全文获取类型
收费全文 | 127420篇 |
免费 | 20317篇 |
国内免费 | 12770篇 |
专业分类
化学 | 87559篇 |
晶体学 | 1518篇 |
力学 | 8038篇 |
综合类 | 743篇 |
数学 | 15148篇 |
物理学 | 47501篇 |
出版年
2024年 | 277篇 |
2023年 | 2358篇 |
2022年 | 4143篇 |
2021年 | 4238篇 |
2020年 | 4828篇 |
2019年 | 4686篇 |
2018年 | 4021篇 |
2017年 | 3755篇 |
2016年 | 5832篇 |
2015年 | 5557篇 |
2014年 | 6798篇 |
2013年 | 9067篇 |
2012年 | 10994篇 |
2011年 | 11731篇 |
2010年 | 7857篇 |
2009年 | 7598篇 |
2008年 | 8159篇 |
2007年 | 7507篇 |
2006年 | 6805篇 |
2005年 | 5787篇 |
2004年 | 4324篇 |
2003年 | 3445篇 |
2002年 | 3184篇 |
2001年 | 2640篇 |
2000年 | 2306篇 |
1999年 | 2573篇 |
1998年 | 2282篇 |
1997年 | 2108篇 |
1996年 | 2305篇 |
1995年 | 1850篇 |
1994年 | 1781篇 |
1993年 | 1476篇 |
1992年 | 1345篇 |
1991年 | 1232篇 |
1990年 | 1004篇 |
1989年 | 738篇 |
1988年 | 621篇 |
1987年 | 495篇 |
1986年 | 499篇 |
1985年 | 460篇 |
1984年 | 333篇 |
1983年 | 213篇 |
1982年 | 209篇 |
1981年 | 159篇 |
1980年 | 126篇 |
1979年 | 101篇 |
1978年 | 72篇 |
1976年 | 72篇 |
1974年 | 85篇 |
1973年 | 75篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
151.
Summary Consider the solution of one-dimensional linear initial-boundary value problems by a finite element method of lines using a piecewiseP
th
-degree polynomial basis. A posteriori estimates of the discretization error are obtained as the solutions of either local parabolic or local elliptic finite element problems using piecewise polynomial corrections of degreep+1 that vanish at element ends. Error estimates computed in this manner are shown to converge in energy under mesh refinement to the exact finite element discretization error. Computational results indicate that the error estimates are robust over a wide range of mesh spacings and polynomial degrees and are, furthermore, applicable in situations that are not supported by the analysis.This research was partially supported by the U.S. Air Force Office of Scientific Research, Air Force Systems Command, USAF, under Grant Number AFOSR 90-0194; by the U.S. Army Research Office under Contract Number DAAL03-91-G-0215; and by the National Science Foundation under Institutional Infrastructure Grant Number CDA-8805910 相似文献
152.
Addition of functionalized zinc-copper reagents to the title complexes proceeds in a highly diastereoselective fashion to afford dienol complexes. The relative configurations of adducts 3d were determined by single X-ray diffraction analysis. 相似文献
153.
A short regio- and stereoselective synthesis of two carbocyclic 3′-deoxynucleoside analogues is described, the key step of which consists in the photosensitized addition of MeOH to a cyclopent-2-enone derivative. As in both cases functional groups capable to react with each other are present in the same molecule, the synthetic compounds can form polymers similar to oligonucleotides. 相似文献
154.
155.
The theory of tree-growing (RECPAM approach) is developed for outcome variables which are distributed as the canonical exponential family. The general RECPAM approach (consisting of three steps: recursive partition, pruning and amalgamation), is reviewed. This is seen as constructing a partition with maximal information content about a parameter to be predicted, followed by simplification by the elimination of ‘negligible’ information. The measure of information is defined for an exponential family outcome as a deviance difference, and appropriate modifications of pruning and amalgamation rules are discussed. It is further shown how the proposed approach makes it possible to develop tree-growing for situations usually treated by generalized linear models (GLIM). In particular, Poisson and logistic regression can be tree-structured. Moreover, censored survival data can be treated, as in GLIM, by observing a formal equivalence of the likelihood under random censoring and an appropriate Poisson model. Three examples are given of application to Poisson, binary and censored survival data. 相似文献
156.
K. Y. Lin 《Journal of statistical physics》1987,49(1-2):269-279
The spontaneous magnetization of the Ising model on a 4–8 lattice with six different coupling constants and two different magnetic moments is studied. A formula for the spontaneous magnetization is proposed. The result agrees with the exact low-temperature series expansions up to the 12th order. 相似文献
157.
Let V be a hypersurface with an isolated singularity at the origin in ? n+1. It is a natural question to ask when V is defined by weighted homogeneous polynomial or homogeneous polynomial up to biholomorphic change of coordinates. In 1971, a beautiful theorem of Saito gives a necessary and sufficient condition for V to be defined by a weighted homogeneous polynomial. For a two-dimensional isolated hypersurface signularity V, Xu and Yau found a coordinate free characterization for V to be defined by a homogeneous polynomial. Recently Lin and Yau gave necessary and sufficient conditions for a 3-dimensional isolated hypersurface singularity with geometric genus bigger than zero to be defined by a homogeneous polynomial. The purpose of this paper is to prove that Lin-Yau’s theorem remains true for singularities with geometric genus equal to zero. 相似文献
158.
采用化学自燃烧法制备了不同Ag+掺杂浓度的Y2O3:Eu纳米晶体粉末样品([Y3+]∶[Eu3+]∶[Ag+]=99∶1∶X,X=0—3.5×10-2),以及通过退火处理得到了相应的体材料.根据X射线衍射谱确定所得纳米和体材料样品均为纯立方相.实验表明在纳米尺寸样品中随着Ag离子浓度的增加,荧光发射强度随之增加,当X=2×10-2时达到最大值,其发光强度比X=0时提高了近50%.当Ag离子浓度继续增加,样品发光强度保持不变.在相应的体材料样品中则没有观察到此现象.通过对各样品的发射光谱,激发光谱,X射线衍射图谱,透射电镜(TEM)照片和荧光衰减曲线的研究,分析了引起纳米样品荧光强度变化的原因是由于Ag离子与表面悬键氧结合,从而使这一无辐射通道阻断,使发光中心Eu3+的量子效率提高;Ag+的引入所带来的另一个效应是使激发更为有效.这两方面原因使发光效率得到了提高. 相似文献
159.
采用顶部籽晶提拉法(TSSG)生长出Yb:KY(WO4)2(Yb:KYW)激光晶体.对预烧后的原料及晶体进行了XRD分析,结果表明,分别在920℃和600℃预烧8h后的熔质和助熔剂基本上形成一相,抑止了实验中的挥发问题;所生长的晶体为β-Yb:KYW,计算其晶格常数为a=1.063nm,b=1.034nm,c=0.755nm,β=130.75°.测得不同厚度样品的吸收光谱,结果表明样品在933nm和981nm有较强的吸收峰,计算出主峰981nm的吸收截面σ关键词:
Yb:KYW
TSSG法
晶体结构
光谱参数 相似文献
160.
针对VO2薄膜在微测辐射热计上的应用,采用射频反应溅射法,在室温下制备氧化钒薄膜;研究了氧分压对薄膜沉积速率、电学性质及成分的影响.通过调节氧分压,先获得成分接近VO2的非晶化薄膜,再在400℃空气中氧化退火,便可制得高电阻温度系数,低电阻率的VO2薄膜,电阻温度系数约为-4%/℃,薄膜方块电阻为R□为100—300kΩ;薄膜在室温下沉积,400℃下退火的制备方法与微机电加工(micro electromechanic
关键词:
二氧化钒
电阻温度系数
氧分压
射频反应溅射法 相似文献