5-羧基-3-氨基-1,2,4-三氮唑芳香醛席夫碱的合成与表征

利用氨基胍碳酸氢盐与草酸反应合成5-羧基-3-氨基-1,2,4-三氮唑,然后用5-羧基-3-氨基-1,2,4-三氮唑与芳香醛反应,合成了2种5-羧基-3-氨基-1,2,4-三氮唑芳香醛席夫碱,通过元素分析,红外光谱和紫外光谱对产物的结构进行了表征.     

亚10 μm线宽的投影光刻物镜设计及其成像性能的实验测定

 采用Zemax软件设计出6镜片、数值孔径为0.06、2倍缩小、以405 nm半导体激光器为光源、分辨精度达5 μm、视场12 mm×12 mm 内波像差小于1/4波长、畸变小于0.005%的双远心投影光刻物镜的设计方法。将设计的物镜实物化,并对其光学传递函数(MTF)作精确的实验测定,利用所提出的MTF标准实验测量法,得到该投影物镜的成像性能达亚10 μm线宽。     

Tripartite Nonlinear Entangled State Representations in Quantum Mechanics

Based on the technique of integral within an ordered product of nonlinear bosonic operators we construct a kind of tripartite nonlinear entangled states, which can make up a complete set. As its application, we also derive nonlinear 3-mode charge-related entangled state. The essential point for constructing these states lies in choosing the appropriate charge operator.     

Nonlinear Absorption and Dispersion Response in Optically Dense Media Driven by a Single-Mode Laser

Taking the density-dependent near dipole-dipole （NDD） interaction into consideration, we theoretically investigate the response of nonlinear absorption and dispersion in optically dense media of three-level atoms driven by a single-mode probe laser. The influence of the NDD effects on the absorption and dispersion spectra of the probe field is predicted via numerical calculations. It is shown that the NDD effects reduce gradually to transient absorption and amplification with the increase of the strengths of the NDD interaction, but do not change the steady-state behavior. Due to the presence of the NDD effects, steady-state absorption spectra exhibit asymmetric double-peak structure and overall shifts when a continuous-wave （cw） probe field is applied. However, frequency dispersion spectra are insensitive to them near the zero detuning.     

稀有衰变B0(Bs)→γv(-v)分支比的计算

在标准模型中,三体稀有衰变B0(Bs)→γv(-v)只有通过箱图和企鹅图才可以发生.这个过程对于确定B介子的衰变常数及其波函数有着较重要的物理意义,由于这些衰变道的分支比较小,因此也是探测新物理理论的比较好的场所.利用B介子强衰变确定的波函数,得到B0(Bs)→γv(-v)的分支比的数量级是10-9(10-8),这些结果可以在未来的实验上得到检验.     

基于TG-FTIR的杨木热解过程中脲醛树脂影响机理的模型物研究

热解是废弃人造板高效回收利用的方式,人造板中所含胶黏剂是其不同于生物质的主要特征。为了有效环保地利用热解技术处理废弃人造板,解明人造板热解过程中其所含脲醛树脂胶黏剂(UF)对木材热解特性的影响,深入探索UF对人造板中木材各组分的作用机制,以杨木及木材的三种主要组分(纤维素、半纤维素、木素)为研究对象,创新性地依据杨木的化学组成,以纤维素、木聚糖和木素配制成模型物,并加入UF模拟人造板的构成。利用热重红外光谱联用(TG-FTIR)分析法,对比分析了加入UF前后模型物以及杨木各主要组分的热失重特性及气相演变规律。热重及红外结果表明,UF促进了纤维素热解过程中水和羧酸类物质的生成。UF与木素结合生成热不稳定的含氮结构,释放大量氨气,并且在200～300 ℃区间内参与了木素的热解并直接影响木素热解产物的生成。由此推测,在人造板热解过程中,木材三种主要组分中与UF作用的主要成分是木素。     

基于红外光谱分析的新型物质分析算法及实验研究

提出了一种基于红外光谱分析技术的物质识别算法以解决定性、定量的进行红外光谱分析时所遇到的难题。通过将欧氏距离相似性判定和光谱分析传统方法的结合,完成了该算法的理论分析并开发了相应的物质分析软件。通过物质分析实验验证了该算法的可行性,实验结果表明该算法应用于测试混合物光谱分析时分析准确度优于96%。通过分析实验结果表明可知:该算法能够程序化地实现物质的现场快速检测,并保持很高的精确度,能够满足食品安全领域的光谱分析需求。     

β-Delayed Proton Decays of 133Sm and 149Yb

¹³³Sm was produced via fusion evaporation in the reaction ⁴⁰Ca+⁹⁶Ru. Its β-delayed proton decay was studied by means of “p-γ” coincidence in combination with a He-jet tape transport system, including half-lives, proton energy spectra, γ-transitions following the proton emissions, and the branching ratios to the low-lying states in the grand-daughter nuclei. The possible spins and parities of ¹³³Sm were extracted by fitting the experimental data with a statistical model calculation. The configuration-constrained nuclear potential energy surfaces of ¹³³Sm were calculated by using the Woods-Saxon Strutinsky method. Comparing the experimental and calculated results, the spins and parities of ¹³³Sm were assigned to be 5/2⁺ and 1/2^－, which is reconciled with our published simple (EC+β⁺) decay scheme of ¹³³Sm in 2001. In addition, our experimental data on the beta-delayed proton decay of ¹⁴⁹Yb reported in Eur. Phys. J., 2001, A12: 1—4 was also analyzed by using the same method. The spin and parity of ¹⁴⁹Yb was assigned to be 1/2^－.     

壳聚糖亚胺环钯化合物的合成与表征

用水杨醛接枝改性后的壳聚糖亚胺与Li₂PdCl₄甲醇溶液反应得到壳聚糖环钯化合物。壳聚糖、壳聚糖席夫碱及其钯化合物用红外光谱(IR)、X射线衍射光谱(XRD)、热分析(DTA-TG)、荧光光谱以及X射线光电子能谱(XPS)等分析手段进行了表征分析。根据表征结果提出了席夫碱及壳聚糖亚胺环钯化合物的结构。     

理论研究电流注入对垂直腔面发射激光器多横模行为的影响

从包含时空变量的速率方程出发,针对弱折射率导引垂直腔面发射激光器(VCSELs),利用空间积分法分析了典型电注入参数对VCSELs多横模行为的影响,在不降低模型准确性的前提下提高了仿真效率。仿真结果表明,注入盘孔径和注入环越小、注入强度越低以及电流扩散越弱时,VCSELs更易实现单横模工作;反之,VCSELs高阶横模开始出现并呈现较强的模式竞争,引发了载流子空间烧孔效应,并导致基模强度降低。进一步得出,在环形注入方式下,高阶模式更容易出现且彼此间的竞争较盘形注入时强。