Surface states and its influence on luminescence in ZnS nanocrystallite

In this pape,r the influence of surface effects on the self-activated (SA) luminescence in ZnS nanoparticles prepared by the wet-chemical method is presented. It is observed that the luminescence of SA decreases dramatically by rinsing with methanol. In the rinsed sample, the luminescence of SA increases more by ultraviolet (UV) light irradiation. To clarify its origin, the Raman spectra and electron paramagnetic resonance (EPR) are studied. The results demonstrate that the vibrational modes assigned to organic functional groups of -OH and -COO and -CH₃ decreases remarkably by rinsing, while the EPR signal originated from the unpaired electrons of some transition metal impurity ions including Mn²⁺ increases. It is suggested that the SA centers prefer to occupy the sites near the surface and that the donor of SA emission may be partly related to the organic functional groups of -OH and -COO adsorbed on the surface. The surface-dangling bonds caused by unpaired electrons of some transition metal impurity ions play a role of surface states, leading to the quenching of the SA emissions. The organic functional groups chemically combine with these surface-dangling bonds leading to the decrease in surface states and surface nonradiative relaxation channels and to the increase in the SA emissions.     

I.I.D.随机变量序列矩完全收敛的精确渐近性

{X,Xn;n≥1}为独立同分布的随机变量序列, EX=0,01 p/2满足E|X|r<∞,且E|X|3<∞,那么其中Z服从均值为0,方差为σ2的正态分布.     

空间相机光学窗口的热光学评价

光学窗口是空间相机光学系统中直接暴露在轨道热真空环境中的光学元件，所处的热环境非常复杂，要产生温度梯度，从而对空间相机的成像质量和分辨率产生影响，文中结合工程实际，以光学波像差的基本理论为基础对空间相机光学窗口的非轴地称温度场进行了热光学评价，编程计算了空间相机光学窗口在一个轨道周期内各典型位置处的均方波像差，并把计算结果与美国“天空实验室”光学窗口的相应数据进行比较，以验证本文热光学分析的合理性     

生物无毒性高分子膜的紫外光透过性能研究

本文对PVA、PAN等几种高分子膜的紫外光透过性能进行了实验研究,为高分子膜在生物领域找到了新的应用,在选择透紫外光膜时,一方面要考虑高分子的分子结构,另一方面要考虑膜孔、膜厚等膜结构参数。     

2,5─哌嗪二酮与α,β─不饱和醛反应研究

综合运用了多种波谱学方法及化学手段确证并归属了2,5-哌嗪二酮与α,β-不饱和醛在超声波分散金属钾及双季铵盐作用下反应产物的立体化学与核磁共振信号,为研究这个反应提供了有用的信息.     

Review of two-phase flow and flow boiling of mixtures in small and mini channels

Two-phase flow and flow boiling phenomena of fluidic mixtures in small and mini channels are becoming important in the miniaturization of thermal systems. This paper aims to present a state-of-the-art review in this important area and to identify what have been done so far and what still need to be done in the future. Firstly, various definitions of small and mini channels are described and the criteria based on these definitions are compared with each other. Comments on different viewpoints of the channel size classifications are acknowledged. Secondly, the background of two-phase flow and flow boiling of mixtures is described. Then, the current research status of two-phase flow and flow boiling of mixtures in normal size channels is presented as it is a basis for the study of two-phase flow and flow boiling of mixtures in small and mini channels. Finally, an overall review of two-phase flow and flow boiling of mixtures in small and mini channels is presented. It is concluded that the available study of two-phase flow and flow boiling of mixtures in small and mini channels is rather scarce and a systematic knowledge of two-phase flow and flow boiling of mixtures in small and mini channels is required. Based on this review, the future research directions including both fundamental and applied research in this area have been indicated.     

外显子拼接法合成真菌灵芝漆酶基因cDNA

为真菌漆酶基因cDNA的克隆提供了一种简便快速的新方法．从含有内含子的灵芝漆酶基因出发，采用外显子拼接PCR方法，合成了灵芝漆酶的cDNA．设计了10对引物分别经PCR扩增该基因的10个外显子，引物设计使前一个外显子的下游引物与下一个外显子的上游引物都有一段同源匹配序列，然后通过两两片段混合作为模板PCR扩增得到两两拼接的外显子片段，再将得到的5个片段前两个混合，后3个混合分别作为模板扩增获得拼接好的外显子1～4大片段和外显子5～10大片段，最后将这两个大片段混合作为模板扩增得到拼接好的全长cDNA序列．与常规方法相比，该方法既避免了RNA的操作，又不用摸索酶表达的条件，可以和基因组步行技术结合快速获得真菌漆酶基因的cDNA．     

Rosenthal type inequalities forB-valued strong mixing random fields and their applications

Some inequalities for moments of partial sums of aB -valued strong mixing field are established and their applications to the weak and strong laws of large numbers and the complete convergences are discussed. Project supported by the National Natural Science Foundation of China (Grant No. 19701011) and China Postdoctoral Science Foundation.     

一类拟线性双曲型方程组混合初-边值问题的半整体C~1解

本文证明了具零特征且形式更广泛的一类拟线性双曲型方程组的具有一般非线性边界条件的混合初 一边值问题半整体C1解的存在唯一性.     

A STRONG OPTIMIZATION THEOREM IN LOCALLY CONVEX SPACES

This paper presents a geometric characterization of convex sets in locally convex spaces on which a strong optimization theorem of the Stegall-type holds, and gives Collier's theorem of w Asplund spaces a localized setting.