AAS测定紫皮石斛中5种重金属元素的含量

对天然紫皮石斛(Dendrobium devoninum Paxt.)根和茎中Cr、Cd、Pb、Hg、Cu 5种重金属元素的含量进行了测定,旨在为该资源的药(食)利用提供基础数据.利用干法灰化处理样品,采用原子吸收光谱法(AAS)分别测定紫皮石斛根和茎中Cr、Cd、Pb、Hg、Cu 5种重金属元素的含量.根中Cr、Hg和Cu 3种元素含量分别为122.8043士39.02、311.5152士24.28、0.2890士0.19mg·kg-1,相对标准偏差(RSD)在3.20％-14.07％之间;茎中Cr、Hg和Cu 3种元素的含量分别为139.3997士14.72、276.0101士45.61、0.2854士0.29mg·kg-1,相对标准偏差(RSD)在4.83％-10.99％之间;根和茎中均未检出Cd、Pb两种元素,可能与地球化学背景有关.与人工种植石斛中重金属元素含量相比,Cr、Hg两种元素含量相对较高,Cu元素含量较低.本法操作简便,重复性好,测定结果满意.     

pr3+ 激活的CaMoO4红色荧光粉的发光性质

采用高温固相法制备了稀土pr3+激活的Ca1-xPrxMoO4(0.005≤x≤0.02)系列红色荧光粉.荧光光谱表明:在453 nm激发下,样品产生了红光发射,其中对应于pr3+的特征跃迁3 P0→3F2位于654 nm的红色发射峰最强.分析了pr3的掺杂摩尔分数x对样品发光强度的影响,确定pr3+的最佳掺杂摩尔分数...     

超冷铷铯极性分子振转光谱的实验研究

利用激光冷却俘获技术在双暗磁光阱中获得高密度的超冷铷原子和铯原子,通过光缔合方法制备超冷铷铯极性分子.采用共振增强双光子电离技术探测基三重态a³∑⁺的铷铯分子,产率约为10⁴/s.通过改变缔合光频率,获得（2）0⁺,（3）0^-,（2）0^-等分子态的高分辨振转光谱,拟合得到相应的转动常数分别为0.00349 cm^-1,0.00649 cm^-1,0.00372 cm^-1.     

Near-field and far-field spreading of partially coherent annular beams propagating through atmospheric turbulence

Based on the extended Huygens–Fresnel principle, closed-form expressions for the Rayleigh range and the far-field divergence angle of partially coherent annular beams propagating through atmospheric turbulence are derived by using the Wigner distribution function (WDF). Taking the Rayleigh range and the far-field divergence angle as the characteristic parameters of near-field and far-field spreading, respectively, the spreading of partially coherent annular beams both in free space and in turbulence is studied in detail. It is found that the effect of the strength of turbulence and beam parameters (e.g., the spatial correlation length, the waist width, and the wave length) on the beam spreading in the near field is in agreement with that in the far field. However, in turbulence, the effect of the obscure ratio of annular beams on the spreading is different between in the near field and in the far field. Namely, in turbulence the beam spreading in the near field becomes smaller and the beam spreading in the far field becomes larger as the obscure ratio increases. In particular, the effect of turbulence on the Rayleigh range and the far-field divergence angle is nearly unchanged versus the obscure ratio when the spatial correlation length is small. The main results obtained in this paper are explained physically.     

An improved novel joint channel estimation algorithm for the 112 Gbit/s PDM CO-OFDM system

In this paper, an improved novel joint channel estimation algorithm is proposed for the 112 Gbit/s PDM CO-OFDM system. This method combines the advantages of the intra-symbol frequency domain averaging (ISFA) method and the time domain averaging (TA) method, which can realize more accuracy channel estimation. Simulation results show that this proposal could promise a relatively stable performance even under a rapidly time varying environment. It significantly outperforms the ISFA method by 2.2 dB when the DGD equals 1000 ps, and has the advantages of 0.5 dB over ISFA in considering the laser linewidth and frequency offset.     

(2+1)-Dimensional Analytical Solutions of the Combining Cubic-Quintic Nonlinear Schrdinger Equation

We investigate analytical solutions of the(2+1)-dimensional combining cubic-quintic nonlinear Schrdinger(CQNLS) equation by the classical Lie group symmetry method.We not only obtain the Lie-point symmetries and some(1+1)-dimensional partial differential systems,but also derive bright solitons,dark solitons,kink or anti-kink solutions and the localized instanton solution.     

中子半影成像的闪烁体阵列空间分辨力模拟

为了比较3种闪烁体探测器的性能,利用蒙特卡罗方法计算了不同光纤直径的闪烁体阵列的空间分辨和能量沉积。模拟结果表明:相同光纤直径的普通液体闪烁体阵列空间分辨力比塑料闪烁体阵列提高了约0.1 mm,而氘代液体闪烁体阵列空间分辨力约为普通液体闪烁体阵列的1/2;富氢闪烁体的能量沉积比氘代闪烁体高;闪烁体光纤直径越小,分辨力越好;闪烁体越厚,光产额越高。     

Orbital-decomposed electronic and magnetic properties of the double perovskite Sr2FeReO6

The detailed orbital-decomposed electronic structures and magnetic properties of the double perovskite Sr₂FeReO₆ have been studied using the first-principles projector augmented wave (PAW) potential within the generalized gradient approximation (GGA). Both occupied and unoccupied s and three p states of Fe³⁺ ion are located far away from the Fermi level, while all up-spin states and most down-spin states are completely filled for the s and three p states of Re⁵⁺ ion. The octahedral crystal field of the oxygen atoms around transition-metal (TM) sites splits the five-fold degenerate d states of the free TM atoms into triply degenerate t_2g states with smaller bonding-antibonding splitting and doubly degenerate e_g states with larger bonding-antibonding splitting. The Fe³⁺ and Re⁵⁺ ions are in the states (3d⁵, S=5/2) and (5d², S=1) with magnetic moments 3.70 and −0.86μ_B, respectively and thus antiferromagnetic coupling via oxygen between them. There are no direct interactions between two nearest Fe-Fe or Re-Re pairs, whereas along each Fe-O-Re-O-Fe or Re-O-Fe-O-Re chains, the hybridizations between Fe 3d and 4s, O 2s and 2p, as well as Re 5p, 5d and 6s orbitals are fairly significant.     

First-principles study of mechanical stability and thermal properties of MNNi3 （M=Zn,Mg,Al） under pressure

The mechanical stability,elastic,and thermodynamic properties of the anti-perovskite superconductors MNNi 3（M=Zn,Mg,Al） are investigated by means of the first-principles calculations.The calculated structural parameters and elastic properties of MNNi 3 are in good agreement with the experimental and the other theoretical results.From the elastic constants under high pressure,we predict that ZnNNi 3,MgNNi 3,and AlNNi 3 are not stable at the pressures above 61.2 GPa,113.3 GPa,and 122.4 GPa,respectively.By employing the Debye model,the thermodynamic properties,such as the heat capacity and the thermal expansion coefficient,under pressures and at finite temperatures are also obtained successfully.