Synthesis in the diazasteroid group VI. A synthesis of 2,3-dimethoxy-15-methyl-8,15-diazaestra-1,3,5(10)triene

Homoveratrylamine (II) was condensed with 3-(2-carbomethoxyethyl)-1,3-dimethyl-2-pyrrol-idone (Ib) to furnish the corresponding amide (III), which was subjected to the Bischler-Napieralski reaction to afford the corresponding dihydroisoquinoline derivative (IV). Compound V was obtained by the reductive ring closure of Vila which was obtained by the hydrogena-tion of IV. The stereochemistry of V is proposed to have the anti-trans-trans quinolizidine conformation.     

Ab initio mo study on base stacking: Adenine-adenine interaction in single-stranded polyadenylic acid (Poly A)

The interaction energy for base stacking in single-stranded poly A is calculated by an ab initio MO method. The calculated value agrees well with the observed stacking enthalpy. Dispersion and charge transfer interactions are the main factors stabilizing the polynucleotide; the contribution of the former is dominant.     

Liquid-liquid equilibria for four ternary systems containing methanol and cyclohexane

Nagata, I., 1984. Liquid-liquid equilibria for four ternary systems containing methanol and cyclohexane. Fluid Phase Equilibria, 18: 83–92.Liquid-liquid equilibria have been obtained experimentally for the systems methanol-benzene-cyclohexane, methanol-toluene-cyclohexane, methanol-acetone-cyclohexane and methanol-2-propanol-cyclohexane at 298.15 K. The experimental results are compared with predicted values obtained from the UNIQUAC and extended UNIQUAC equations.     

Vapor—liquid equilibria for the ternary Ethanol—2-butanone—benzene system at 298.15 K

Vapor—liquid equilibrium data for the ternary ethanol—2-butanone—benzene system and its constituent binary systems at 298.15 K are presented. The results are correlated with the Wilson, original and modified UNIQUAC equations and the UNIFAC group contribution method.     

Biodegradable network elastomeric polyesters from multifunctional aliphatic carboxylic acids and poly(epsilon-caprolactone) diols

Biodegradable elastomeric network polyesters were prepared from multifunctional aliphatic carboxylic acids such as tricarballylic acid (Yt) or meso-1,2,3,4-butanetetracarboxylic acid (Xb) and poly(epsilon-caprolactone) (PCL) diols with molecular weights of 530, 1,250 and 2,000 g.mol-1. Prepolymers prepared by a melt polycondensation were cast from DMF solution and postpolymerized at 280 degrees C for various periods of times to form a network. The resultant films were transparent, flexible and insoluble in organic solvents. The network polyesters obtained were characterized by IR absorption spectra, WAXS, density measurement, DSC, and tensile test. YtPCL1250, and XbPCL1250 network polyester films showed good elastomeric properties with high ultimate elongation (540-590%), and low Young's modulus (2.5-3.3 MPa). The enzymatic degradation was estimated by the weight loss of network films in a buffer solution with Rhizopus delemar lipase at 37 degrees C. The degree and rate of degradation were significantly affected by the molecular weight of PCL diol, chemical structures of multifunctional aliphatic carboxylic acids and the morphology of network films. The changes in the solid states of network films during the degradation were also estimated by the results of DSC and WAXS. [see text]     

A complete calculation for direct detection of Wino dark matter

In the anomaly-mediated supersymmetry (SUSY) breaking scenario, neutral gaugino of SUL₍₂₎$\mathit{SU}{(2)}_L$ multiplet, Wino, can be the lightest SUSY particle and become a candidate for dark matter. We calculated scattering cross section of Wino dark matter with nucleon, which is responsible for direct detection of the dark matter, on the assumption that the SUSY particles and the heavier Higgs bosons have masses of the order of the gravitino mass in the SUSY standard model. In such a case, the Wino–nucleon coupling is generated by loop processes. We have included two-loop contribution to Wino–gluon interaction in the calculation, since it is one of the leading contributions to the Wino–nucleon coupling. It was found that the spin-independent scattering cross section with proton is ^{10−(46–48)} cm²${10}^{-(46\text{–}48)}{\text{cm}}^2$. While it is almost independent of the Wino mass, the result is quite sensitive to the Higgs boson mass due to the accidental cancellation.     

Photoluminescence of SrGa2S4:Sn,Re(=Ce, Gd) phosphors

The photoluminescence (PL) spectra, PL excitation spectra, color coordinates, and X-ray diffraction spectra are reported for SrGa₂S₄:Sn,Re(=Ce and Gd, respectively) phosphors. By mixing SrGa₂S₄:Sn,Ce phosphors with different Ce³⁺ concentrations, white emissions can be obtained under the excitation of a 340-nm UV LED. Emissions in the green to yellow color range can be obtained from SrGa₂S₄:Sn,Gd phosphors. The rare earth ions enhance the green emission band, which peaks at 534 nm, instead of the yellow one. The origin of this enhancement is discussed. The resonant energy transfer rates are estimated in the cases from Ce³⁺ to the green and yellow centers of Sn²⁺ and between the yellow centers and the green centers.