Crystal chemistry of AB2X4 (X = S,Se, Te) compounds

An attempt is made to correlate the crystal structures of ternary chalcogenides of composition AB₂X₄ with the cationic radius ratio and a pseudo force-constant involving their electronegativities. The resultant diagram adequately resolves structures based on the types K₂SO₄, monoclinic, olivine, MnY₂S₄, Th₃P₄, and CaFe₂O₄ but structure types based on spinel, Cr₃Se₄, and Ag₂HgI₄ are not resolved. Crystal chemical arguments are used to explain these observations and to advance reasons for the successes and failures of this method for predicting structure types.     

The influence of ions on the structure of water

Journal of Structural Chemistry - The main features of the changes produced by ions in water may be summarized as follows. The influence of ions on the structure of the “free” water...     

Kupfer

Analytical and Bioanalytical Chemistry -     

Influence of alkali metal and ammonium cations on the structure of iron(II) and cobalt(III) hexacyanide complexes encapsulated in faujasite

Changing the cation composition (Na⁺ to K⁺, NH₄ ⁺ Cs⁺) of faujasite with hexacyanoferrate(II) encapsulated in the large pores causes distortion of the octahedral symmetry of the complex.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 30, No. 5, pp. 293–297, September–October, 1994.