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101.
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103.
在材料研制中的连续介质细观力学有限元建模现状评论(译文) 总被引:5,自引:1,他引:5
评述了机械载荷下材料力学行为有限元模拟的先进技术.分析
了考虑材料微观及细观结构情况下,对材料变形、损伤、断裂进行模
拟时各种方法的优缺点及发展前景.阐述了对材料行为模拟方法的发
展,包括基本的及先进的方法,如体胞方法、真实结构模拟、粘结区
模型等.分析了在先进新材料的开发中运用有限元方法的可能性 相似文献
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105.
A massively parallel nanofluidic concentration device array for multiplexed and high-throughput biomolecule detection is demonstrated. By optimizing the microchannel/nanojunction design and channel conductivity, an array of up to 128 nanofluidic concentration devices were fabricated. Operation of the entire array requires only one inlet and one outlet reservoir, with the application of a single operational voltage bias across them. Concentration efficiencies of the devices were found to be uniform within the array, within 5% error. Alternatively, concentration speed in each channel can be individually tuned by controlling the length of the inlet microchannel and thus controlling the flow rate based on change of the tangential electric field. This allows immuno-binding reactions at different concentration ranges to be performed in parallel. Using multiplexed, successive-concentration enhanced detection in the device, we have shown that the dynamic range and reliability of the immunoassay can be significantly increased. 相似文献
106.
Pinched flow coupled shear-modulated inertial microfluidics for high-throughput rare blood cell separation 总被引:1,自引:0,他引:1
Blood is a highly complex bio-fluid with cellular components making up >40% of the total volume, thus making its analysis challenging and time-consuming. In this work, we introduce a high-throughput size-based separation method for processing diluted blood using inertial microfluidics. The technique takes advantage of the preferential cell focusing in high aspect-ratio microchannels coupled with pinched flow dynamics for isolating low abundance cells from blood. As an application of the developed technique, we demonstrate the isolation of cancer cells (circulating tumor cells (CTCs)) spiked in blood by exploiting the difference in size between CTCs and hematologic cells. The microchannel dimensions and processing parameters were optimized to enable high throughput and high resolution separation, comparable to existing CTC isolation technologies. Results from experiments conducted with MCF-7 cells spiked into whole blood indicate >80% cell recovery with an impressive 3.25 × 10(5) fold enrichment over red blood cells (RBCs) and 1.2 × 10(4) fold enrichment over peripheral blood leukocytes (PBL). In spite of a 20× sample dilution, the fast operating flow rate allows the processing of ~10(8) cells min(-1) through a single microfluidic device. The device design can be easily customized for isolating other rare cells from blood including peripheral blood leukocytes and fetal nucleated red blood cells by simply varying the 'pinching' width. The advantage of simple label-free separation, combined with the ability to retrieve viable cells post enrichment and minimal sample pre-processing presents numerous applications for use in clinical diagnosis and conducting fundamental studies. 相似文献
107.
Leon A. Luxemburg Philip R. Brown 《Journal of Computational and Applied Mathematics》2011,235(8):2615-2625
We show that if the Nevanlinna-Pick interpolation problem is solvable by a function mapping into a compact subset of the unit disc, then the problem remains solvable with the addition of any number of boundary interpolation conditions, provided the boundary interpolation values have modulus less than unity. We give new, inductive proofs of the Nevanlinna-Pick interpolation problem with any finite number of interpolation points in the interior and on the boundary of the domain of interpolation (the right half plane or unit disc), with function values and any finite number of derivatives specified. Our solutions are analytic on the closure of the domain of interpolation. Our proofs only require a minimum of matrix theory and operator theory. We also give new, straightforward algorithms for obtaining minimal H∞ norm solutions. Finally, some numerical examples are given. 相似文献
108.
Guillem Aromí Leoní A. Barrios Olivier Roubeau Patrick Gamez 《Coordination chemistry reviews》2011,255(5-6):485-546
The current great interest in preparing functional metal-organic materials is inevitably associated with tremendous research efforts dedicated to the design and synthesis of new families of sophisticated multi-nucleating ligands. In this context, the N-donor triazole and tetrazole rings represent two categories of ligands that are increasingly used, most likely as the result of the recent dramatic development of “click chemistry” and Zeolitic Imidazolate Frameworks (ZIFs). Thus, azole-based complexes have found numerous applications in coordination chemistry.In the present review, we focus on the utilization of 1,2,3-triazole, 1,2,4-triazole and tetrazole ligands to create coordination polymers, metal complexes and spin-crossover compounds, reported to the end of 2009. In the first instance, we present a compendium of all the relevant ligands that have been employed to generate coordination polymers and Metal-Organic Frameworks (MOFs). Due to the huge amount of reported MOFs and coordination polymers bearing these azole rings, three representative examples for each category (therefore nine in total) are described in detail. The second section is devoted to the use of the bridging abilities of these azole ligands to prepare metal complexes (containing at least two metal centers). Given the large number and the great structural diversity of the polynuclear compounds found in the literature, these have been grouped according to their nuclearity. Finally, in the last section, the triazole- and tetrazole-containing coordination compounds exhibiting spin-crossover properties are presented. 相似文献
109.
Cohen L 《The journal of physical chemistry. A》2011,115(45):12919-12923
We show that for any wave function and potential the local virial theorem can always be satisfied 2K(r) = r·ΔV by choosing a particular expression for the local kinetic energy. In addition, we show that for each choice of local kinetic energy there are an infinite number of quasi-probability distributions which will generate the same expression. We also consider the local tensor virial theorem. 相似文献
110.
Diffusion rate of dye-labelled PAMAM dendrimers through free-standing silica colloidal crystals was studied as a function of the dendrimer generation and nanopore size to determine the transport selectivity. 相似文献