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951.
In dispersive propagation, waves from the same source will generally differ depending on how far they have traveled. Accordingly, it is desirable for classification in such environments to either account for propagation effects, or to obtain features that are invariant to such effects. The latter approach is taken in this paper, and features are derived that are unaffected by channel dispersion, per mode. A "local" view of pulse propagation in time-frequency phase space is considered. It is shown that the local duration of a wave, obtained from its time-frequency Wigner distribution, is invariant to dispersion. While higher moments of the Wigner distribution are not invariant to dispersion, the phase space considerations suggest an approach for defining "dispersion-invariant moments" (DIMs) of any order. This approach is also used to define a dispersion-invariant correlation coefficient that can be used for classification. The classification utility of the DIMs, and of the dispersion-invariant correlation coefficient, is evaluated via simulations of acoustic scattering from steel shells in a dispersive channel model (Pekeris waveguide). Receiver operating characteristic curves quantify the improved discriminability of the DIMs versus ordinary temporal moments, and of the dispersion-invariant correlation coefficient versus the ordinary correlation coefficient. 相似文献
952.
We investigate several varying-mass dark matter particle models in the framework of phantom cosmology. We examine whether there exist late-time cosmological solutions, corresponding to an accelerating universe and possessing dark energy and dark matter densities of the same order. Imposing exponential or power-law potentials and exponential or power-law mass dependence, we conclude that the coincidence problem cannot be solved or even alleviated. Thus, if dark energy is attributed to the phantom paradigm, varying-mass dark matter models cannot fulfill the basic requirement that led to their construction. 相似文献
953.
We propose that observables in quantum theory are properly understood as representatives of symmetry-invariant quantities relating one system to another, the latter to be called a reference system. We provide a rigorous mathematical language to introduce and study quantum reference systems, showing that the orthodox “absolute” quantities are good representatives of observable relative quantities if the reference state is suitably localised. We use this relational formalism to critique the literature on the relationship between reference frames and superselection rules, settling a long-standing debate on the subject. 相似文献
954.
Svenja Sommer Leon M. Lang Laura Drummond Markus Buchhaupt Marco A. Fraatz Holger Zorn 《Molecules (Basel, Switzerland)》2022,27(12)
Several non-canonical, methylated terpenes have been described as products of genetically modified Escherichia coli recently, and the aroma properties of 28 odor-active methylated derivatives of prenol, isoprenol, bornane, camphene, carene, citronellol, fenchol, geraniol, limonene, linalool, terpineol, and farnesol were characterized for the first time in the current study. Twelve methylated monoterpenes exhibited a particularly intense and pleasant odor and were therefore chosen for the determination of their respective odor thresholds (OTs) in comparison to their non-methylated equivalents. In addition to the determination of OTs based on the literature value for the internal standard, (2E)-decenal, the threshold values of the compounds with individually determined OTs of the participants were calculated. This enabled a more precise identification of the OTs. Among the non-canonical terpenes, the lowest OTs in the air were found for 2-methyllinalool (flowery, 1.8 ng L−1), 2-methyl-α-fenchol (moldy, 3.6 ng L−1), 2-methylgeraniol (flowery, 5.4 ng L−1), 2-methylcitronellol (citrus-like, 7.2 ng L−1), and 4-methylgeraniol (citrus-like, 16 ng L−1). The derivatives of geraniol, linalool, and citronellol showed very pleasant odor impressions, which could make them interesting for use as flavoring agents in the flavor and fragrance industry. 相似文献
955.
Marcel J. Rost Leon Jacobse Marc T. M. Koper 《Angewandte Chemie (International ed. in English)》2023,62(27):e202216376
Many chemical surface systems develop ordered nano-islands during repeated reaction and restoration. Platinum is used in electrochemical energy applications, like fuel cells and electrolysers, although it is scarce, expensive, and degrades. During oxidation-reduction cycles, simulating device operation, nucleation and growth of nano-islands occurs that eventually enhances the dissolution. Preventing nucleation would be the most effective solution. However, little is known about the atomic details of the nucleation; a process almost impossible to observe. Here, we analyze the nuclei-distance distribution mapping out the underlying atomic mechanism: a rarely observed, non-random nucleation takes place. Special, preferential nucleation sites that a priori do not exist, develop initially via a precursor and eventually form a semi-ordered Pt-oxide structure. This precursor mechanism seems to be general, possibly explaining also the nano-island formation on other surfaces/reactions. 相似文献
956.
M.Sc. Steffen Maier M.Sc. Nikolai Hippchen Fabian Jester Marcus Dodds Michel Weber Leon Skarjan Dr. Frank Rominger Dr. Jan Freudenberg Prof. Uwe H. F. Bunz 《Angewandte Chemie (International ed. in English)》2023,62(5):e202214031
Cyclopentannulation was explored as a strategy to access large, stable azaarenes. Buchwald–Hartwig coupling of previously reported di- and tetrabrominated cyclopentannulated N,N′-dihydrotetraazapentacenes furnished stable azaarenes with up to 13 six-membered rings in a row and a length of 3.1 nm. Their optoelectronic and semi-conducting properties as well as their aromaticity were investigated. 相似文献
957.
Foundations of Computational Mathematics - Tackling semi-supervised learning problems with graph-based methods has become a trend in recent years since graphs can represent all kinds of data and... 相似文献
958.
959.
We propose a computational model for the numerical analysis of the dynamic interaction between a single excavation tool and the surrounding soil. An incremental non-linear (hypoplastic) constitutive model is employed to capture the complex response of soft soils. Large displacements and deformations are handled by an Updated Lagrangian formulation, the particle finite element method (PFEM). (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献