Generalized holographic and Ricci dark energy models

In this paper, we consider generalized holographic and Ricci dark energy models where the energy densities are given as ρ _R =3c ² M _pl² Rf(H ²/R) and ρ _h =3c ² M _pl² H ² g(R/H ²), respectively; here f(x), g(y) are positive defined functions of the dimensionless variables H ²/R or R/H ². It is interesting that holographic and Ricci dark energy densities are recovered or recovered interchangeably when the function f(x)=g(y)≡1 or f(x)=Id and g(y)=Id are taken, respectively (for example f(x),g(x)=1−ε(1−x), ε=0or1, respectively). Also, when f(x)≡xg(1/x) is taken, the Ricci and holographic dark energy models are equivalent to a generalized one. When the simple forms f(x)=1−ε(1−x) and g(y)=1−η(1−y) are taken as examples, by using current cosmic observational data, generalized dark energy models are considered. As expected, in these cases, the results show that they are equivalent (ε=1−η=1.312), and Ricci-like dark energy is more favored relative to the holographic one where the Hubble horizon was taken as an IR cut-off. And the suggested combination of holographic and Ricci dark energy components would be 1.312R−0.312H ², which is 2.312H²+1.312[(H)\dot]2.312H^{2}+1.312\dot{H} in terms of H ² and [(H)\dot]\dot{H} .     

基于倏逝波的光纤生物传感器研究

构建了一种以光纤束作为激发光信号和荧光信号传输通道的光纤生物传感器结构.根据光纤探针的倏逝波理论和模式匹配理论对光纤探针的几何形状进行了设计,制作了数组光纤探针并根据需要对其中一部分进行荧光标记.选择了光纤探针置于空气中和水溶液中两种情况,对光纤传感器系统进行了信号检测实验,对比标记了的和未标记的相同几何结构参数的光纤探针两者在系统中被探测的信号差异.从二者的差别区分出系统所探测的倏逝波激发的荧光信号,证明了该光纤传感器系统的可行性.     

注汽油井蒸气汽液比的折射率法测量研究

给油田的油井中注入高温高压蒸气时,从井口到井底连续地查明汽液比对节省能源和提高产出率意义重大。由于干蒸气和水的折射率不同,汽液的比例可以从汽液两相流的折射率响应特性反映出来。研制的测量装置采用蓝宝石作为折射率敏感的探测头,直接对汽液两相流的比例变化产生响应,能够应用于高温高压及狭窄工作空间的输汽环境中。装置在锅炉输汽管道中的实测响应曲线反映了输汽过程中汽液比的真实变化。该装置还在井深800m,井口蒸气温度270℃、压力10Mpa的油田注汽井中进行测量,测得的结果对注汽法采油的井况分析具有一定的作用。     

Rubidium bis­(tri­fluoro­methane­sulfonyl)­imidate dioxane disolvate

The bis­(tri­fluoro­methane­sulfonyl)­imidate anion crystallizes with Rb as the title dioxane 1:2 solvate, Rb⁺·CF₃SO₂NSO₂CF₃⁻·2C₄H₈O₂, with the anion in a transoid conformation, as opposed to the cisoid form typically seen when there are significant cation–anion interactions. The Rb^I cation is eight‐coordinate, interacting with one anion in a chelating fashion and with two other anions through the remaining sulfonyl O atoms. The latter interactions link ion pairs through the formation of Rb₂O₂ dimers about inversion centers at (0, , 0) and (, , 0), forming extended columns which run parallel to the a axis of the unit cell. Rb–dioxane bridges crosslink these salt columns in the (010), (001) and (011) directions, resulting in a three‐dimensional network solid. One dioxane solvent mol­ecule is disordered over two half‐occupancy sites.     

细乳液聚合制备载有CdTe的交联聚苯乙烯荧光微球

利用改进的正相细乳液聚合法, 对疏水的CdTe纳米晶进行包覆, 得到了纳米级的交联聚苯乙烯荧光微球. 研究发现, 较高的引发剂浓度和较高的交联度有利于抑制相分离的发生和荧光的保持. 进而将3-甲基丙烯酰氧基丙基三甲氧基硅烷作为共聚单体, 得到了表面硅羟基功能化的聚苯乙烯荧光微球, 改善了微球在水相中的分散性, 并将此类荧光功能微球成功用于细胞成像.     

Synthesis and characterization of the water-soluble silica-coated ZnS:Mn nanoparticles as fluorescent sensor for Cu ions

Silica-coated ZnS:Mn nanoparticles were synthesized by coating hydrophobic ZnS:Mn nanoparticles with silica shell through microemulsion. The core–shell structural nanoparticles were confirmed by X-ray diffraction (XRD) patterns, high-resolution transmission electron microscope (HRTEM) images and energy dispersive spectroscopy (EDS) measurements. Results show that each core–shell nanoparticle contains single ZnS:Mn nanoparticle within monodisperse silica nanospheres (40 nm). Photoluminescence (PL) spectroscopy and UV–vis spectrum were used to investigate the optical properties of the nanoparticles. Compared to uncoated ZnS:Mn nanoparticles, the silica-coated ZnS:Mn nanoparticles have the improved PL intensity as well as good photostability. The obtained silica-coated ZnS:Mn nanoparticles are water-soluble and have fluorescence sensitivity to Cu²⁺ ions. Quenching of fluorescence intensity of the silica-coated nanoparticles allows the detection of Cu²⁺ concentrations as low as 7.3 × 10⁻⁹ mol L⁻¹, thus affording a very sensitive detection system for this chemical species. The possible quenching mechanism is discussed.     

Chiral ruthenium-SDPs/diamine complexes-catalyzed enantioselective hydrogenation of α-alkyl arylacetones via dynamic kinetic resolution

The asymmetric hydrogenation of the conformationally flexible racemic α-substituted acyclic dialkyl ketones via dynamic kinetic resolution (DKR) has been developed by using Ru-SDPs/diamine catalysts. Chiral alcohols were produced in high yields with good to excellent enantioselectivities (85%–97% ee) and diastereoselectivities (up to 97:3). This hydrogenation reaction provided a new approach to the synthesis of the key intermediate of J-104118.     

The global attractor of the viscous Fornberg–Whitham equation

This paper aims to present a proof of the existence of the attractor for the one-dimensional viscous Fornberg–Whitham equation. In this paper, the global existence of solution to the viscous Fornberg–Whitham equation in L² under the periodic boundary conditions is studied. By using the time estimate of the Fornberg–Whitham equation, we get the compact and bounded absorbing set and the existence of the global attractor for the viscous Fornberg–Whitham equation.     

A note on non-support points, negligible sets, Gâteaux differentiability and Lipschitz embeddings

This paper first presents a characterization of three classes of negligible closed convex sets (i.e., Gauss null sets, Aronszajn null sets and cube null sets) in terms of non-support points; then gives a generalization of Gâteaux differentiability theorems of Lipschitz mapping from open sets to those closed convex sets admitting non-support points; and as their application, finally shows that a closed convex set in a separable Banach space X can be Lipschitz embedded into a Banach space Y with the Radon–Nikodym property if and only if the closure of its linear span is linearly isomorphic to a closed subspace of Y.