全文获取类型
收费全文 | 4858篇 |
免费 | 799篇 |
国内免费 | 541篇 |
专业分类
化学 | 3381篇 |
晶体学 | 46篇 |
力学 | 347篇 |
综合类 | 24篇 |
数学 | 605篇 |
物理学 | 1795篇 |
出版年
2024年 | 19篇 |
2023年 | 102篇 |
2022年 | 161篇 |
2021年 | 184篇 |
2020年 | 199篇 |
2019年 | 192篇 |
2018年 | 178篇 |
2017年 | 137篇 |
2016年 | 269篇 |
2015年 | 220篇 |
2014年 | 254篇 |
2013年 | 368篇 |
2012年 | 472篇 |
2011年 | 456篇 |
2010年 | 308篇 |
2009年 | 286篇 |
2008年 | 306篇 |
2007年 | 250篇 |
2006年 | 243篇 |
2005年 | 211篇 |
2004年 | 185篇 |
2003年 | 158篇 |
2002年 | 132篇 |
2001年 | 111篇 |
2000年 | 94篇 |
1999年 | 100篇 |
1998年 | 73篇 |
1997年 | 73篇 |
1996年 | 73篇 |
1995年 | 60篇 |
1994年 | 45篇 |
1993年 | 45篇 |
1992年 | 27篇 |
1991年 | 38篇 |
1990年 | 35篇 |
1989年 | 26篇 |
1988年 | 12篇 |
1987年 | 12篇 |
1986年 | 14篇 |
1985年 | 18篇 |
1984年 | 9篇 |
1983年 | 10篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1974年 | 2篇 |
1971年 | 2篇 |
1944年 | 4篇 |
1942年 | 3篇 |
1941年 | 1篇 |
1940年 | 1篇 |
排序方式: 共有6198条查询结果,搜索用时 22 毫秒
841.
We introduce the so-called naive tests and give a brief review of the new developments. Naive testing methods are easy to understand and perform robustly, especially when the dimension is large. We focus mainly on reviewing some naive testing methods for the mean vectors and covariance matrices of high-dimensional populations, and we believe that this naive testing approach can be used widely in many other testing problems. 相似文献
842.
Superconvergence and recovery type a posteriori error estimators are analyzed for Pian and Sumihara's 4-node hybrid stress quadrilateral finite element method for linear elasticity problems. Superconvergence of order O(h~(1+min){α,1}) is established for both the displacement approximation in H~1-norm and the stress approximation in L~2-norm under a mesh assumption, where α 0 is a parameter characterizing the distortion of meshes from parallelograms to quadrilaterals. Recovery type approximations for the displacement gradients and the stress tensor are constructed, and a posteriori error estimators based on the recovered quantities are shown to be asymptotically exact. Numerical experiments confirm the theoretical results. 相似文献
843.
Ya-Ting Wang Hou Chen Dong-Ju Wang Liang-Jiu Bai Hui Xu Wen-Xiang Wang 《Chemical Papers》2016,70(9):1171-1184
Corn stalk-based adsorbents modified from corn stalk were prepared by Cu(0)-mediated reversible-deactivation radical polymerization (Cu(0)-mediated RDRP). They were applied to remove metal ions and they exhibited good adsorption capacity, especially for Hg(II). Adsorption properties of corn stalk can be enhanced by introducing cyano, amino, amidoxime, and carboxyl groups onto its surface, which results in efficient adsorbents for different metal ions. TGA, SEM, EA, and FTIR analyses were employed to characterize the structures of corn stalk-graft-polyacrylonitrile (CS-g-PAN), corn stalk-graft-polyacrylamide (CS-g-PAM), amidoxime corn stalk-graft-polyacrylonitrile (AO CS-g-PAN) and carboxyl corn stalk-graft-poly(methyl acrylate) (CO CS-g-PMA). The maximum adsorption capacity for Hg(II) was 8.06 mmol g?1 of AO CS-g-PAN. Kinetics of the Hg(II) adsorption on AO CS-g-PAN was found to follow the pseudo-second-order model and the adsorption isotherms were well fitted with the Freundlich isotherm model. 相似文献
844.
A facile approach was exploited for fast preparation of polymer-based monoliths in UV-transparent fused-silica capillaries via “one-pot” photo-initiated thiol-acrylate polymerization reaction of dipentaerythritolpenta-/hexaacrylate (DPEPA) and 1-octadecanethiol (ODT) in the presence of porogenic solvents (1-butanol and ethylene glycol). Due to relative insensitivity of oxygen inhibition in thiol-ene free-radical polymerization, the polymerization could be performed within 5 min. The effects of composition of prepolymerization solution on the morphology and permeability of poly(ODT-co-DPEPA) monoliths were investigated in detail by adjusting the content of monomer and binary porogen ratio. The physical properties of poly(ODT-co-DPEPA) monoliths were characterized by Fourier transform infrared spectroscopy (FT-IR), mercury intrusion porosimetry (MIP) and nitrogen adsorption/desorption measurement. The evaluation of chromatographic performance was carried out by capillary liquid chromatography (cLC). The results indicated that the poly(ODT-co-DPEPA) monolith was homogeneous and permeable, and also possessed a typical reversed-phase retention mechanism in cLC with high efficiency (∼75,000 N m−1) for separation of alkylbenzenes. Eventually, the further separation of tryptic digest of proteins by cLC tandem mass spectrometry (cLC-MS/MS) demonstrated its potential in the analysis of biological samples. 相似文献
845.
Qiang Ma Hua Bai Wentao Li Chao Wang Xinshi Li R. Graham Cooks Zheng Ouyang 《Analytica chimica acta》2016
Significantly simplified work flows were developed for rapid analysis of various types of cosmetic and foodstuff samples by employing a miniature mass spectrometry system and ambient ionization methods. A desktop Mini 12 ion trap mass spectrometer was coupled with paper spray ionization, extraction spray ionization and slug-flow microextraction for direct analysis of Sudan Reds, parabens, antibiotics, steroids, bisphenol and plasticizer from raw samples with complex matrices. Limits of detection as low as 5 μg/kg were obtained for target analytes. On-line derivatization was also implemented for analysis of steroid in cosmetics. The developed methods provide potential analytical possibility for outside-the-lab screening of cosmetics and foodstuff products for the presence of illegal substances. 相似文献
846.
This paper is concerned with the spectral properties of the unbounded upper triangular operator matrix with diagonal domain. Some sufficient and necessary conditions are given under which the essential spectrum, the Weyl spectrum and the Browder spectrum of such operator matrix, respectively, coincide with the union of the essential spectrum, the Weyl spectrum and the Browder spectrum of its diagonal entries. 相似文献
847.
Delipidation‐based solid‐phase extraction pretreatment technique for plasma broad‐coverage metabolomic profiling to reveal the potential pathogenesis of yeast‐induced fever in rats
下载免费PDF全文
![点击此处可从《Journal of separation science》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Mingxing Guo Shanshan Gao Qingqing Zhang Qing Wang Zhiwei Lu Huizhen Zhao Yuehong Liu Meiling Wang Shuang Fu Xu Bai Xiaoyan Gao 《Journal of separation science》2016,39(13):2616-2625
During the process of metabolomics profiling by using ultra high performance liquid chromatography coupled with time‐of flight mass spectrometry, blood sample pretreatment is a crucial step for biomarker discovery. Herein, in order to prevent the potential loss of metabolites and ion suppression phenomena caused by the proteins and phospholipids contained in blood fluids, a delipidation‐based solid‐phase extraction pretreatment technique for plasma broad‐coverage metabolomic profiling was performed. This technique can be summarized as a single extraction, a single elution of solid‐phase extraction plate, followed by four times measuring with electrospray ionization in positive and negative ion mode, respectively. This approach significantly increased the number of features detected in plasma, and 1572 features in positive mode and 1352 features in negative mode were detected, respectively. Besides, the stability and repeatability of the approach were greatly improved. For these advantages, the approach was employed to elucidate the potential pathogenesis of yeast‐induced fever in rats. The biomarkers associated with the pathogenesis of fever were shown to be related to amino acids metabolism and lipid metabolism. The delipidation‐based solid‐phase extraction pretreatment approach can provide a useful tool to reveal the pathological mechanisms of such systemic pathological process. 相似文献
848.
Development of a DNA‐Templated Peptide Probe for Photoaffinity Labeling and Enrichment of the Histone Modification Reader Proteins
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Xue Bai Dr. Congcong Lu Dr. Jin Jin Shanshan Tian Zhenchang Guo Pu Chen Dr. Guijin Zhai Shuzhen Zheng Prof. Xiwen He Dr. Enguo Fan Prof. Yukui Zhang Prof. Kai Zhang 《Angewandte Chemie (International ed. in English)》2016,55(28):7993-7997
Histone post‐translational modifications (HPTMs) provide signal platforms to recruit proteins or protein complexes to regulate gene expression. Therefore, the identification of these recruited partners (readers) is essential to understand the underlying regulatory mechanisms. However, it is still a major challenge to profile these partners because their interactions with HPTMs are rather weak and highly dynamic. Herein we report the development of a HPTM dual probe based on DNA‐templated technology and a photo‐crosslinking method for the identification of HPTM readers. By using the trimethylation of histone H3 lysine 4, we demonstrated that this HPTM dual probe can be successfully utilized for labeling and enrichment of HPTM readers, as well as for the discovery of potential HPTM partners. This study describes the development of a new chemical proteomics tool for profiling HPTM readers and can be adapted for broad biomedical applications. 相似文献
849.
Reply to: “Comment on Probing the Properties of Polynuclear Superhalogens without Halogen Ligand via ab Initio Calculations: A Case Study on Double‐Bridged [Mg2(CN)5]−1 Anions by Li et al. ”
下载免费PDF全文
![点击此处可从《Chemphyschem》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Jin‐Feng Li Miao‐Miao Li Dr. Hongcun Bai Yin‐Yin Sun Prof. Jian‐Li Li Dr. Bing Yin 《Chemphyschem》2016,17(18):2947-2947
850.