重复脉冲激光辐照光学材料的热力效应

在建立高斯型重复脉冲激光辐照光学材料模型的基础上,得到了圆柱型光学材料的二维温度场和热应力的解析解.以K9玻璃为例,通过数值计算得到同条件下重复脉冲激光对光学材料的损伤阈值.研究表明：在高斯型重复脉冲激光辐照下,损伤阈值受到脉冲数目、宽度、重复频率以及脉冲激光光斑半径的影响,多数情况下K9玻璃会发生热应力损伤.     

锂离子聚合物常温固体电解质的研究进展

综述了锂离子电池聚合物常温固体电解质的最新研究进展。主要关注的是电化学性能,尤其是室温下的离子电导率。对性能较好的聚合物固体电解质体系进行了概述。     

Statistical Characterization of the Yield Stress of Nanoparticles

Atomistic simulations are performed to study the statistical mechanical properties of gold nanoparticles.It is demonstrated that the yielding behavior of gold n...     

TiO2晶型对Au/TiO2上光催化分解臭氧的影响

以不同晶型TiO2为载体,采用沉积-沉淀法制备了Au/TiO2光催化剂,并用紫外-可见漫反射光谱、X射线光电子能谱(XPS)和表面光电压谱(SPS)等手段进行了催化剂表征,详细考察了Ti O2晶型对Au/TiO2光催化分解臭氧活性的影响.结果表明,光催化分解臭氧的活性顺序为Au/P25>Au/Anatase>Au/Rutile,这与不同的单一Ti O2对光催化臭氧分解的活性顺序是一致的.但在TiO2上沉积金后,其对光催化臭氧的分解活性有了显著的提高.由催化剂的Au4fXPS分析发现,不同晶型Ti O2上的电荷向金簇迁移的能力有明显差异,加之载体本身对光催化臭氧分解活性不同,两者协同作用导致负载金催化剂光催化分解臭氧活性的不同.SPS信号强度与催化剂光催化活性有很好的对应关系,SPS信号越强,光生电子和空穴分离效率越高,光催化活性越好.     

光学参变啁啾脉冲放大相位失配啁啾脉冲频谱整形新方法

相位匹配是实现高效光学参变啁啾脉冲放大(OPCPA)能量转换的关键之一,通过对几种常用非线性晶体的光学参变啁啾脉冲放大过程进行数值模拟研究,结果表明一定程度的相位失配不但能增加光学参变啁啾脉冲放大增益带宽,而且会使啁啾脉冲光谱强度分布中间凹陷。提出利用光学参变啁啾脉冲放大相位失配放大作为啁啾脉冲频谱整形的新方法,通过理论分析和模拟计算,找到了光学参变啁啾脉冲放大相位失配啁啾脉冲频谱整形效果的控制量;并对几种常用非线性晶体在简并、近简并、非简并等条件下的光学参变啁啾脉冲放大相位失配放大特性进行了比较。     

产生暗归零码光标记信号的新方案

在对预编码、调制和编码过程进行改进的基础上,提出了一种利用一个双臂马赫-曾德尔铌酸锂调制器和一个电信号时延器产生可调占空比和消光比的光暗脉冲归零码二进制信号的新方案。实验证明这种信号能用传统的二进制强度调制-直接检测系统的接收机进行检测。实验得到了在调节电信号时延器时速率为2.5 Gbit/s的光暗脉冲归零码二进制信号的频谱变化规律,以及占空比分别为0.25,0.35,0.60和0.80时光暗脉冲归零码二进制信号的误码率和眼图。此外,利用该方案产生的光暗脉冲归零码二进制信号可以作为标记在光标记交换网络中得到应用。     

Light Promotes the Immobilization of U(VI) by Ferrihydrite

The environmental behaviors of uranium closely depend on its interaction with natural minerals. Ferrihydrite widely distributed in nature is considered as one main natural media that is able to change the geochemical behaviors of various elements. However, the semiconductor properties of ferrihydrite and its impacts on the environmental fate of elements are sometimes ignored. The present study systematically clarified the photocatalysis of U(VI) on ferrihydrite under anaerobic and aerobic conditions, respectively. Ferrihydrite showed excellent photoelectric response. Under anaerobic conditions, U(VI) was converted to U(IV) by light-irradiated ferrihydrite, in the form of UO_2+x (x < 0.25), where •O₂⁻ was the dominant reactive reductive species. At pH 5.0, ~50% of U(VI) was removed after light irradiation for 2 h, while 100% U(VI) was eliminated at pH 6.0. The presence of methanol accelerated the reduction of U(VI). Under aerobic conditions, the light illumination on ferrihydrite also led to an obvious but slower removal of U(VI). The removal of U(VI) increased from ~25% to 70% as the pH increased from 5.0 to 6.0. The generation of H₂O₂ under aerobic conditions led to the formation of UO₄•xH₂O precipitates on ferrihydrite. Therefore, it is proved that light irradiation on ferrihydrite significantly changed the species of U(VI) and promoted the removal of uranium both under anaerobic and aerobic conditions.     

爆破影响下岩质高边坡浅表层块体稳定性研究

摘要：岩质高边坡整体稳定性主要受软弱结构面及其组合控制,在组合有利的情况下,边坡主要发生浅表层块体失稳,开挖时的爆破振动作用是影响浅表层块体稳定的重要因素。本文以大渡河中游某岩质块状结构高边坡为例研究浅表层块体的稳定性,在总结浅表层块体失稳特征的基础上,实测爆破振动曲线,进行块体稳定性评价。研究结果表明,开挖后已失稳浅表层块体大多小于10m3,80%受软弱结构面控制,70%集中在马道下缘;实测的浅表层块体爆破振动加速度曲线显示,与邻近围岩相比,浅表层块体振动持续时间长,频率低,峰值小;等效静力法评价结果较爆破参数推算法更适用于临界失稳浅表层块体的稳定性评价。     

Tylophorine B benzene solvate

The crystal structure of tylophorine B (or 2,3,6‐tri­methoxy­phen­an­thro­[9,10‐f]­indol­izidine) as the benzene solvate, C₂₃H₂₅NO₃·­C₆H₆, has been determined. The compound was isolated from albizzia julibrissin and this is the first definitive report of the steochemistry of tylo­phorine.     

基于概率的工程结构动力特性优化设计

首先对结构材料物理参数为随机变量时 ,结构刚度和质量矩阵的建立以及结构特征值随机变量的数字特征进行了推导。在此基础上 ,构造了具有频率或频率禁区可靠性约束的工程结构动力优化数学模型 ,并对其中关切频率的估定 ,两种频率约束的统一表示等进行了讨论。优化求解采用子空间迭代和复合形方法。最后通过桁架和梁结构两个算例 ,说明文中模型和方法的正确与可行。