One-sided omnidirectional constant transmission between two isotropic media

In this paper, the reflection and transmission at the planar interface between an isotropic achiral medium (IAM) and an isotropic chiral medium (ICM) are theoretically studied. For one of the circularly polarized (CP) waves fullfilling the wavenumber matching condition incident from IAM with incident angle from 0 to π/2, the amplitude reflection and transmission coefficients are constant. The phenomenon is called the omnidirectional constant transmission (OCT). In the situation of CP waves incident from ICM, OCT will not occur, but the absolute values of the amplitude reflection and transmission coefficients can be constants in a range of incident angle under certain conditions. It is suggested that for OCT to occur, both the wavenumber matching condition and the mode matching condition should be satisfied.     

Solid-phase photocatalytic degradation of polystyrene plastic with goethite modified by boron under UV-vis light irradiation

A novel photodegradable polyethylene-boron-goethite (PE-B-goethite) composite film was prepared by embedding the boron-doped goethite into the commercial polyethylene. The goethite catalyst was modified by boron in order to improve its photocatalytic efficiency under the ultraviolet and visible light irradiation. Solid-phase photocatalytic degradation of the PE-B-goethite composite film was carried out in an ambient air at room temperature under ultraviolet and visible light irradiation. The properties of composite films were compared with those of the pure PE films and the PE-goethite composite films through performing weight loss monitoring, scanning electron microscope (SEM) analysis, FT-IR spectroscopy and X-ray photoelectron spectroscopy (XPS). The photo-induced degradation of PE-B-goethite composite films was higher than that of the pure PE films and the PE-goethite composite films under the UV-irradiation, while there has been little change under the visible light irradiation. The weight loss of the PE-B-goethite (0.4 wt.%) composite film reached 12.6% under the UV-irradiation for 300 h. The photocatalytic degradation mechanism of the composite films was briefly discussed.     

Laser-induced damage and periodic stripe structures of a CaF_2 single crystal by an ArF excimer laser

The laser-induced damage threshold of a calcium fluoride(CaF2)single crystal was obtained by a 193 nm ArF excimer laser.The damage morphology of the crystal was analyzed.The results showed that the surface of CaF2 single crystal broke along the natural cleavage plane under ArF excimer laser irradiation,some fragments fell off,and Newton’s rings were observed on the curved fragments.Laser-induced periodic stripe structures(LIPSS)appeared on the surface layer beneath the fragments that peeled off.The spacing of LIPSS was measured,and the formation mechanism of LIPSS was analyzed based on the interference model.     

应用高速莫尔形貌法测量飞弹偏角

本文提出了利用飞弹表面的高速莫尔形貌所包含的三维信息测量飞弹偏角的新方法。对于攻角而言,该方法可以从一张照片上,同时判读得到飞弹攻角在两个垂直面内的分量,从而简化了实验设备。文中,推导了有关计算公式,并对各个参数进行了误差分析;介绍了从静态到动态莫尔形貌的三步实验。实弹结果表明,用该方法可以精确地测量飞弹攻角。     

时间序列动态散斑相关跟踪测量原理及其应用

在对散斑场的特性进行研究与分析的基础上,提出了时间序列动态散斑相关跟踪测量法,它弥补了一般散斑相关法不适合大变形测量的缺点,扩大了散斑相关法的应用范围.运用这种方法不仅可以测量大动态范围的面内变形,而且可以测量分析面内动态变形过程和变形速度.     

A Two‐Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis,Structure, and Reactivity

The synthesis, structural characterization, and reactivity of the first two‐coordinate cobalt complex featuring a metal–element multiple bond [(IPr)Co(NDmp)] ( 4 ; IPr=1,3‐bis(2′,6′‐diisopropylphenyl)imidazole‐2‐ylidene; Dmp=2,6‐dimesitylphenyl) is reported. Complex 4 was prepared from the reaction of [(IPr)Co(η²‐vtms)₂] (vtms=vinyltrimethylsilane) with DmpN₃. An X‐ray diffraction study revealed its linear C Co N core and a short Co N distance (1.691(6) Å). Spectroscopic characterization and calculation studies indicated the high‐spin nature of 4 and the multiple‐bond character of the Co N bond. Complex 4 effected group‐transfer reactions to CO and ethylene to form isocyanide and imine, respectively. It also facilitated E H (E=C, Si) σ‐bond activation of terminal alkyne and hydrosilanes to produce the corresponding cobalt(II) alkynyl and cobalt(II) hydride complexes as 1,2‐addition products.     

富稀土YAG的确定

掺铵或掺钕和镥的钇铝石榴石至今仍是最好的激光晶体而被广泛地应用。钇铝石榴石的化学计量学至今未研究过。不时地怀疑在石榴石组成的邻近存在固溶体。这些问题具有重大的理论和实际意义。本文分析了用引上法生长的两种掺杂的13组YAG晶体。证明其组成与熔体组成、生长条件和炉内气氛无关,都是富稀土的。首次确定了这种晶体的化学式及其组成的变动范围。     

短波长三维光子晶体

本文提出了一种新型三维光子晶体—组合式三维光子晶体,它是由数块一维光子晶体组合而成的封闭式结构.从理论上论证了它的可行性.指出在短波长工作区域,这种新型光子晶体的制造工艺简单易行.文中给出并讨论了三个例子.     

The deflected angle and reflected displacement of Airy beams

The deflected angle of airy beams is defined to describe their bending degree. Based on this parameter, we analyze the lateral displacement of airy beams and the changes of deflected angles during reflection process. In multi-reflections of airy beams, we find that deflected angles increase linearly with the times of reflection, which is useful to study the propagation properties of airy beam in parallel plate waveguides and other waveguides. Also we can use this parameter to control the incident and reflected routes to realize airy beam bypassing obstacles and reflecting back at predictable location.     

高斯光束衍射测量中暗点漂移的研究

在丝径的激光高精度衍射测量中,激光的偏振方向、光束的几何属性和光束中心对衍射体对称中心的偏离都会影响测量的结果.本文从测量的角度对后二者的影响进行较为深入的研究.在理论研究的基础上,进行了计算机模拟,最后提出处理结果的方法.