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In a paper of 2003, Külshammer, Olsson and Robinson defined-blocks for the symmetric groups, where >1 is an arbitraryinteger. In this paper, we give a definition for the defectgroup of the principal -block. We then check that, in the Abeliancase, we have an analogue of one of Broué's conjectures. 相似文献
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Framework functionalisation triggers metal complex binding 总被引:1,自引:0,他引:1
Ingleson MJ Barrio JP Guilbaud JB Khimyak YZ Rosseinsky MJ 《Chemical communications (Cambridge, England)》2008,(23):2680-2682
Post-synthetic derivatisation of a porous material produces a functionalized material that binds the metal complex V(O)acac2, in contrast to the unfunctionalized precursor, which is inactive for complex binding. 相似文献
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McNally BA Koulov AV Lambert TN Smith BD Joos JB Sisson AL Clare JP Sgarlata V Judd LW Magro G Davis AP 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(31):9599-9606
Chloride transport by a series of steroid-based "cholapod" receptors/carriers was studied in vesicles. The principal method involved preincorporation of the cholapods in the vesicle membranes, and the use of lucigenin fluorescence quenching to detect inward-transported Cl-. The results showed a partial correlation between anion affinity and transport activity, in that changes at the steroidal 7 and 12 positions affected both properties in concert. However, changes at the steroidal 3-position yielded irregular effects. Among the new steroids investigated the bis-p-nitrophenylthiourea 3 showed unprecedented activity, giving measurable transport through membranes with a transporter/lipid ratio of 1:250 000 (an average of <2 transporter molecules per vesicle). Increasing transporter lipophilicity had no effect, and positively charged steroids had low activity. The p-nitrophenyl monourea 25 showed modest but significant activity. Measurements using a second method, requiring the addition of transporters to preformed vesicle suspensions, implied that transporter delivery was problematic in some cases. A series of measurements employing membranes of different thicknesses provided further evidence that the cholapods act as mobile anion carriers. 相似文献
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This work describes a new microfluidic device developed for the rapid screening of solubility diagrams. In several parallel channels, hundreds of nanolitre volume droplets of a given solution are first stored with a gradual variation in the solute concentration. Then, the application of a temperature gradient along these channels enables us to read directly and quantitatively phase diagrams, concentration vs. temperature. We show, using a solution of adipic acid, that we can measure ten points of the solubility curve in less than 1 hr and with only 250 microL of solution. 相似文献
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Peter A. Summers Ajesh P. Thomas Timothy Kench Jean-Baptiste Vannier Marina K. Kuimova Ramon Vilar 《Chemical science》2021,12(43):14624
The important role that G-quadruplex DNA (G4 DNA) structures play in regulating biological processes is becoming widely recognised. These structures have also been proposed to be attractive drug targets. Therefore, there has been significant interest in developing small molecules that can selectively bind to G4 DNA over other topologies. In this paper we investigate the interaction between DNA and helical compounds (helicenes) based on a central carbocation trisubstituted with aromatic rings. We show that the non-planar structure of these helicenes results in a significantly reduced affinity for dsDNA when compared to their planar analogues, whilst maintaining a high affinity for G4 DNA. Additionally, the right- and left-handed enantiomers of one of these helicenes recognise the chiral DNA environments of G4 and dsDNA differently. We show that upon DNA binding the helicenes display a fluorescence switch-on effect, which we have successfully used for cellular imaging in live and fixed U2OS cells, staining mitochondria and the nucleus, respectively.G-quadruplex DNA (G4 DNA) structures are selectively recognised by helical optical probes. 相似文献
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In this work, design and fabrication of a hybrid micro-device dedicated to the selective detection of hydrogen fluoride vapours is reported. This micro-device is composed by a gas chromatographic micro-column positioned in front of a tin dioxide-based gas sensor. The efficiency of this hybrid micro-system regarding to reproducibility and reversibility for various HF concentrations was investigated. The influence of the HF concentration on the electrical responses of the sensor is also studied. The experimental results show that this hybrid micro-system is efficient since it allows the elution, separation and detection of hydrogen fluoride at a low temperature close to ambient. 相似文献
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Bernard Bonnard Jean-Baptiste Caillau Robert Sinclair Minoru Tanaka 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2009,26(4):1081-1098
The objective of this article is to present a sharp result to determine when the cut locus for a class of metrics on a two-sphere of revolution is reduced to a single branch. This work is motivated by optimal control problems in space and quantum dynamics and gives global optimal results in orbital transfer and for Lindblad equations in quantum control. 相似文献