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51.
Summary Dichlorobis(cyclopentadienyl)titanium(IV), Cp2TiCI2, reacts with bidentate Schiff bases such as salicylideneaniline, salicylidene-o-toluidine, salicylidene-m-toluidine, salicylidene-p-toluidine and 2-hydroxy-l-naphthylReprints of this paper are not available.To whom all correspondence should be addressed. 相似文献
52.
The aggregation/deaggregation of chlorin p6 with the surfactants CTAB, SDS, and TX 100 have been studied by using absorption, fluorescence, and light scattering techniques. The ionic surfactants are found to cause aggregation of fluorophore at submicellar concentrations. The aggregates dissolve at higher surfactant concentrations to yield micellized monomers. This is rationalized by the interplay of electrostatic and hydrophobic effects. A prominent pH effect is observed in the ionic surfactant induced aggregation process as the charge on the fluorophore is controlled by the pH of the medium. Interestingly, the neutral TX-100 also induces aggregation of chlorin p6 at low concentrations, indicating that hydrophobic effects by themselves can cause aggregation unless there is a hindrance by repulsive electrostatic effects. 相似文献
53.
Jaya N. Iyer 《Compositio Mathematica》2003,136(3):317-321
In this paper, we show that the Chern classes c
k
of the de Rham bundle
defined on any good toroidal compactification
of the moduli space of Abelian varieties of dimension g are zero in the rational Chow ring of
, for g=4, 5 and k>0. 相似文献
54.
Jaya N. Iyer 《Transactions of the American Mathematical Society》2003,355(8):3209-3216
We show that ample line bundles on a -dimensional simple abelian variety , satisfying 2^g\cdot g!$">, give projective normal embeddings, for all .
55.
Jaya Ram Simkhada Seung Sik Cho Seong Ju Park Poonam Mander Yun Hee Choi Hyo Jeong Lee Jin Cheol Yoo 《Applied biochemistry and biotechnology》2010,162(5):1457-1470
Organic solvent- and detergent-resistant proteases are important from an industrial viewpoint. However, they have been less
frequently reported and only few of them are from actinomycetes. A metalloprotease from Streptomyces olivochromogenes (SOMP) was purified by ion exchange with Poros HQ and gel filtration with Sepharose CL-6B. Apparent molecular mass of the
enzyme was estimated to be 51 kDa by sodium dodecyl sulfate–polyacrylamide gel electrophoresis and gelatin zymography. The
activity was optimum at pH 7.5 and 50 °C and stable between pH 7.0 and 10.0. SOMP was stable below 45 °C and Ca2+ increased its thermostability. Ca2+ enhanced while Co2+, Cu2+, Zn2+, Mn2+, and Fe2+ inhibited the activity. Ethylenediaminetetraacetic acid and ethylene glycol-bis (β-aminoethyl ether)-N,N,N′,N′-tetraacetic acid, but not phenylmethylsulfonyl fluoride, aprotinin, and pefabloc SC, significantly suppressed the activity,
suggesting that it might be a metalloprotease. Importantly, it is highly resistant against various detergents, organic solvents,
and oxidizing agents, and the activity is enhanced by H2O2. The enzyme could be a novel protease based on its origin and peculiar biochemical properties. It may be useful in biotechnological
applications especially for organic solvent-based enzymatic synthesis. 相似文献
56.
S. Kapoor C. Gopinathan R. M. Iyer 《Journal of Radioanalytical and Nuclear Chemistry》1989,130(2):409-415
Trapped electron (e
T
–
) reactivity in methanol-isopropanol glasses irradiated at 77 K has been studied as a function of trap-depth, the variation in the trap depth being achieved by varying the methanol:isopropanol ratio. Benzyl chloride and carbon disulfide have been used as scavengers. In the case of the glasses containing benzyl chloride, the observed yield of the benzyl radical has been correlated with the trapping efficiency of the matrix. The data has been interpreted with the aim of assessing the relative importance of tunnelling in the scavenging of electrons in low temperature glassy matrices. 相似文献
57.
Pratibha Srivastava Inder Pal Singh Kapoor Gurdip Singh Roland Fröhlich 《Journal of Thermal Analysis and Calorimetry》2010,100(1):233-238
Phenylenediammonium dibromide (PDADBr) salts have been prepared and characterized by X-ray crystallography. The thermal decomposition
of PDADBr has been studied by thermogravimetry (TG) and differential thermal analysis (DTA). Kinetic parameters have been
evaluated using model fitting and isoconversional methods. The thermolytic pathways have also been suggested which involve
proton transfer as a primary step to regenerate parent amine and HBr. Interaction between amine and HBr at higher temperature
yields gaseous products. 相似文献
58.
59.
Bahl and Zionts [H.C. Bahl, S. Zionts, A noniterative multiproduct multiperiod production planning method, Operations Research Letters 1 (1982) 219-221] formulated a problem for planning multiproduct multiperiod production on a single facility. They developed a column-minima noniterative method and claimed that it gave an optimal solution. We show that the claim is incorrect. 相似文献
60.
Summary Zinc may be determined polarographically in acetate buffered solutions of PH 4 to 5.6.
Zusammenfassung Die polarographische Bestimmung von Zink ist möglich in mit Acetat gepufferten Lösungen vom PH 4 bis 5,6.
Résumé On peut doser le zinc par polarographie dans des solutions de pH 4 à 5,6 tamponnées à l'acétate.相似文献