Active cancellation of occlusion: an electronic vent for hearing aids and hearing protectors

The occlusion effect is commonly described as an unnatural and mostly annoying quality of the voice of a person wearing hearing aids or hearing protectors. As a result, it is often reported by hearing aid users as a deterrent to wearing hearing aids. This paper presents an investigation into active occlusion cancellation. Measured transducer responses combined with models of an active feedback scheme are first examined in order to predict the effectiveness of occlusion reduction. The simulations predict 18 dB of occlusion reduction in completely blocked ear canals. Simulations incorporating a 1 mm vent (providing passive occlusion reduction) predict a combined active and passive occlusion reduction of 20 dB. A prototype occlusion canceling system was constructed. Averaged across 12 listeners with normal hearing, it provided 15 dB of occlusion reduction. Ten of the subjects reported a more natural own voice quality and an appreciable increase in comfort with the cancellation active, and 11 out of the 12 preferred the active system over the passive system.     

Nonequilibrium fluctuations from a nematic under a thermal gradient and a gravity field*

We use a fluctuating hydrodynamics (FH) approach to study the fluctuations of the hydrodynamic variables of a thermotropic nematic liquid crystal (NLC)in a nonequilibrium steady state (NESS). This NESS is produced by an externally imposed temperature gradient and a uniform gravity field. We calculate analytically the equilibrium and nonequilibrium seven modes of the NLC in this NESS. These modes consist of a pair of sound modes, one orientation mode of the director and two visco-heat modes formed by the coupling of the shear and thermal modes. We find that the nonequilibrium effects produced by the external gradients only affect the longitudinal modes. The analytic expressions for the visco-heat modes show explicitly how the heat and shear modes of the NLC are coupled. We show that they may become propagative, a feature that also occurs in the simple fluid and suggests the realization of new experiments. We show that in equilibrium and in the isotropic limit of the NLC, our modes reduce to well-known results in the literature. For the NESS considered we point out the differences between our our modes and those reported by other authors. We close the paper by proposing the calculation of other physical quantities that lend themselves to a more direct comparison with possible experiments for this system.     

Theoretical study of the smiles rearrangement in the activation mechanism of proton pump inhibitors

This work describes the conformational behavior and the activation mechanism of timoprazole and substituted prazoles from the most stable conformation to the sulphenic acid. The stability of the conformers can be explained by the presence of hydrogen bonds, stereoelectronic effect because of the lone pair of sulfur atom and the N^…C and N^…S interactions. The first step of the Smile rearrangement is a nucleophilic addition to benzimidazole by pyridine moiety, which depends on the difference of the electron population of the atoms involved in the attack. The second step produces sulphenic acid by a concerted reaction where breaking of the S–C bond goes along with a proton migration, and is determined by the electron population of the sulfur atom. Copyright © 2011 John Wiley & Sons, Ltd.     

Surface wave effect on light scattering from one-dimensional photonic crystals

Light scattering and reflection measurements using attenuated total reflection technique for s polarization of the incident light on a finite one-dimensional photonic crystal are reported. Angular specular reflection was measured experimentally to determine, the optimum thickness, the angular position of the surface mode, and the number of bi-layers of the system. It was demonstrated that the position of the surface mode inside the last film is close to the asymptotic value when the number of periods is increased. Spectral reflection measurements were made to determine experimentally the band gap width and measure the dispersion relation of the surface mode inside this band. The corresponding field amplitude was calculated (∣E∣²) showing that in resonant conditions it has a maximum near the surface. The angular dependence of the scattered light measured displays a peak caused by singles cattering and located approximately at the excitation angle of the surface electromagnetic mode. When the incident light is in resonance with the surface electromagnetic wave, it is found experimentally that the scattering of light is enhanced overall by approximately one order of magnitude in comparison with the off-resonance case.     

Modelling of optical absorption of silver NP’s produced by UV radiation embedded in mesostructured silica films

Hexagonal mesostructured films containing silver ions were obtained by sol–gel method. Brij 58 was used to produce channels into the film, which house these ions. The films were exposure to UV radiation to produced silver metallic nanoparticles. The presence of the metallic nanoparticles was determined by infrared spectroscopy and optical absorption. Besides, these nanoparticles and core–shell structures of silver–silver oxide nanoparticles were identified by high-resolution transmission electronic microscopy. From these measurements, the obtained size range for silver nanoparticles was 6.1 nm. The absorption spectrum located at 440 nm was modelled and well fitted with the Gans theory considering refractive index higher than the one coming from host matrix. This index is explained because the silver oxide shell modifies the local surrounding medium of the metallic nanoparticles.     

Atomistic modeling of Zn deposition on the low index faces of Cu

The formation process of Zn/Cu surface alloys is investigated using the Bozzolo-Ferrante-Smith (BFS) method for alloys. The effects of the crystallographic orientation on the deposition process, formation of surface alloys as a function of temperature and coverage, Zn surface migration, and interdiffusion in the Cu substrate, are modeled and discussed with atom-by-atom energy analyses and large scale simulations.     

Signatures of short-range many-body effects in the dielectric function of silicon for finite momentum transfer

We present an investigation of the dynamic structure factor and of the dielectric function epsilonM(Q,omega) of the prototypical semiconductor silicon for finite momentum transfer, combining inelastic x-ray scattering experiments and ab initio calculations. In contrast with optical spectra, for finite momentum transfer time-dependent density-functional theory in the adiabatic local-density approximation together with lifetime broadening describes the physics of valence excitations correctly. Major structures in the spectra, governed by short-range crystal and exchange-correlation local-field effects, are strongly influenced by a mixing of transitions of positive and negative energies, in striking difference to spectra for vanishing momentum transfer. This mixing gives rise to a pronounced Fano asymmetry.     

XANES speciation of mercury in three mining districts – Almadén,Asturias (Spain), Idria (Slovenia)

The mobility, bioavailability and toxicity of mercury in the environment strongly depend on the chemical species in which it is present in soil, sediments, water or air. In mining districts, differences in mobility and bioavailability of mercury mainly arise from the different type of mineralization and ore processing. In this work, synchrotron‐based X‐ray absorption near‐edge spectroscopy (XANES) has been taken advantage of to study the speciation of mercury in geological samples from three of the largest European mercury mining districts: Almadén (Spain), Idria (Slovenia) and Asturias (Spain). XANES has been complemented with a single extraction protocol for the determination of Hg mobility. Ore, calcines, dump material, soil, sediment and suspended particles from the three sites have been considered in the study. In the three sites, rather insoluble sulfide compounds (cinnabar and metacinnabar) were found to predominate. Minor amounts of more soluble mercury compounds (chlorides and sulfates) were also identified in some samples. Single extraction procedures have put forward a strong dependence of the mobility with the concentration of chlorides and sulfates. Differences in efficiency of roasting furnaces from the three sites have been found.