全文获取类型
收费全文 | 783篇 |
免费 | 149篇 |
国内免费 | 90篇 |
专业分类
化学 | 463篇 |
晶体学 | 8篇 |
力学 | 82篇 |
综合类 | 8篇 |
数学 | 112篇 |
物理学 | 349篇 |
出版年
2024年 | 8篇 |
2023年 | 9篇 |
2022年 | 32篇 |
2021年 | 30篇 |
2020年 | 37篇 |
2019年 | 25篇 |
2018年 | 26篇 |
2017年 | 39篇 |
2016年 | 40篇 |
2015年 | 31篇 |
2014年 | 58篇 |
2013年 | 55篇 |
2012年 | 78篇 |
2011年 | 87篇 |
2010年 | 45篇 |
2009年 | 38篇 |
2008年 | 20篇 |
2007年 | 61篇 |
2006年 | 45篇 |
2005年 | 33篇 |
2004年 | 28篇 |
2003年 | 22篇 |
2002年 | 33篇 |
2001年 | 22篇 |
2000年 | 19篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 12篇 |
1996年 | 8篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 7篇 |
1992年 | 6篇 |
1991年 | 6篇 |
1990年 | 16篇 |
1989年 | 9篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1979年 | 1篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 2篇 |
排序方式: 共有1022条查询结果,搜索用时 156 毫秒
71.
A new dual chemosensor (TTF-PBA) for Fe3+ and Cu2+ in different signal pathways was designed and synthesized. The absorption spectrum, fluorescence spectrum and cyclic voltammograms changed in the presence of Cu2+ and Fe3+. The optical color changed within 5 s from yellow to orange upon the addition of Cu2+, and it changed to dark yellow when Fe3+ existed. The cyclic voltammogram of Cu2+/TTF-PBA changed from Eox = 0.50 V, Ered = 0.32 V to Eox = 0.64 V, Ered = 0.80 V (vs Ag/AgCl) upon the addition of 2.0 equiv. Cu2+. As for Fe3+/TTF-PBA, its oxidation wave disappeared, and its reduction wave appeared at Ered = ?0.59 V (vs Ag/AgCl) upon the addition of 4.0 equv. Fe3+. The sensor displayed high selectivity for Cu2+ and Fe3+ over other ions including Pb2+, Zn2+, Ni2+, Ag+, Cr3+, Mn2+, Al3+, Co2+, Pd2+, Hg2+, Fe2+, Cd2+, Ce3+, Bi3+ and Au3+, the detection limits for Cu2+ and Fe3+ ion reached as low as 5.33 × 10?7 mol/L and 5.34 × 10?7 mol/L, respectively. Furthermore, when Fe3+ existed, Cu2+ can be detected sequentially by the sensor through the absorption spectrum and the color change observed by naked-eyes. 相似文献
72.
A 'living' controlled hydrogel formation method was first reported to create loose and compact in situ biodegradable hydrogels. The method executed under mild reaction conditions can conveniently tailor the hydrogel properties, and it has the potential to develop into a powerful tool for the design, synthesis, and self-assembly of novel tailor-made biomaterials and drug delivery systems. 相似文献
73.
本文对Hg的577 nm、579 nm谱线的塞曼效应进行了理论分析和实验验证,通过对F-P标准具分辨率的讨论.证明实验现象与理论分析是一致的.定量计算了分裂谱线的波数差. 相似文献
74.
C.Y. Jiang H.S. Yang X.Y. Xu F.Y. Yu C.H. Sun S.Q. Ke R.J. Leng 《Physica C: Superconductivity and its Applications》2011,471(1-2):19-22
The X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra, and resistivity ρ are measured on Nd1.85?xRxCe0.15CuO4±δ (R = Gd and Sm) single crystals. From the XRD and FTIR spectra studies, the lattice constant c are found to decrease faster for Gd doping than that for Sm doping with increasing doping concentration x. Upon Gd doping, all the transmission peaks shift to high frequency but nearly unchanged with increasing Sm doping content. The volume of the unit cell observed through XRD and FTIR spectra decreases faster for Gd doping than that for Sm doping. Furthermore, for Gd doping the superconducting Tc decreases rapidly with increasing the doping concentration, while the Tc decreases slowly for Sm doping with increasing Sm content, which is found to be very well consistent with the evolution of the volume of the unit cell for two series. 相似文献
75.
Dean P Lim YL Valavanis A Kliese R Nikolić M Khanna SP Lachab M Indjin D Ikonić Z Harrison P Rakić AD Linfield EH Davies AG 《Optics letters》2011,36(13):2587-2589
We demonstrate terahertz (THz) frequency imaging using a single quantum cascade laser (QCL) device for both generation and sensing of THz radiation. Detection is achieved by utilizing the effect of self-mixing in the THz QCL, and, specifically, by monitoring perturbations to the voltage across the QCL, induced by light reflected from an external object back into the laser cavity. Self-mixing imaging offers high sensitivity, a potentially fast response, and a simple, compact optical design, and we show that it can be used to obtain high-resolution reflection images of exemplar structures. 相似文献
76.
We present a new approach for simultaneous spectral and coherent combining in a master oscillator power amplifier (MOPA) configuration with active phasing. Spectrally combined single-frequency seed lasers are employed as a master oscillator for the all-fiber power amplifier chain, which provides robust performance suppressing of the stimulated Brillouin scattering effect, while coherent combining of spectrally combined amplifiers with active phase control provides stable in-phase combining, despite the strong phase fluctuation. In experiments, two spectrally combined seed MOPA chains are coherently combined with a total output power of 390 W. The power of the main lobe in the closed loop is two times of that value in the open loop, and visibility of more than 75% of the long-exposure interference pattern at the receiving plane is obtained. 相似文献
77.
Siew Leng Lim Yiliang LiuJing Li En-Tang KangChong Kim Ong 《Applied Surface Science》2011,257(15):6612-6617
Transparent TiO2 nanotube arrays of micrometer lengths were prepared by anodization of titanium thin film RF sputtered on indium tin oxide (ITO) which was coated on glass substrate. The sputtering process took place at elevated temperature of 500 °C. The structures of the films were studied using scanning electron microscopy (SEM) and X-ray diffraction (XRD) while the optical properties of the films were investigated using UV-visible spectroscopy. Two types of electrolytes were used in this work: an aqueous mixture of acetic acid and HF solution and a mixture of NH4F and water dissolved in ethylene glycol. The concentration of NH4F, voltage and the thickness of the sputtered titanium film were varied to study their effect on the formation of TiO2 nanotube arrays. It is demonstrated in this work that the nanoporous layer is formed on top of the ordered array of TiO2 nanotubes. Furthermore, the optical transmittance of TiO2 nanotubes annealed at 450 °C is much lower than the non annealed TiO2 nanotubes in the visible wavelength region. 相似文献
78.
We analyze retail space-exchange problems where two or more retailers exchange their excess retail spaces to improve the utilization of their space resource. We first investigate the two-retailer space exchange problem. In order to entice both retailers with different bargaining powers to exchange their spaces, we use the generalized Nash bargaining scheme to allocate the total profit surplus between the two retailers. Next, we consider the space-exchange problem involving three or more retailers, and construct a cooperative game in characteristic function form. We show that the game is essential and superadditive, and also prove that the core is non-empty. Moreover, in order to find a unique allocation scheme that ensures the stability of the grand coalition, we propose a new approach to compute a weighted Shapley value that satisfies the core conditions and also reflects retailers’ bargaining powers. Our analysis indicates that the space exchange by more retailers can result in a higher system-wide profit surplus and thus a higher allocation to each retailer under a fair scheme. 相似文献
79.
We investigate an automobile supply chain where a manufacturer and a retailer serve heterogeneous consumers with electric vehicles (EVs) under a government’s price-discount incentive scheme that involves a price discount rate and a subsidy ceiling. We show that the subsidy ceiling is more effective in influencing the optimal wholesale pricing decision of the manufacturer with a higher unit production cost. However, the discount rate is more effective for the manufacturer with a lower unit production cost. Moreover, the expected sales are increasing in the discount rate but may be decreasing in the subsidy ceiling. Analytic results indicate that an effective incentive scheme should include both a discount rate and a subsidy ceiling. We also derive the necessary condition for the most effective discount rate and subsidy ceiling that maximize the expected sales of EVs, and obtain a unique discount rate and subsidy ceiling that most effectively improve the manufacturer’s incentive for EV production. 相似文献
80.
We investigate rigidity problems for odd-dimensional compact submanifolds.We show that if Mn(n 5)is an odd-dimensional compact submanifold with parallel mean curvature in Sn+p,and if RicM(n-2-1n)(1+H2)and Hδn,whereδn is an explicit positive constant depending only on n,then M is a totally umbilical sphere.Here H is the mean curvature of M.Moreover,we prove that if Mn(n 5)is an odd-dimensional compact submanifold in the space form Fn+p(c)with c 0,and if RicM(n-2-εn)(c+H2),whereεn is an explicit positive constant depending only on n,then M is homeomorphic to a sphere. 相似文献