Fluorimetric and mass spectrometric study of the interaction of beta-cyclodextrin and osthole

The inclusion complex of beta-cyclodextrin (beta-CD) and osthole was studied by the electrospray ionization mass spectrometry (ESI-MS) and fluorescence spectrometry. From the mass spectrum, the 1:1 stoichiometric inclusion complex of beta-CD and osthole was observed. The tandem mass spectrum was performed. The fluorescence intensity of osthole increased in the present of beta-CD. According to the 1:1 beta-CD-osthole mode, the dissociation constant (KD) was obtained by ESI-MS and fluorescence spectrometry. The KD of beta-CD-osthole inclusion complex is 6.96 x 10(-3) mol L(-1) obtained by mass spectrometry and that is 8.14 x10 (-3) mol L(-1) obtained by fluorescence spectrometry, which is consistent with each other.     

Covalent modification of glassy carbon electrode with aspartic acid for simultaneous determination of hydroquinone and catechol

Glassy carbon electrode (GCE) is covalently modified with aspartic acid (Asp). The modified electrode is used for the simultaneous electrochemical determination of hydroquinone (HQ) and catechol (CC) and shows an excellent electrocatalytical effect on the oxidation of HQ and CC by cyclic voltammetry (CV) in 0.1 mol/L acetate buffer solution (pH 4.5). In differential pulse voltammetric (DPV) measurements, the modified electrode could separate the oxidation peak potentials of HQ and CC present in binary mixtures by about 101 mV though the bare electrode gave a single broad response. A successful elimination of the fouling effect by the oxidized product of HQ on the response of CC has been achieved at the modified electrode. The determination limit of HQ in the presence of 0.1 mmol/L CC was 9.0 x 10(-7) mol/L and the determination limit of CC in the presence of 0.1 mmol/L HQ was 5.0 x 10(-7) mol/L. The proposed method has been applied to the simultaneous determination of HQ and CC in a water sample with simplicity and high selectivity.     

Capillary array electrophoresis for the research of racemization reaction of L-amino acids

Research to the racemization reaction of L-amino acids is performed through a laboratory-made 16-channel capillary array electrophoresis. The impact factors such as catalyst, solvent, and reactive time which influenced the racemization reaction are screened, the experimental results proved that the capillary array electrophoresis is qualified as combinatorial enantiomeric screening system.     

Entanglement of individual coordination polymers having helicates as building intermediates

A series of Ag(I) coordination compounds, from one-dimensional chains to 3D porous frameworks, were achieved from N,N'-bis[1-(2-pyrazinyl)ethylidene]benzil dihydrazone, L, via self-assembly, using helicates as effective secondary building units. Compound 2 [(Ag(2.75)L)(NO(3))(2.75)] was comprised of two opposite-handed 3D frameworks formed by connecting the 4(1) helical chains into (10(3)-b) nets. The pairs of the racemic 3D frameworks were connected through additional silver(I) centers and entangled each other forming a racemic 3D net. Compound 3 [(Ag(13)L(8))(BF(4))(13)(H(2)O)(12)] was comprised of a 3D framework that was constructed from double-helical building intermediates Ag(2)L(2) with one-dimensional infinite chains being threaded into the large voids of a 3D framework to form a weave structure. The ladder-like chains in compound 4 [(Ag(3)L(2))(ClO(3))(3)(CH(3)OH)(2)(CH(3)CN)] were formed by the addition of excess NaClO(3) into the methanol solution containing AgNO(3) and the ligand L, and the zigzag chains in compound 5 [(Ag(2)L(2))(ClO(4))(2)(CH(3)CN)(2)] were constructed by the addition of excess NaClO(4) into an acetonitrile solution containing AgNO(3) and the ligand L.     

近场光学扫描显微镜图象的行噪音处理

在近场光学扫描显微镜以及其他一些以扫描方式工作的系统中,由于各种原因,致使系统的扫描图象带有较大的行噪音.在这种情况下,采用传统的求平均法以及傅里叶滤波法去除行噪音效果不佳.本文提出了在空间域的自适应迭代处理和小波分析结合处理行噪音的方法.由于小波分析可以在时-频域局部化,而且时窗和频窗的宽度可以调节,故而可以检测到行噪音信号,并实现噪音的定位,实验证明效果较好.     

用于飞秒紫外激光产生的LD泵浦高效Nd:YVO4绿光激光器研究

利用简单的折叠腔,腔内不含任何其它附加光学元件,LD双端泵浦Nd:YVO₄,KTP腔内倍频绿光激光器实现了低阈值、高效率的TEM₀₀模稳定激光输出.最高绿光输出功率可达到3.3W,光-光转换效率为16.2%.     

对称相位函数掩模化的研究

本文对各种连续对称相位函数及其特性进行了分析,讨论了相位函数的2π调制、2^N和N-1法量化等问题及数据处理过程,提出二元衍射元件CIF(Caltech Intermediate Form)格式掩模数据的生成方法,并建立了实用软件,为激光直写技术实现二元衍射光学元件制作提供了有效的手段.     

一种含硫光学树脂的合成与表征

采用低温脱水剂法合成了一种含硫、苯环及双键的化合物甲基丙烯酸苯硫酚酯( TPMA) ,并利用 FTIR、1H- NMR、HPLC等技术进行了结构表征。将其作为一种单体与苯乙烯进行共聚 ,制备得到含硫透明光学树脂。对树脂的性能测试结果表明 ,共聚树脂具有较高的可见光透光率 ,而且随着 TPMA含量的增加 ,树脂的折光指数和密度线性增大 ,冲击强度提高     

简谐振动实验中阻尼力作用的估算

根据振动振幅随时间的衰减来得到阻尼系数,并估算了阻尼力对振动周期和总机械能的影响。     

三元混配络合物形成的极谱研究——Cd-Bipy-Gly体系的稳定常数测定

用般谱法研究了Cd(Ⅱ)-2,2′-联吡啶(bipy)、Cd(Ⅱ)-甘氨酸(Gly)二元体系及cd(Ⅱ)-bipy-Gly三元体系的配合物的形成条件,用极谱法测定了不同浓庹配体的E_1/2(a)、E_1/2(c)、ΔE_1/2、(i_d)_s和(i_d)_c值,利用Lrden函数作图,外推求得各级稳定常数。