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891.
S. V. Litvinenko V. I. Savich L. D. Bobrovnik 《Chemistry of Heterocyclic Compounds》1994,30(3):340-344
We have developed a method for synthesis of N-(3-clzloro-2-quinoxalyl)sulfonamides by reaction of 2,3-dichloroquinoxaline with substituted arylsufonamides. Based on the IR spectra, we have established that in the solid state, the synthesized compounds exist in the form of amide tautomers. Alkylation of these compounds leads to N-metliyl-N-(3-chloro-2-quinoxalyl)arylsulfonamides. We demonstrate the possibility of nucleophilic substitution of the halogen upon treatment with O- and N-nucleophiles. The use of bifunctional nucleophiles leads to condensed quinoxalines.Translated from Khimiya Geterotsiklicheskikh Soedinenii, Vol. 30, No. 3, pp. 387–392, March, 1994. 相似文献
892.
The reaction of 2-(2 pyridytcarbonyl)benzoic acid with thionyl chloride affords an unexpected product of the intramolecular acylation of the pyridine nitrogen atom, namely, 6,11-dioxo-6,11-dihydrobenzo[blquinotizinium chloride. At the same time, 2-(2-quinotylcarbonyl)benzoic acid forms the expected cyclic acid chloride, namely, 3-(2-gitinotyl)-3-chlorophthalide in this reaction. Both compounds acylate ammonia and primary amines, including those with bulky alkyl groups (tert-butyl, 1-adamantyl, and 1,1,3,3-tetramethylbutyl) with the formation of 2-R-3-hydroxy-3-(2pyridyl- or 2-quinolyl)isoindolines. The protonation of the pyridine nitrogen atom of N-(1,1,3,3-tetramethylbutyl)-2-(2pyridylcarbonyl)benzamide, obtained in the open amide form, is accompanied by the closing of the isoindotinone ring; the deprotonation is accompanied by ring opening.Riga Technical University, Riga LV-1048. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 499–504, April, 1994. Original article submitted March 17, 1994. 相似文献
893.
894.
V. D. Orlov Z. Kaluski N. P. Borob'eva E. Figas A. A. Tishchenko F. G. Yaremko 《Chemistry of Heterocyclic Compounds》1994,30(8):964-971
We have measured the PMR spectra of 5, 7-diaryl-1, 4-diazabicyclo[4. ].O]hept-4-enes. We have studied the structure of the 5-(4-nitrophenyl)-7-phenyl derivative by x-ray diffraction. We show that the six-membered heterocycle has the half-chair form. The 6-H and 7-H protons of the aziridine ring are trans, while the 7-aryl is exo relative to the six-membered ring. Introduction of substituents into the aromatic ring has practically no effect on the geometry of the bicycle.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1117–1124, August, 1994.For Communication 11, see [1]. 相似文献
895.
896.
Ya. Stradyn 《Chemistry of Heterocyclic Compounds》1994,30(3):377-379
897.
É. Abele Yu. Popelis É. Lukevits M. Shimanska Yu. Gol'dberg 《Chemistry of Heterocyclic Compounds》1994,30(1):14-19
Alkylation of 2 furanyl- and 2-thienylalkyl ketoximes with alkyl, allyl, and propargyl halides in the two phase catalytic system sol. K2CO3/C6H6/18-crown-6 at room temperature causes the formation of mixtures of E- and Z-isomers of the corresponding O-ethers with yields of 32–74%. Partial E/Z-isomerization takes place during the reaction.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 18–23, January, 1994. 相似文献
898.
G. D. Krapivan N. I. Val'ter T. Ya. Kaklyugina V. G. Kul'nevich 《Chemistry of Heterocyclic Compounds》1994,30(3):289-295
Halogen in positions 3 and 5 of the furan ring in ftirfurylidenedioxanediones is readily replaced by dithiocarbonate, dithiocarbatnate, dithiophosphate, thiocyanate, and azide anions, and by thiourea, and secondary and tertiary amines. The conformation of the initial halogen derivative is retained in the substitution products.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 327–334, March, 1994. 相似文献
899.
M. A. Mikhaleva B. M. Bolotin T. A. Kizner E. S. Serebrykova 《Chemistry of Heterocyclic Compounds》1994,30(1):79-81
We have synthesized 5-alkyl(alkoxy)-2-(o-lzydroxy-p-alkoxyphenyl)pyrimidines and considered the effect of the OH group on the inesomorphism. We have found that in binuclear o-hydroxyarylpyrimidines, an ortho OH group forming an intramolecular hydrogen bond increases Tmp, inhibits the appearance of nematic properties, and promotes the appearance of a smectic A.Translated from Khimiya Geterotsiklicheskikh Soedinenii, Vol. 30, No. 1, pp. 90–92, January, 1994. 相似文献
900.
By changing the conditions of the electrohydraulic treatment of aqueous plant heterodisperse systems comparatively high degradation
of the lignin component of plant tissue has been achieved. In addition to free monosaccharides, their reduced forms have been
detected in the aqueous phase.
Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, fax (3712) 89
14 75. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 795–798, November–December, 1994. 相似文献