Influence of large eddies on the suspension of solid particles

The phenomena of solid particles suspensions, in a turbulent flow, can more conveniently be described by stochastic models than by diffusion models, particularly in the case of relatively coarse particles.

The fundamental difficulties of using such models are principally due to the difficulty of performing direct measurements of probabilities, because the number of observations (or tests) necessary to obtain physically representative values is important (theoretically infinite).

We have used such a model to describe the movement of spheres in an inclinable pipe.

To do so, we have identified the movement through a Markov process which permits us to show that we can characterize it by the limit distribution for passage probabilities in a cross section. We have used a special system of close-circuit television to measure it, doing a sufficiently large number of observations for the measurements to be significant.

In the case of a vertical pipe, the phenomena is one-dimensional. By using the model stochastic displacement, we obtain a differential equation which it is possible to integrate by assuming an obviously constant radial dispersion. The interpretation of limit distributions for passage probabilities and visual observations of particles movement in the pipe have caused us to conclude that the mean displacment is due, on one hand, to a radial acceleration bounded to a stochastic rotation of the flow and, on the other hand, to the effect of the mean velocity gradient. The experimental results show that the radial dispersion is a function of the relative dimension of particles with respect to the macroscale of the turbulence.

In the case of an inclined pipe, a two-dimensional stochastic model of the displacement is possible, but the integration of the equation is quite complicated and may be done numerically. We have prefered a two-dimensional simulation model. The results of the simulations permit us to obtain a limit repartition of passage probabilities, the moments of which we have compared with those that we have measured. These comparisons show that the model obviously represents the phenomena when the pipe is horizontal or very slightly inclined but differs in the near vertical case. This is due to the simplicity of the model in which we neglect the radial acceleration we have considered previously and the effect of which is negligible in comparison with gravity when the pipe is inclined.

The interpretation of the measurements by comparison of moments with the two-dimensional model shows that the angular dispersion of solid particles is essentially due to big eddies and that the particle diameters are not essential parameters in this case.

By associating this conclusion with that obtained previously concerning the radial dispersion, it seems that the eddies bigger than the macroscale of turbulence may be of capital importance in the dispersion of solid particles and that it will be of practical interest to characterize them as a function of a mean parameter of the flow.

The study of the movement of sufficiently large particles seems to be a method which is able to give this result.     

Comparative 13C NMR study of deuteriated and undeuteriated dibenzothiophenes,dibenzofurans, carbazoles,fluorenes and fluorenones

The NMR assignments of all carbons of dibenzothiophene and its S-oxides, dibenzofuran, various carbazoles, fluorene and fluorenone have been carried out using deuteriated derivatives and lanthanide shift reagents. Chemical shifts and coupling constants are discussed as a function of the nature of the central ring.     

Conductivite electrique des magnetites finement divisees substituees a l'aluminium et au chrome

The magnetites substituted for aluminium and chromium show a high conductivity decrease as well as a change in the conduction type under vacuum when passing from the inverse to the normal spinel during substitution. This type of conduction is confirmed by the study of oxygen chemisorption at temperatures close to room temperature. At higher temperatures, volume oxidation is accompanied by a sharp change in conductivity, which differs depending on whether the spinel is inverse or normal.     

Heterocycles contenant du phosphore-XXI. Etude par RMP de déeriveés de l'oxazaphospholane-l,3,2: I-Analyse des spectres des composksés non substitués en 4 et 5.

The PMR spectra of the title 1,3,2-oxazaphospholane derivatives present an ABKLX pattern. The subspectral analysis of such a system shows that there are eight solutions. INDOR experiments permit the establishment of the energy diagram and the selection of the correct solution.     

FTIR study of the reaction of ethyl radicals with O2 and Cl2 in air at 295 K

Using Fourier transform infrared spectroscopy, the ethene yield from the reaction of C₂H₅ radicals with O₂ has been determined to be 1.50 ± 0.09%, 0.85 ± 0.11%, and <0.1% at total pressures of 25, 50, and 700 torr, respectively. Additionally, the rate constant of the reaction of C₂H₅ radicals with molecular chlorine was measured relative to that with molecular oxygen. (1) A ratio k₆/k₇ = 1.99 ± 0.14 was measured at 700 torr total pressure which, together with the literature value of k₇ = 4.4 × 10^?12 cm³ molecule^?1s^?1, yields k₆ = (8.8 ± 0.6) × 10^?12 cm³ molecule^?1s^?1. Quoted errors represent 2σ. These results are discussed with respect to previous kinetic and mechanistic studies of C₂H₅ radicals.     

Electromagnetic annihilation of e+e− into quarkonium states with even charge conjugation

We calculate the production of narrow resonances with even charge conjugation ${}^3\text{P}{}_{\mathrm{J}}\text{=1,2}$ in e⁺e^? annihilation in the quarkonium and vectordominance models. We give unitarity bounds for $\text{Γ(}{}^3\text{P}{}_{\mathrm{J}}\text{→ e}{}^{\mathrm{+}}\text{e}{}^{\mathrm{?}}\text{)}$ in terms of $\text{Γ(}{}^3\text{P}{}_{\mathrm{J}}\text{→ γγ)}$ and $\text{Γ(}{}^3\text{P}{}_{\mathrm{J}}\text{→ e}{}^{\mathrm{+}}\text{e}{}^{\mathrm{?}}\text{)}$. The electromagnetic production dominates through the neutral current at low energies independent of details of the model. For masses above 10 GeV the situation is reversed.     

Dilute solution studies of nitrogen-substituted polyurethanes

A high molecular weight linear polyurethane was prepared by the polyaddition of equimolar amounts of ethylene glycol and methylene bis(4-phenyl isocyanate). Varying amounts of the labile carbamate protons of the polyurethane backbone were substituted by a number of groups of varying length and composition. The resultant grafted or nitrogen-substituted polyurethanes were then studied viscometrically in both polymer solvent and in a polymer solvent—nonsolvent mixture. The configuration of the nitrogen-substituted polyurethane was found to be dependent upon the number and length of pendent branches.