全文获取类型
收费全文 | 3433篇 |
免费 | 588篇 |
国内免费 | 353篇 |
专业分类
化学 | 2727篇 |
晶体学 | 40篇 |
力学 | 185篇 |
综合类 | 14篇 |
数学 | 330篇 |
物理学 | 1078篇 |
出版年
2024年 | 14篇 |
2023年 | 67篇 |
2022年 | 124篇 |
2021年 | 128篇 |
2020年 | 178篇 |
2019年 | 169篇 |
2018年 | 149篇 |
2017年 | 122篇 |
2016年 | 189篇 |
2015年 | 201篇 |
2014年 | 195篇 |
2013年 | 290篇 |
2012年 | 320篇 |
2011年 | 339篇 |
2010年 | 203篇 |
2009年 | 177篇 |
2008年 | 241篇 |
2007年 | 174篇 |
2006年 | 173篇 |
2005年 | 135篇 |
2004年 | 128篇 |
2003年 | 114篇 |
2002年 | 90篇 |
2001年 | 74篇 |
2000年 | 48篇 |
1999年 | 57篇 |
1998年 | 32篇 |
1997年 | 29篇 |
1996年 | 33篇 |
1995年 | 26篇 |
1994年 | 28篇 |
1993年 | 16篇 |
1992年 | 17篇 |
1991年 | 10篇 |
1990年 | 23篇 |
1989年 | 10篇 |
1988年 | 12篇 |
1987年 | 5篇 |
1986年 | 7篇 |
1985年 | 2篇 |
1984年 | 10篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1977年 | 2篇 |
1974年 | 1篇 |
排序方式: 共有4374条查询结果,搜索用时 15 毫秒
71.
对临床、病理、放射线或CT检查确诊的82名癌肿患者,在放疗前后和对42名健康人进行了微量元素铁、锌、铜、锰、硒,铬、钴、镍的分析。研究结果显示:1.癌肿患者血清铜、镍、锰、铬、钴的含量比健康人高,而血清锌、铁、硒的含量却比健康人低;2.血清Cu/Zn、Cr/Zn、Co/Zn、Ni/Zn的比值癌肿患者均比健康人高,而Fe、Zn、Se/Zn的比值却相反。因此,可根据血清铜升高、血清锌降低,血清铜/锌比值升高的特点。用于癌肿的早期诊断;3.癌肿患者放疔后血清铁、锌含量进一步下降,铜、锰、铬的含量也出现降低,唯有硒的含量有所上升。因此,放疗时应注意补充铁、锌、铜元素。 相似文献
72.
73.
We present an algorithm for numerically computing an absolutely continuous invariant measure associated with a piecewiseC
2 expanding mappingS: on a bounded region R
N. The method is based on the Galerkin projection principle for solving an operator equation in a Banach space. With the help of the modern notion of functions of bounded variation in multidimension, we prove the convergence of the algorithm. 相似文献
74.
75.
Supported iron tetrasulfophthalocyanine can efficiently catalyze the degradation of organic pollutants by H2O2 under visible light irradiation in an aqueous solution, and the catalyst can be easily recycled without apparent loss of activity. 相似文献
76.
A new triterpenoid saponin was isolated by bioactivity-guided isolation from "Gualou-xiebai-baijiu-tang" consisting ofFructus trichosanthisi and Bulbus allii macrostemi. Its structure was determined as 3-O-β-D-galactopyranosyl-hederagenin 28-O-β-D-xylopyranosyl (1→6)- β-D-galactopyranosyl ester by means of chemical evidences and spectral analysis. 相似文献
77.
Fokin AA Kiran B Bremer M Yang X Jiao H von Rague Schleyer P Schreiner PR 《Chemistry (Weinheim an der Bergstrasse, Germany)》2000,6(9):1615-1628
A series of charged and neutral four-center n-electron (4c-ne, n = 1-4) molecules based on the adamantane framework, but which include combinations of boron, nitrogen, and phosphorus atoms at bridgehead positions, were studied computationally at the B3LYP/6-31G* level of density functional theory (DFT). The three-dimensional aromaticity, observed earlier for the 1,3,5,7-bisdehydroadamantane dication (1), is found to be general for 4c-2e electron systems. The degree of electron delocalization, evaluated by energetic, geometric, and various magnetic criteria, is quite independent of the molecular symmetry (point groups vary from Td to Cs), the degeneracy of the orbitals, the molecular charges, and the nature of the atoms participating in the delocalized bonding. Although the multiple positive (e.g., in 1 and some of the heteroatom systems) and multiple negative charges are strongly repulsive, the rigid adamantane frameworks help hold the bridgehead atoms within bonding distances with the fewer available electrons. The corresponding 4c-1e doublets are approximately half as aromatic as the 4c-2e singlets based on the same criteria. However, the three-electron systems may either adopt distorted but still four-center delocalized structures, or alternative 3c-2e two-dimensional arrangements in which the fourth bridgehead atom is more distant. There is no need to derive special rules for each point group for 4c-ne systems. Although the three-dimensional stabilization is computed to be quite appreciable, ranging between 10 and 50 kcalmol(-1), this delocalization energy is generally not sufficient to overcome distortion due to strain in higher homologues of 1 and in analogous noncage systems. Among the various 4c-2e homoadamantanedehydro dications studied, only the 1,8-dehydrohomoadamandiyl-3,6-dication forms a three-dimensional aromatic system. 相似文献
78.
The contamination of foods with ochratoxin A can be determined very sensitively by high-performance liquid chromatography (HPLC) with fluorescence detection. A novel procedure is described to confirm OA-positive results quantitatively down to the HPLC detection limit of 0.1 ppb. For this, ochratoxin A in the sample extract is converted into its O-methylochratoxin A methyl ester derivative, which is identified subsequently by gas chromatography-mass spectrometry negative-ion chemical ionization and multiple ion detection modes using the hexadeuterated O-methyl-d3-ochratoxin A methyl-d3 ester derivative as internal standard for quantification. In the analysis of more than 60 contaminated samples, the procedure was found to be very accurate. 相似文献
79.
Zhang H Hong K Jablonsky M Mays JW 《Chemical communications (Cambridge, England)》2003,(12):1356-1357
Use of a room temperature ionic liquid as the medium for conventional free radical copolymerization of styrene and methyl methacrylate resulted in reactivity ratios that were significantly different from those obtained in conventional organic solvents or in bulk, demonstrating that polymerization in this alternative medium offers potential to create copolymers having new monomer sequences. 相似文献
80.