江苏-西部能源需求-供给模型及其动力学分析

根据江苏省能源需求与西部能源供给及江苏省能源进口量之间相互支持、相互制约的复杂关系建立了江苏-西部能源需求-供给系统．分析了系统的稳态、周期、分叉、混沌等若干动力学行为．通过调节参数可以使系统处于稳定发展或周期震荡区域中．基于Silnikov定理,应用待定系数法,求出了能源系统的同宿轨的表达式．证明了在两个平衡点处均有Silnikov型的同宿轨．根据Silnikov定理确保了能源系统有Smale马蹄和马蹄形混沌．     

A solvent-controlled highly efficient Pd-C catalyzed hydrogenolysis of benzaldehydes to methylbenzenes via a novel ‘acetal pathway’

Pd-C catalyzed hydrogenolysis of benzaldehydes to methylbenzenes has been described to proceed via a ‘benzenemethanol pathway’. In this article, a novel ‘acetal pathway’ was first revealed by a systematic study when lower alcohols were used as solvents and a solvent-controlled highly efficient procedure was established.     

等离子体喷涂层的正电子湮没研究

本文用正电子湮没技术对等离子体喷涂铜基合金压缩形变的微观缺陷进行了测量。对等离子体喷涂合金，随着压缩量的增加，正电子寿命变短，这一现象与常规合金中观察到的情况相反。     

Strontium‐based initiator system for ring‐opening polymerization of cyclic esters

An amino isopropoxyl strontium (Sr‐PO) initiator, which was prepared by the reaction of propylene oxide with liquid strontium ammoniate solution, was used to carry out the ring‐opening polymerization (ROP) of cyclic esters to obtain aliphatic polyesters, such as poly(ε‐caprolactone) (PCL) and poly(L ‐lactide) (PLLA). The Sr‐PO initiator demonstrated an effective initiating activity for the ROP of ε‐caprolactone (ε‐CL) and L‐lactide (LLA) under mild conditions and adjusted the molecular weight by the ratio of monomer to Sr‐PO initiator. Block copolymer PCL‐b‐PLLA was prepared by sequential polymerization of ε‐CL and LLA, which was demonstrated by ¹H NMR, ¹³C NMR, and gel permeation chromatography. The chemical structure of Sr‐PO initiator was confirmed by elemental analysis of Sr and N, ¹H NMR analysis of the end groups in ε‐CL oligomer, and Fourier transform infrared (FTIR) spectroscopy. The end groups of PCL were hydroxyl and isopropoxycarbonyl, and FTIR spectroscopy showed the coordination between Sr‐PO initiator and model monomer γ‐butyrolactone. These experimental facts indicated that the ROP of cyclic esters followed a coordination‐insertion mechanism, and cyclic esters exclusively inserted into the Sr–O bond. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1934–1941, 2003     

关于Banach空间光滑性的两点注记

In this paper, We show that a real or complex Banach space is smooth at x₀(∈S(X)) iff, for any y∈S(X).(?)where X_x0,y= span {x₀, y} . For a real Banach space X, we obtain that X is F-differentia ble at x₀(∈S(X)) iff (?) Remark. The sufficient conditions of the conclusion have been proved by Yu Xintai [2].     

Self-modulated highly chemoselective direct-reductive-amination (DRA) of benzaldehydes straightforward to N-monosubstituted benzylamine hydrochlorides

An unprecedented efficient and chemoselective DRA of benzaldehydes and primary amines was developed to directly yield N-monosubstituted benzylamine hydrochlorides as single products in practically quantitative yields. The method was characterized by simply adding a few milliliters of CHCl₃ in the conventional Pd-C catalytic hydrogenation system at atmospheric pressure and room temperature. A self-modulated system and a four-stage cyclic pathway were proposed.     

流动注射分光光度系统中基体的折射率梯度响应与其浓度之间的关系

本文系统研究了氯化钠溶液作为样品基体时在流动注射分光光度系统中的折射率梯度响应现象，揭示了基体分别在低浓度和高浓度时，其折射率梯度响应曲线随浓度的变化规律，初步探讨了响应机理。本文得出的结论有助于全面了解当样品中的基体在不同浓度时，基体的折射率梯度响应对样品分光光度测定的干扰情况。     

Blocking analysis andT(1) theorem

TheT(1) theorem with a weak condition on the distribution kernel is proved by using a new method—blocking analysis. It improves a result of Meyer’s. Project supported by the National Natural Science Foundation of China (Grant No. 19631080) and the Foundation of Advanced Research Center, Zhongshan University.     

ON THE PRODUCT OF GTEAUX DIFFERENTIABILITY LOCALLY CONVEX SPACES

A locally convex space is said to be a Gateaux differentiability space (GDS) provided every continuous convex function defined on a nonempty convex open subset D of the space is densely Gateaux differentiable in .D.This paper shows that the product of a GDS and a family of separable Prechet spaces is a GDS,and that the product of a GDS and an arbitrary locally convex space endowed with the weak topology is a GDS.