零点约束矩阵滤波设计

为解决在空域预滤波阶段抑制强噪声的问题,提出了零点约束矩阵滤波设计方法,并给出了解的表达式。通过设计凸规划问题,在严格约束阻带响应等于零的情况下,使通带误差最小。将凸规划问题转换为线性约束二阶最优化问题,构造Lagrange函数并得到最优解,重排后得出滤波矩阵。仿真可知,本方法可设计出强干扰离散分布或处于某扇面的预滤波器,可用于解决常规波束形成算法受强干扰影响方位估计性能的问题。     

波束形成与独立分量分析融合的宽带高分辨方位估计方法

针对波束域高分辨方位估计存在方位估计偏差大等缺点,提出了将波束形成与独立分量分析融合的宽带高分辨方位估计方法:(1)阵元域数据转换到波束域后,对多波束数据利用基于二阶统计量的独立分量分析算法处理,(2)将波束域独立分量分析融合方法输出结果重构回阵元域信号,(3)对重构后的阵元域数据,使用约束最优化方法改进的MUSIC算法做高分辨方位估计。最后利用ICS (Interactre Circuts&System)声呐模拟器数据和海试数据对算法进行了验证。结果表明:本文方法在弱目标检测、观测区域外强干扰抑制、方位分辨率方面都优先于波束域MUSIC和波束MVDR方法。     

基于离散极大值法的太赫兹光谱特征吸收峰提取方法

太赫兹波在电磁波谱中介于微波和红外辐射之间,具有指纹特性、安全无损、强穿透性等特点,因此太赫兹光谱技术在药品成分和组成检测领域具有广泛应用价值。针对高纯度物质识别研究中存在部分弱吸收峰不易识别,以及混合物的太赫兹光谱中吸收峰强度降低而导致吸收峰位信息模糊化的问题,提出了一种基于离散极大值法的光谱吸收峰位识别方法,即伴随拐点法。伴随拐点法首先利用目标检测物太赫兹吸收系数谱图的一阶和二阶导数确定吸收峰位的伴随拐点和基线谱,其次将原始吸收光谱与基线谱进行差分运算得到差谱,最后根据离散极大值法确定吸收峰位,从而实现特征吸收峰的识别。为验证伴随拐点法的有效性,采用伴随拐点法对四种硝基呋喃类样品光谱进行吸收峰提取,并将吸收峰位识别结果与仿真结果进行比较。实验结果证明,伴随拐点法能有效识别目标检测物的强吸收峰和弱吸收峰。该方法不仅在含峰目标物的太赫兹特征吸收峰识别问题中具有广泛的应用前景,还适用于其他光谱的谱峰峰位检测。     

Syntheses,Crystal Structures and Antibacterial Activities of 5-Chloro-3-methyl-1-phenyl-1H-pyrazole-4-carboxylic Acid and Its Copper(Ⅱ) Compound

The title compounds 5-chloro-3-methyl-1-phenyl-1H-pyrazole-4-carboxylic acid(C11H9Cl N2O2, HL)(1) and [Cu(L)2(H2O)](2) were prepared and structurally characterized by elemental analysis, IR and single-crystal X-ray diffraction. Compound 1(C11H9Cl N2O2) crystallizes in the monoclinic system, space group P21/n with a = 7.249(3), b = 20.515(10), c = 7.249(3),β= 96.30°, V = 1071.6(9) ?3, Z = 4, Mr = 236.65, Dc = 1.467 g/cm3, F(000) = 488, GOOF = 1.029, μ= 0.341 mm-1, the final R = 0.0736 and w R = 0.1966 for 1500 observed reflections with I 2σ(I). Compound 2(C22H18Cl2Cu N4O5) crystallizes in the monoclinic system, space group P21/c with a = 7.2931(6), b = 24.548(2), c = 13.2726(11), β= 99.4040(10)°, V = 2344.2(3) ?3, Z = 4, Mr = 552.84, Dc = 1.566 g/cm3, F(000) = 1124, GOOF = 1.050, μ= 1.201 mm-1, the final R = 0.0376 and w R = 0.1000 for 3626 observed reflections with I 2σ(I). 1 and 2 are connected through hydrogen bonding interactions to generate 2D and 3D supramolecular structures, respectively. Moreover, the preliminary antibacterial activities of 1 and 2 against the gram positive bacteria(S. aureus, C. albicans and B. subtilis) and gram negative bacteria(E. coli and P. aeruginosa) have been tested by using the microdilution method, and the results indicate that 2 is more active than 1 against the tested bacteria.     

一种具有噪声估计能力的图像恢复正则化方法

利用小波为正则化方法提供了一种估计噪声能量的机制，根据估计得到的噪声能量，再利用经典正则化方法求解正则化参数，从而得到正则化解，实验结果表明估计噪声能量机制的正则化方法，在噪声能量和原图像能量信息未知的情况下，具有较快的计算程度和较好的恢复能力。     

DYNAMIC ANALYSIS OF AN AUTOMATIC WASHING MACHINE WITH A HYDRAULIC BALANCER

A mathematical model of a hydraulic balancer in steady state condition was derived from a whirling model of a vertical axis washing machine, with the aim of implementing a dynamic analysis of an automatic washing machine during spin drying mode. The centrifugal force acting on the hydraulic balancer depends on the centroidal distance of the fluid in the hydraulic balancer, and the centroidal distance is a function of an eccentricity of the geometric center of the hydraulic balancer from the axis of rotation. A mathematical model of the hydraulic balancer in steady state is validated by the experimental result of the centrifugal force. Experiments were performed on a washing machine during spin drying mode, and results were compared with the simulation result. The parameters affecting the vibration of the washing machine were investigated by the parameter study.     

LaNi5的硫化物中毒及其再生的表面研究

本文概括了氢气中的硫化物(如H₂S,SO₂和CS₂)对LaNi₅的表面中毒和再生。AES,XPS的分析表明,三种硫化物的中毒性质不同:H₂S中毒产生La₂S₃和NiS这样的表面化合物;SO₂和CS₂中毒分别发生化学吸附和物理吸附。此外,从Ni(2P_3/2)谱峰强度变化,表明了在LaNi关键词：     

探索性问题设计方法八种

给出了设计探索性问题的八种方法     

EuMO3的XPS和Mossbauer谱研究

对ＥｕＭＯ３进行了ＸＲＤ、ＸＰＳ、ＩＲ和＾１５１Ｅｕ Ｍｏｓｓｂａｕｅｒ谱测量，研究了晶胞参数与离子半径、Ｅｕ４ｄ光电子峰的结合能、同质异能移位的关系。结果表明，Ｅｕ４ｄ结合能和同质异能移位均与Ｂ位离子Ｍ的变化有关，且结合能与同质异能移位成线性关系。     

水合高氯酸盐+有机溶剂体系中氢氧化物电沉积的EQCM研究

采用电化学石英晶体微天平(EQCM)定量研究了含水合高氯酸盐的丙酮、DMF、DMSO、C2H5OH或CH3OH有机溶液中LiOH(或NaOH)的电沉积过程. 这种电沉积现象可归因于有机溶液中的溶解氧和共存水在负电位下电还原产生OH−, OH−与溶液中金属阳离子结合生成在非水溶剂中溶解度很小的氢氧化物而沉淀在电极表面, 从而引起压电参数的响应, 而使用四丁基溴化铵为支持电解质时这种现象不明显. 讨论了不同支持电解质、不同溶剂、支持电解质浓度和外加水浓度对氢氧化物电沉积的影响, 估算了氢氧化物沉淀的电极收集效率.