing glycol, ammonium sulfate ((NH4)2SO4) and deionized (DI) water. Scanning electron microscopy analysis indicated that morphology of the anodized bismuth foil changed markedly along with the changing of oxidation time, water content, electrolyte concentration, temperature, and applied voltages. The optimized morphology was obtained when bismuth was anodized at 20 V, 40 °C for 40 min in glycol solution containing 0.3 wt% (NH4)2SO4 and 5 wt% DI water. The composition and crystal structure of the samples formed in the optimized conditions were characterized by energy-dispersive spectroscopy and X-ray diffraction. Results showed that the as-prepared nanoporous structures were amorphous. β-Bi2O3 was obtained when the samples were annealed at 200 °C. The photocurrent response experiments demonstrated that the Bi2O3 nanoporous film can generate photocurrent as large as 2.893 and 6.980 μA/cm2 under 0 and 0.5 V bias voltage versus saturated calomel electrode, respectively. 相似文献