青蒿素抗疟机理研究最近的重要进展

１．论文名称ＵｎｉｆｉｅｄＭｅｃｈａｎｉｓｔｉｃＦｒａｍｅｗｏｒｋｆｏｒｔｈｅＦｅ（Ｉ）－ＩｎｄｕｃｅｄＣｌｅａｖａｇｅｏｆＱｉｎｇｈａｏｓｕａｎｄＤｅｒｉｖａｔｉｖｅｓ／Ａｎａｌｏｇｕｅｓ．ＴｈｅＦｉｒｓｔＳｐｉｎ－ＴｒａｐｐｉｎｇＥｖｉｄｅｎｃｅ...     

扫描近场光学显微镜光纤锥中导波反射特性

利用局部模耦合模型理论上分析了扫描近场光学显微镜光纤的光场性质,给出光纤维中存在的正,反向传播的基模场微分方程,以及基模反向耦合系数的数值计算结果,其最高反射系数达１％左右。这种反射光可起着光纤维激光器谐振腔输出端镜的作用。     

Fractal Characteristics Investigation on Light Scattering from Two Dimensional Rough Surface

A normalized two dimensional band-limited Weierstrass fractal function is used for modeling the rough surface. Based on Kirchhoff theory, an analytic solution of the average scattering field and the variance of scattering intensity are derived with emphasis on examining the relation of fractal dimension with the scattering pattern. The important conclusion is obtained that the diffracted envelope slopes of scattering pattern can be approximated to a slope of linear equation.     

粗锌中镉的测定方法研究

样品用硝酸-盐酸分解,采用扣除背景的方式消除高含量的锌对低含量镉测定的影响。优化了镉测定的仪器条件,建立了粗锌中镉含量的测定方法。用于测定粗锌中镉,结果的相对标准偏差(RSD,n=11)为0.95%～6.3%。按照实验方法对粗锌样品进行加标回收实验,加标回收率为98.0%～102%。与ICP-AES法测定结果基本一致,能满足日常对粗锌中镉含量的测定要求。     

电感耦合等离子体原子发射光谱法(ICP-AES)测定铅锌混合精矿中的Cu，Cd，Fe，As，Ag，Al 6种元素

建立了电感耦合等离子体原子发射光谱法(ICP-AES)测定铅锌混合精矿中6种元素的定量分析方法。通过实验选择324.754,228.802,259.940,193.696,328.068,396.152nm分别作为Cu,Cd,Fe,As,Ag,Al的分析谱线,方法的检出限均小于0.010μg/mL。对铅锌矿标准样品进行分析,测定结果与标准值基本一致。方法的回收率在96%~104%,精密度实验结果表明,相对标准偏差(RSD,n=6)均小于4%,能满足日常分析对铅锌混合精矿中杂质元素的检测要求。     

A High‐Efficiency All‐Fiber Laser Operated in High‐Order Mode using Ring‐Core Yb‐Doped Fiber

An all‐fiber laser generating a cylindrical vector beam is proposed and demonstrated using a home‐made ring‐core Yb‐doped fiber (RC‐YDF). In the RC‐YDF, not only annular doping but also ring‐type beam pump is realized. This is believed to be the first report describing the realization of annular doping and ring‐type beam pump in active fiber simultaneously, which can enhance the efficiency for high‐order mode oscillation. This laser operates in the high‐order mode stably with a slope efficiency of as high as 55.7%. Cylindrical vector modes can be obtained easily through adjusting the polarization controller. This work may have great potential for providing high‐efficiency and high‐power cylindrical vector beam and vortex beam sources.     

Synthesis of NaxMoO3 crystals through high pressure solid-state reaction

We report growth of high-purity single crystals of the sodium molybdenum bronzes Na_xMoO₃ through high pressure solid-state reaction routes. Our results demonstrate that the crystallite sizes of Na_xMoO₃ can rapidly grow to ～25?μm under a moderate pressure of 4.0?GPa in just 10?min. This discovery provides a starting point for the growth of large single crystals of alkali metal molybdenum bronzes under high pressure.     

Ullmann反应百年纪念及近期复兴——兼及碳-杂原子键的形成

1901年Ullmann报道了一个形成sp²C-C键的偶联反应,1903年报道了苯胺的N-芳基化反应,1905年又报道了苯酚的O-芳基化的缩合反应。这些经典的反应进入催化领域且范围又有扩展,但由于反应条件苛刻等缺点,也限制了反应的应用。20世纪末,在多位科学家的努力下,发现具有一定结构的化合物--配体,对于铜催化的Ullmann缩合反应（或交叉偶联反应）具有配体加速催化反应（LAC）的效果,于是引发了对这一反应的研究热潮。本文对于各种配体的选用,特别是草酰二胺类,对于无机碱,特别是有机离子性碱的选用以及铜源、配体的负载化、溶剂的考量和绿色化等方面进行了较为详细的讨论。鉴于在2004年已有单篇论文提出了Ullmann反应的复兴,Beletskaya则提出了精辟的问题：这就是复兴吗?在金属催化的交叉偶联反应中,铜催化是否已成为钯催化的有力竞争者?Beletskaya在历数了铜催化的优点之后,也深刻地列出了铜催化的五大不足之处。经过了十余年众多化学家的成功发展,本文对此给出了明确的回答。     

Optimal system,group invariant solutions and conservation laws of the CGKP equation

In this paper, the (2 + 1)-dimensional cubic generalized Kadomtsev–Petviashvili (CGKP) equation that is derived from the Maxwell–Bloch equations is investigated. By means of Lie symmetry analysis method, we obtain the Lie point symmetries for the equation and the optimal system of the symmetry algebra. Based on the optimal system, a lot of group invariant solutions are obtained. In addition, explicit conservation laws of the equation are studied.     

Cluster synchronization of overlapping uncertain complex networks with time-varying impulse disturbances

Nonlinear Dynamics - This paper addresses the scheme of cluster synchronization of overlapping uncertain complex networks with time-varying impulse disturbances. Many existing works on cluster...