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981.
Abdrakhmanova L. A. Fakhrutdinova V. Kh. Khozin V. G. 《Russian Journal of Applied Chemistry》2003,76(11):1832-1834
The structural transformations of oligoglycol acrylates in the surface layers of polymethyl methacrylate were studied. 相似文献
982.
L. M. Babkov O. V. Gorshkova G. A. Puchkovskaya I. N. Khakimov 《Journal of Structural Chemistry》1998,39(1):44-48
The polymorphism, conformation mobility and structure of 4-cyano-4′-pentalkoxybiphenyl (5OCB) in different physical states
are studied by IR spectroscopy. The spectra were measured in the frequency range 400–4000 cm−1 at temperatures from 300 to 350 K. The IR spectra of 5OCB are modeled using the concept of conformational mobility of these
molecules. An analysis of the experimental and theoretical spectra reveals absorption bands whose spectroscopic parameters
are sensitive to variations of temperature (experiment) and conformation (theory); a relationship between these changes is
established. It is concluded that the polymorphism of 5OCB is of conformation type. In the solid crystalline state, 5OCB molecules
have conformations with a planar biphenyl fragment; the angle of orientation of the plane of the carbon framework of the alkyl
radical relative to the biphenyl fragment decreases as the temperature increases from 35° in the solid crystalline state to
10° in the liquid crystalline and isotropic liquid states. In both of these states the biphenyl fragment becomes nonplanar.
The angle between the phenyl rings is up to 30°.
Saratov State University. Institute of Physics, Ukrainian Academy of Sciences. Samarkand State University. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 1, pp. 55–60, January–February, 1998.
This work was supported by RFFR grant No. 97-03-32175a. 相似文献
983.
An indirect laser photoacoustic technique is described. The basic principle, the experimental set-up and the influencing factors are discussed in detail. This method was used to quantify phenylamine, arginine and methylene blue on membranes. The linear ranges of the calibration curve are up to two orders of magnitude. With 1 microliter of sample solution, the detection limits are 0.25, 1.52 and 0.14 pmol for phenylamine, arginine and methylene blue, respectively. 相似文献
984.
The titled compounds were prepared by reacting N-(2-bromoethyl)phthalimide with enolates of phenylacetic acid esters. 2,3-Dihydrooxazolo[2,3-a]isoindolones are believed to be intermediates in the process. An X-ray crystallographic analysis was conducted on one of the compounds. 相似文献
985.
Asymmetry and magnetism in bis(oximato)-bridged heterobimetallic compounds: a computational approach
Cano J Rodríguez-Fortea A Alemany P Alvarez S Ruiz E 《Chemistry (Weinheim an der Bergstrasse, Germany)》2000,6(2):327-333
A density functional study of exchange coupling was carried out for a series of heterobinuclear oximato-bridged transition metal complexes. Model calculations were used to examine the influence of the electronic configuration of the metal atoms on the coupling constants. This analysis was complemented by a study of the variation of the coupling constant with the most usual structural distortions within this family of compounds. The influence of the nature of the terminal ligands as well as that of the symmetry on the bridge were also investigated. 相似文献
986.
M. V. Otdel’nova J. A. Zakharova E. M. Ivleva V. A. Kasaikin A. B. Zezin V. A. Kabanov 《Polymer Science Series A》2006,48(4):413-421
Supramolecular organization of complexes formed by poly(N-ethyl-4-vinylpyridinium bromide) and sodium dodecylsulfate in aqueous salt solutions was studied as a function of temperature and concentration of the complexes. It was shown that a decrease in temperature and/or concentration of complexes led to their reversible disaggregation into a molecularly dispersed (“unipolymer”) state. The ratio between the components in complex particles remained unchanged in this case. It was first found that phase separation in aqueous solutions of the complexes upon temperature elevation is accompanied by the precipitation of a nonstoichiometric complex. 相似文献
987.
988.
989.
990.
A. V. Barinov N. I. Pechurova L. I. Martynenko K. I. Popov V. I. Spitsyn 《Russian Chemical Bulletin》1977,26(6):1135-1138
Conclusions In solution, the complexes MII(NdA)2 do not have a polynuclear structure. In the conditions studied, hydroxo polynuclear complexes including EDTA and MII and Nd3+ ions are also not formed. Our results are not inconsistent with the hypothesis that the solid complex Ca(NdA)2·17H2O has a polynuclear structure and that the polynuclear character is successively weakened as Ca2+ is replaced by Sr2+ and Ba2+.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1235–1239, June, 1977. 相似文献