Complementary regioselective esterification of non-reducing oligosaccharides catalyzed by different hydrolases

The enzymatic transesterification of several tri- and tetrasaccharides with vinyl laurate is described. The lipases from Candida antarctica B (Novozym 435) and Thermomyces lanuginosus (Lipozyme TL IM) and the alkaline protease from Bacillus licheniformis (subtilisin Carlsberg) have been used with each carbohydrate to obtain different regioisomers. By using the sugars in their amorphous form, complete solubility is achieved in the reaction media (tert-butanol/pyridine mixtures for the lipases and pyridine for the protease) and high isolated yields of the corresponding monoesters are obtained. Good to excellent regioselectivity is observed for all the enzymes, showing a final complementary picture respect to the primary hydroxyls of the oligosaccharides studied.     

配送量不定的供应链协调

本文研究供应链管理中配送量不确定时，制造商和分销商之间的协调问题。通过建立惩罚和奖励机制模型来协调供应链各部分的运作，使得分散系统就如一个整体。同时分析供应链的利润分配问题，分别得出各个机制下分销商的最优决策。     

The study and applications of photochemical-dynamical gravity wave model I

A two-dimensional, nonlinear, compressible, diabatic, nonhydrostatic photochemical-dynamical gravity wave model has been advanced. The model includes diabetic process produced by photochemistry and the effect of gravity wave on atmospheric chemical species. In the horizontal direction, the pseudospectral method is used. The finite difference approximations are used in vertical direction z and time t. The FICE method is used to solve the model. The model results on small amplitude fluctuation are very close to those of linear theory, which demonstrates the correctness of the model.

     

直流磁控溅射一步法原位制备MgB2超导薄膜

用MgB2靶,控制直流磁控溅射工作在异常辉光放电或弧光放电状态,在SrTiO3衬底上原位一次性得到了MgB2超导薄膜,其起始转变温度为32K,零电阻温度为15K. 关键词： 高温超导体 超导薄膜 磁控溅射 二硼化镁     

A Class of Two-mode Nonclassical State via Generalize Super Positions of Two-mode Coherent States

A new method is introduced to generate a elliptical hollow beam inside a cavity. Using a matrix eigenvalue method, the laser resonator with optical diffraction elements is theoretically analyzed and simulated. A elliptical hollow beam of good quality is realized experimentally. The interaction between linearly polarized elliptical hollow beam and a two-level atom is investigated theoretically. Although the linearly polarized elliptical hollow beam does not carry angular momentum, it can produce very high torque. The atoms initially at rest and located at off-beam- axis positions will rotate under the drive of the torque of the beam. The atomic motion trajectory in the field of elliptical hollow beam has been demonstrated. The study shows that the elliptical hollow beam might be a useful tool in the study of vortex property of Bose-Einstein condensate or ultra cold atom media.     

Enantiodiscrimination of racemic electrophiles by diketopiperazine enolates: asymmetric synthesis of methyl 2-amino-3-aryl-butanoates and 3-methyl-aspartates

Enolates of (S)-N,N′-bis-(p-methoxybenzyl)-3-iso-propylpiperazine-2,5-dione exhibit high levels of enantiodiscrimination in alkylations with (RS)-1-aryl-1-bromoethanes and (RS)-2-bromoesters, affording substituted diketopiperazines containing two new stereogenic centres in high de. Deprotection and hydrolysis of the resultant substituted diketopiperazines provides a route to the asymmetric synthesis of homochiral methyl 2-amino-3-aryl-butanoates and 3-methyl-aspartates in high de and ee.     

一类(0,1)-矩阵的最大积和式的积分表达式

给出了线和n-2的n阶（0，1）－矩阵的最大积和式的积分表达式，并证明了该积分表达式与[1]得到的组合表达式等价。     

5D Dirac Equation in Induced-Matter Theory

According to an induced-matter approach, Liu and Wesson obtained the rest mass of a typical particle from the reduction of a 5D Klein–Gordon equation to a 4D one. Introducing an extra-dimension momentum operator identified with the rest mass eigenvalue operator, we consider a way to generalize the 4D Dirac equation to 5D. An analogous normal Dirac equation is gained when the generalization reduces to 4D. We find the rest mass of a particle in curved space varies with spacetime coordinates and check this for the case of exact solitonic and cosmological solution of the 5D vacuum gravitational field equations.     

利用振幅调制器进行光电负反馈抑制激光强度噪声

采用振幅调制器作为抑制激光强度噪声的元件，首先对光电负反馈回路进行了简要的理论分析，然后利用该光电负反馈进行抑制激光二极管抽运全固化单频环形Nd:YVO4红外激光器强度噪声的实验。结果表明，在0－1MHz的低频段，强度噪声大幅度降低，最大降低约15dB。     

The study and applications of photochemical-dynamical gravity wave model II

A nonlinear, compressible, non-isothermal gravity wave model that involves photochemistry is used to study the effects of gravity wave on atmospheric chemical species distributions in this paper. The changes in the distributions of oxygen compound and hydrogen compound density induced by gravity wave propagation are simulated. The results indicate that when a gravity wave propagates through a mesopause region, even if it does not break, it can influence the background distributions of chemical species. The effect of gravity wave on chemical species at night is larger than in daytime.