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111.
Mohammad Sedghi-Asl Javad Farhoudi Hassan Rahimi Sven Hartmann 《Transport in Porous Media》2014,104(3):565-579
In this paper, an analytical solution to solve 1-D partial differential equation is presented for fully developed turbulent flow through highly permeable sloping deposited porous medium. The present solution will be applicable for a wide range of slopes varying from zero to relatively steep slopes. To confirm the solution, the analytical results have been validated using two sets of experimental data including rounded and crushed material. To see the compatibility of solution, a Darcy-based form of the solution is derived and compared with proposed solution and experimental data. The results showed a satisfactory agreement with experimental records from water surface profiles through rock cavities for both rounded and crushed rock materials. Finally, it may be concluded that the proposed solution could be used to analyze water surface profiles and normal depth in such slanting permeable porous media. This solution provides a reliable realization of the flow profiles in porous materials which are widely used in open-channel flow concepts. 相似文献
112.
The minimum variance lower bound (MVLB) represents the best achievable controller capability in the variance sense. Realization of MVLB for nonlinear systems confronts some difficulties. To realize the MVLB, in this paper, a nonlinear non-affine generalized minimum variance controller is designed. The situations in which the model is not in hand, accurate, or invertible are addressed. Moreover, in order to design minimum variance controller for nonlinear structures, inverse of the system is modeled; then, the controller parameters are tuned by a recursive optimization algorithm. The most classical recursive algorithms are gradient-based. In this paper, a relationship between gradient of the controller with that of the system model is derived by inverse lemma. Therefore, the recursive algorithm is free of any need for the gradient of the system model. Finally, an experimental test on four-tank benchmark processes is used to clarify the effectiveness of the proposed control scheme. 相似文献
113.
The composition and in?vitro antibacterial activity of essential oils from four Satureja species (S. bachtiarica, S. khuzistanica, S. mutica and S. rechingeri) growing in Iran were determined. According to the results of GC-FID and GC-MS analysis, all oil samples were principally composed of phenolic constituents (carvacrol and/or thymol) with the percentages ranging from 41.2% (S. bachtiarica) to 77.7% (S. rechingeri). Determining antibacterial activities by the disc diffusion method against two Gram-positive and two Gram-negative bacteria revealed the maximum activity against Bacillus cereus with a range of minimum inhibitory concentration values from 0.25 to 1?mg?mL(-1) and minimum bactericidal concentration values from 0.5 to 1?mg?mL(-1). The oils of S. khuzistanica and S. rechingeri appeared to be more active in general than those of other species. In conclusion, the essential oils of studied Satureja species have the potential to be considered as alternatives for synthetic food preservatives. 相似文献
114.
The Pd-poly(N-vinyl-2-pyrrolidone)/KIT-6 nanocomposite was prepared by an in situ polymerization method and used as an efficient heterogeneous catalyst for C–C bond formation through the Heck coupling reaction of aryl iodides, bromides and chlorides with styrene. The physical and chemical properties of the catalyst were characterized by XRD, BET, FT-IR, TGA, UV-Vis and TEM techniques. The reactions were performed in methanol-water as solvent and the products were obtained in high yield and purity after a simple work-up. The stability of the nanocomposite catalyst was excellent and could be reused 8 times without much loss of activity in the Heck coupling reaction. 相似文献
115.
A novel and efficient route for the synthesis of 1,8-dioxooctahydroxanthenes and 14-aryl-14H-dibenzo[a,j]xanthenes is described through one-pot multi-component reaction of dimedone and 2-naphthol with various aryl aldehydes using ZnO nanoparticles under solvent-free conditions.This method provides a novel and improved pathway for the synthesis of xanthenes in the terms of excellent yields,short reaction times,reusability and low catalyst loading. 相似文献
116.
Effects of substrate on crystallinity, surface morphology, and luminescence properties of radio frequency sputtered zinc oxide (ZnO) thin films were investigated. A variety of materials such as Si (100), Si (111), Al2O3, quartz, and silicon carbide (SiC) wafers were examined as substrates for deposition of ZnO thin films. The results showed smooth and uniform growth of c-axis orientation films. The thickness of the layers was about 50 nm. The average grain sizes of films were about 10, 13, and 12 nm for Si (111), quartz, and SiC samples, respectively. The deposited film on Al2O3 showed the largest grain size, about 500 nm. Grazing incidence x-ray diffraction patterns of the samples revealed that sputtered layers on Al2O3 and quartz had better crystallinity with higher peak at (002) orientation compared to Si and SiC substrates. Moreover, the Al2O3 sample exhibited a weak peak at position of (100) planes of ZnO too. The photoluminescence spectra of the samples showed a typical luminescence behavior with a broad UV band, including a main peak at around 388 nm and a weak shoulder peak at around 381 nm, corresponding with bound excitonic recombination and free excitonic recombination, respectively. The luminescence peak revealed that the intensity of UV emission is not necessarily dependent on the grain sizes and the micro-structural quality of ZnO films. 相似文献
117.
Balanced fuzzy particle swarm optimization 总被引:1,自引:0,他引:1
Amir Robati Gholam Abbas BaraniHossein Nezam Abadi Pour Mohammad Javad FadaeeJavad Rahimi Pour Anaraki 《Applied Mathematical Modelling》2012,36(5):2169-2177
In the present study an extension of particle swarm optimization (PSO) algorithm which is in conformity with actual nature is introduced for solving combinatorial optimization problems. Development of this algorithm is essentially based on balanced fuzzy sets theory. The classical fuzzy sets theory cannot distinguish differences between positive and negative information of membership functions, while in the new method both kinds of information “positive and negative” about membership function are equally important. The balanced fuzzy particle swarm optimization algorithm is used for fundamental optimization problem entitled traveling salesman problem (TSP). For convergence inspecting of new algorithm, method was used for TSP problems. Convergence curves were represented fast convergence in restricted and low iterations for balanced fuzzy particle swarm optimization algorithm (BF-PSO) comparison with fuzzy particle swarm optimization algorithm (F-PSO). 相似文献
118.
We found that elemental iodine and bromine are converted to trihalide nucleophiles (triiodine and tribromide anion, respectively) in the presence of catalytic amounts of meso-tetraphenylporphyrins (H2TPP). Therefore a highly regioselective method for the synthesis of beta-haloalcohols through direct ring opening of epoxides with elemental iodine and bromine in the presence of H2TPPs as new catalysts is described. At room temperature a series of epoxide derivatives were converted into the corresponding halohydrins resulting from an attack of trihalide species anion atoms at the less substituted carbon atom. This method occurs under neutral and mild conditions with high yields in various aprotic solvents, even when sensitive functional groups are present. 相似文献
119.
Majid Kolahdoozan Roozbeh Javad Kalbasi Zohreh S. Shahzeidi 《Monatshefte für Chemie / Chemical Monthly》2012,38(2):325-334
Abstract
Poly(4-vinylpyridine)/SBA-15 (P4VP/SBA-15) composites with various amounts of SBA-15 were prepared and characterized. The physical and chemical properties of P4VP/SBA-15 were investigated by XRD, BET, FT-IR, TGA, and SEM techniques. The catalytic performance of each material was determined for the Knoevenagel condensation reaction between carbonyl compounds and ethyl cyanoacetate in the presence of water as a solvent. The effects of reaction temperature, the amount of catalyst, amount of support, solvent, and the amount of benzoyl peroxide during the synthesis of P4VP/SBA-15 were investigated, as well as the recyclability of the heterogeneous composite. The catalyst used for this synthetically useful transformation showed a considerable level of reusability as well as very good activity. This reaction occurred rapidly when water was used as a solvent, so we assume it to be a green reaction. 相似文献120.
Interactive effect of oxygen diffusion and volatiles advection on transient thermal degradation of poly methyl methacrylate (PMMA) 总被引:1,自引:0,他引:1
A transient, one-dimensional model has been presented to formulate the substantial role of polymer gasification in the early
stages of fire growth. The present model comprises the interaction between the oxygen diffusion and the released volatiles
on the rate of polymer gasification, when the polymeric sample is subjected to an external radiative source. The model also
includes different mechanisms affecting the degradation process such as in-depth thermal and oxidative decomposition, in-depth
absorption of radiation and heat and mass transfer in the both gas and solid phases. The results for two different radiative
heat sources (17 and 40 kW m−2) are reported and yielded realistic results, comparing to the published experimental data. It was found that an increase
in the oxygen concentration will lead to a considerable decrease in the surface temperature as well as significant increase
of gasification rate at 17 kW m−2; nevertheless this effect is less apparent at 40 kW m−2. 相似文献