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961.
For the first time, a new method is described for the determination of scandium based on the cathodic adsorptive stripping of the scandium-alizarin red S complex onto a carbon paste electrode. The second-order derivative linear scan voltammograms of the complex are recorded by use of model JP-303 polarographic analyzer from 0.0 to -1.0 V (versus SCE). Optimum conditions are found to be: an acetic acid (0.36 mol l(-1))-potassium biphthalate (0.064 mol l(-1)) buffer solution (pH 4.0) containing 2.0x10(-5) mol l(-1) alizarin red S, a preconcentration potential of 0.0 V, a preconcentration time of 60 s, a rest time of 10 s and a scan rate of 100 mV s(-1). The results show that the complex can be adsorbed on the surface of a carbon paste electrode, yielding one peak at -0.58 V, corresponding to the reduction of alizarin red S in the complex at the electrode. The detection limit is found to be 6.0x10(-10) mol l(-1) for 3 min of preconcentration time. The linear range is 1.0x10(-9) to 4.0x10(-7) mol l(-1). Application of the procedure to the determination of scandium in the ore samples gave good results. 相似文献
962.
Wang Y Deng K Gui L Tang Y Zhou J Cai L Qiu J Ren D 《Journal of colloid and interface science》1999,213(1):270-272
Nanoscopic particles of oxovanadium phthalocyanine (VOPc, phase-II) with different particle sizes are prepared by aggregation of VOPc molecules in the presence of surfactants for the first time. A size effect in the region of nanoscale was observed in the UV-visible spectra. The photoconductivity of the nanoscopic VOPc is much higher than that of bulk VOPc. Copyright 1999 Academic Press. 相似文献
963.
964.
The new chromophore compounds with NLO properties were prepared by Knoevenagel condensation from forrnyl or diformyl calix[4/arene and isophorone derivatives in the presence of piperidine and acetic acid, respectively. In these chromophore calix[4]arenes, the ring locked trienes were employed as the conjugation bridge and electron acceptor in D-π-A units. The NMR spectra demonstrated that they existed in a cone conformation and consequently non-conjugated D-π-A units could be oriented at nearly the same direction. 相似文献
965.
JPC – Journal of Planar Chromatography – Modern TLC - A new bonded RP-18 sintered silica gel plate for use in reversed-phase planar electrochromatography has been prepared in our... 相似文献
966.
[Reaction: see text] We report a one-step, racemization-free method for the diversification of peptide thiazoles via direct lithiation of the thiazole ring. The method is compatible with N-Boc, N-trityl, carboxylic ester, and carboxamide protecting groups and has been used to directly functionalize the thiazole ring of cyclopeptide natural products. 相似文献
967.
Pei J Chen H Liu Z Han X Wang Q Shen B Zhou J Lai L 《Journal of chemical information and modeling》2005,45(6):1920-1933
To address the problems associated with molecular conformations and alignments in the 3D-QSAR studies, we have developed the Flexible Ligand - Atomic Receptor Model (FLARM) 2.0 method. The FLARM 2.0 method has three unique features as compared to other pseudoreceptor model methods: (1) the training ligands are flexibly optimized inside the receptors to achieve minimal docking energies; (2) the receptor atoms are spatially moveable in the process of genetic evolving in order to avoid improper initial receptor shapes; and (3) void receptor sites are specially favored in order to obtain open receptor models that allow large gaps. Advantages of an open model include less noise information, a smaller risk of overfitting, and ease of locating the key interaction sites. The latter two features, inherited from the previous FLARM 1.0 method, can improve the predictive ability of the 3D-QSAR models, while the first feature is newly implemented to relieve the uncertainty caused by improper conformation and alignment. Three FLARM 2.0 case studies were performed, and the results show that FLARM 2.0 models are highly predictive and robust. FLARM 2.0 pseudoreceptor models can correspond well with the pharmacophore models and/or the binding sites of the real protein receptors. 相似文献
968.
969.
利用电荷迁移反应测定头孢羟氨苄 总被引:4,自引:0,他引:4
提出一种基于电荷迁移反应简便可靠地测定头孢羟氨苄的分光光度法。在甲醇-乙醇介质中,头孢羟氨苄与氯冉酸于50℃反应15min能够形成稳定的1:1络合物,其λmax=528nm,线性范围为20 ̄400mg/L。用拟定的方法测定原粉和胶囊,结果与药典法一致。对浓度100mg/L的药物10次测定相对标准偏差为1.4%,样品的标准加入回收率为99.0% ̄100.8%。 相似文献
970.
枸椽酸锗能明显提高小鼠血清溶血素抗体水平,增强二硝基氯苯(DNCB)致小鼠迟发型皮肤过敏反应。增加小鼠免疫器官胸腺和脾脏的重量,表明枸椽酸锗能增强小鼠体液免疫和细胞免疫水平。 相似文献