Color Appearance of a Patch Explained by RVSI for the Conditions of Various Colors of Room Illumination and of Various Luminance Levels of the Patch

Whenever we enter a space illuminated differently from a previous space whether in color or in illuminance, we can quickly adapt to the new atmosphere and can again perceive white for the originally white object; this is known as color constancy. This phenomenon is explained by rotation of the recognition axis of the recognized visual space of illumination (RVSI) toward the illumination color. The explanation then predicts that the color appearance of a test patch changes radically toward the opposite direction from the color of illumination when the physical property of the test patch is kept unchanged at a neutral white. This prediction was confirmed by Experiment 1, where eight different colors of illumination were employed. The test patch appeared very vivid in color and shifted toward the opposite direction from the color of the illumination. In RVSI theory the light source color mode is explained by the release of the test patch from the restriction of RVSI. The release can be achieved by increasing the luminance of the test patch and the color appearance of the patch should then return to its own color as it is no longer controlled by RVSI. In Experiment 2 these predictions were investigated by increasing the luminance of the test patch to a much higher level than that of the objects in the lit room fixed at an illuminance of about 1001x. The color appearance of the test patch indeed became the light source color and returned to the original neutral white. Emphasis was given in the course of the experiments that the subjects were observing the test patch presented in a real 3D space where the subjects also stayed inside so that they could properly construct RVSI for the space.     

Mechanism of isotope scrambling for CO2 laser photolysis of trifluoremethane-h and-d mixtures

The mechanism of isotope scrambling was studied for infrared multiphoton dissociation of trifluoromethane-h (CHF₃) and-d (CDF₃) mixtures by a CO₂ TEA laser. The CO₂ laser was tuned to the R(14) line of the 001–100 transition, where CDF₃ absorbs the light selectively. Although the highly selective decomposition of CDF₃ occurred at low partial pressures of CDF₃, significant decomposition of CHF₃ was also observed with increasing pressure of CDF₃. The selectivity (s) was found to depend only on the pressure of CDF₃, a resonant molecule, but not on that of CHF₃, an off-resonant molecule. The mechanism involving the formation of two kinds of vibrationally excited molecules, unimolecular decomposition (rate constantk ₂ ),V-V energy transfer (k _3b), and collisional deactivation leads to the simple relationship,s=1+(k ₂ /k _3b)/[CDF₃], which can explain qualitatively the observed results. The ratiok ₂ /k _3b has values of 20–200 Torr, probably depending on experimental conditions.     

Dianion of N-phenyl-2-(phenylsulfonylmethyl)propenamide: an efficient synthetic reagent for (E)-trisubstituted olefins and 5,6-dihydro-2H-pyrans

The dianion of N-phenyl-2-(phenylsulfonylmethyl)propenamide was found to be an efficient reagent for the synthesis of (E)-α,β-unsaturated amides and 5,6-dihydro-2H-pyrans.     

Cesium fluorohydrogenate, Cs(FH)2.3F

Cs(FH)_2.3F is a liquid salt exhibiting a low viscosity of 20.1 cP and a high conductivity of 86.3 mS cm⁻¹ at 25 °C, in spite of the relatively high melting point (16.9 °C). The high density of 2.82 g cm⁻³ at the liquid state is due to the heavy atomic weight and small size of cesium atom compared to the organic cations of general ionic liquids. The infrared spectroscopy indicates that this salt contains (FH)₂F⁻ as a main anionic species. The other anionic species such as (FH)₃F⁻ found in the cases of other M⁺(HF)_2.3F (M = a univalent organic cation) ionic liquid salts is not detected, suggesting its small abundance as well as the presence of neutral HF in the form of molecular and/or oligomers. The result of ¹H NMR also suggests that the anions exchange HF between them. These observations coincide with the experimental result that Cs(FH)_2.3F acts as an acid against general ionic liquid fluorohydrogenates such as EMIm(FH)_2.3F (EMIm = 1-ethyl-3-methylimidazolium) to lose HF and give Cs(FH)₂F precipitate.     

Naphthyridine‐Benzoazaquinolone: Evaluation of a Tricyclic System for the Binding to (CAG)n Repeat DNA and RNA

The expansion of CAG repeats in the human genome causes the neurological disorder Huntington's disease. The small‐molecule naphthyridine‐azaquinolone NA we reported earlier bound to the CAG/CAG motif in the hairpin structure of the CAG repeat DNA. In order to investigate and improve NA ‐binding to the CAG repeat DNA and RNA, we conducted systematic structure‐binding studies of NA to CAG repeats. Among the five new NA derivatives we synthesized, surface plasmon resonance (SPR) assay showed that all of the derivatives modified from amide linkages in NA to a carbamate linkage failed to bind to CAG repeat DNA and RNA. One derivative, NBzA , modified by incorporating an additional ring to the azaquinolone was found to bind to both d(CAG)₉ and r(CAG)₉. NBzA binding to d(CAG)₉ was similar to NA binding in terms of large changes in the SPR assay and circular dichroism (CD) as well as pairwise binding, as assessed by electron spray ionization time‐of‐flight (ESI‐TOF) mass spectrometry. For the binding to r(CAG)₉, both NA and NBzA showed stepwise binding in ESI‐TOF MS, and NBzA ‐binding to r(CAG)₉ induced more extensive conformational change than NA ‐binding. The tricyclic system in NBzA did not show significant effects on the binding, selectivity, and translation, but provides a large chemical space for further modification to gain higher affinity and selectivity. These studies revealed that the linker structure in NA and NBzA was suitable for the binding to CAG DNA and RNA, and that the tricyclic benzoazaquinolone did not interfere with the binding.     

Ion chromatographic determination of hydroxide ion on monolithic reversed-phase silica gel columns coated with nonionic and cationic surfactants

The determination of hydroxide by ion chromatography (IC) is demonstrated using a monolithic octadecylsilyl (ODS)-silica gel column coated first with a nonionic surfactant (polyoxyethylene (POE)) and then with a cationic surfactant (cetyltrimethylammonium bromide (CTAB)). This stationary phase, when used in conjunction with a 10 mmol/l sodium sulfate eluent at pH 8.2, was found to be suitable for the rapid and efficient separation of hydroxide from some other anions, based on a conventional ion-exchange mechanism. The peak directions and detection responses for these ions were in agreement with their known limiting equivalent ionic conductance values. Under these conditions, a linear calibration plot was obtained for hydroxide ion over the range 16 micromol/l to 15 mmol/l, and the detection limit determined at a signal-to-noise ratio of 3 was 6.4 micromol/l. The double-coated stationary phase described above was shown to be superior to a single coating of cetyltrimethylammonium bromide alone, in terms of separation efficiency and stability of the stationary phase. A range of samples comprising solutions of some strong and weak bases was analyzed by the proposed method and the results obtained were in good agreement with those obtained by conventional potentiometric pH measurement.     

Selective determination of ammonium ions by high-speed ion-exclusion chromatography on a weakly basic anion-exchange resin column

This paper describes an ion-exclusion chromatographic system for the rapid and selective determination of ammonium ion. The optimized ion-exclusion chromatographic system was established with a polymethacrylate-based weakly basic anion-exchange resin column (TSKgel DEAE-5PW) as the separation column, an aqueous solution containing 0.05 mM tetramethylammonium hydroxide (pH 9.10) as eluent with conductimetric detection for the analyte determination. Under the optimum chromatographic conditions, ammonium ion was determined within 2.3 min with a detection limit (S/N=3) better than 0.125 microM. Ammonium ion in rain and river waters was precisely determined using this ion-exclusion chromatographic system.     

Syntheses, structures and properties of 1-ethyl-3-methylimidazolium salts of fluorocomplex anions

Fluoroacid-base reactions of a room-temperature ionic liquid, 1-ethyl-3-methylimidazolium fluorohydrogenate (EMIm(HF)2.3F, EMIm = 1-ethyl-3-methylimidazolium cation), and Lewis fluoroacids (BF3, PF5, AsF5, NbF5, TaF5 and WF6) give EMIm salts of the corresponding fluorocomplex anions, EMImBF4, EMImPF6, EMImAsF6, EMImNbF6, EMImTaF6 and EMImWF7, respectively. Attempts to prepare EMImVF6 by both the acid-base reaction of EMIm(HF)2.3F with VF5 and the metathesis of EMImCl with KVF6 failed due to the strong oxidizing power of the pentavalent vanadium, whereas EMImSbF6 was successfully prepared only by the metathesis of EMImCl and KSbF6. EMImBF4, EMImSbF6, EMImNbF6, EMImTaF6 and EMImWF7 are liquids at room temperature whereas EMImPF6 and EMImAsF6 melts at around 330 K. Raman spectra of the obtained salts showed the existence of the EMIm cation and corresponding fluorocomplex anions. IR spectroscopy revealed that strong hydrogen bonds are not observed in these salts. EMImAsF6(mp 326 K) and EMImSbF6(mp 283 K) are isostructural with the previously reported EMImPF6. The melting point of the hexafluorocomplex EMIm salt decreases with the increase of the size of the anion (PF6- < AsF6- < SbF6- 相似文献   

New selenyl linker for solid-phase synthesis of dehydropeptides

A novel linker possessing selenocyanate and masked carboxylic acid was developed for the solid-phase synthesis of dehydropeptides. This linker was used to demonstrate the synthesis of the model compound of RGD-conjugated dehydropeptide.