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101.
Morteza?MoradiEmail author Ali?Aghakhani Mohammad?Javad?Eshraghi 《Structural chemistry》2016,27(2):535-542
Electrical sensitivity of a boron carbon nanotube (B2CNT) was examined toward carbon monoxide (CO) molecule by using dispersion-corrected density functional theory calculations. It was found that CO is weakly adsorbed on the tube, releasing energy of 3.5–4.1 kcal/mol, and electronic properties of the tube are not significantly changed. To overcome this problem, boron and carbon atoms of the tube were substituted by aluminum and silicon atoms, respectively. Although both Al and Si doping make the tube more reactive and sensitive to CO, Si doping seems to be a better strategy to manufacture CO chemical sensors due to the higher sensitivity without deformation of nanotube structure after adsorption procedure. Moreover, it was shown that some interference molecules such as H2O, H2S and NH3 cannot significantly change the electronic properties of B2CNT. Therefore, the Si-doped tube might convert the presence of CO molecules to electrical signal. 相似文献
102.
Omar El-Fallah Emmanuel Fricain Karim Kellay Javad Mashreghi Thomas Ransford 《Constructive Approximation》2016,44(2):269-281
In most classical holomorphic function spaces on the unit disk in which the polynomials are dense, a function f can be approximated in norm by its dilates \(f_r(z):=f(rz)~(r<1)\). We show that this is not the case for the de Branges–Rovnyak spaces \(\mathcal{H}(b)\). More precisely, we exhibit a space \(\mathcal{H}(b)\) in which the polynomials are dense and a function \(f\in \mathcal{H}(b)\) such that \(\lim _{r\rightarrow 1^-}\Vert f_r\Vert _{\mathcal{H}(b)}=\infty \). On the positive side, we prove the following approximation theorem for Toeplitz operators on general de Branges–Rovnyak spaces \(\mathcal{H}(b)\). If \((h_n)\) is a sequence in \(H^\infty \) such that \(\Vert h_n\Vert _{H^\infty }\le 1\) and \(h_n(0)\rightarrow 1\), then \(\Vert T_{\overline{h}_n}f-f\Vert _{\mathcal{H}(b)}\rightarrow 0\) for all \(f\in \mathcal{H}(b)\). Using this result, we give the first constructive proof that, if b is a nonextreme point of the unit ball of \(H^\infty \), then the polynomials are dense in \(\mathcal{H}(b)\). 相似文献
103.
Javad Balooee Yeol Je Cho Mehdi Roohi 《Numerical Functional Analysis & Optimization》2016,37(3):284-303
A new class of contractive mappings called pointwise asymptotically ?-strict pseudo-contractions in Hilbert spaces is introduced and weak convergence of the sequence generated by Mann's iterative scheme to a fixed point of a uniformly Lipschitzian and pointwise asymptotically ?-strict pseudo-contractive mapping T in a Hilbert space is established. Also, a new kind of monotone hybrid method which is a modification of Mann's iterative scheme for finding a common fixed point of an infinitely countable family of uniformly Lipschitzian and pointwise asymptotically ?-strict pseudo-contractive mappings is proposed. Strong convergence of the sequence generated by the proposedmonotone hybrid method for an infinitely countable family of uniformly Lipschitzian and pointwise asymptotically ?-strict pseudo-contractive mappings in a Hilbert space is also shown. The results presented in this article extend and improve some known results in the literature. 相似文献
104.
Mojtahedi MM Chalavi S Ghassempour A Tabar-Heydar K Sharif SJ Malekzadeh M Aboul-Enein HY 《Biomedical chromatography : BMC》2007,21(3):234-240
This work aims to evaluate for the enantiomeric separations of three agrochemical toxins: haloxyfop-methyl, fenoxaprop-p-ethyl and indoxacarb on crystalline degradation products-chiral stationary phase (CDP-CSP) of high-performance liquid chromatography (HPLC) under normal and polar organic phases. In the normal phase, the mobile phase was n-hexane with alcohols including methanol and isopropanol as polar modifiers. In the polar organic phase mode, the mobile phase was methanol with different percentages of triethylammunium acetate. The influence of flow rate (0.3-0.9 mL/min), analyte concentration and silica gel particle sizes (10, 15 and 30 microm) was investigated. This new chiral stationary phase showed excellent stereoselectivity for the two enantiomers of haloxyfop-methyl and fenoxaprop-p-ethyl and chiral recognition for indoxacarb under normal-phase mode. However, under polar organic phase, only indoxacarb was separated (alpha < 1.5). The chromatographic results were compared with commercial chiral columns. 相似文献
105.
Mohammad Javad Nasr Isfahani Maxym Myndyk Armin Feldhoff Vladimir Šepelák 《Journal of magnetism and magnetic materials》2009,321(3):152-156
Mn0.5Zn0.5Fe2O4 nanoparticles (10-30 nm) have been prepared via mechanochemical processing, using a mixture of two single-phase ferrites, MnFe2O4 and ZnFe2O4. SQUID measurements (field-cooled magnetization curves and hysteresis loops) were performed to follow the mechanically induced evolution of the MnFe2O4/ZnFe2O4 mixture submitted to the high-energy milling process. The resulting single MnZn nanoferrite phase was characterized by SQUID (M-H curve), Faraday balance (M-T curve) and transmission electron microscopy. The magnetic characteristics of the mechanosynthesized material were compared with those of bulk Mn0.5Zn0.5Fe2O4. It was found that the saturation magnetization of nanostructured Mn0.5Zn0.5Fe2O4 (87.2 emu/g) is lower than that of the bulk Mn0.5Zn0.5Fe2O4, but, the Néel temperature of the sample (583 K) is higher than that of the bulk Mn0.5Zn0.5Fe2O4. 相似文献
106.
Younes Ghasemi Sara Rasoul-Amini Mohammad Hossein Morowvat Mohammad Bagher Ghoshoon Mohammad Javad Raee Soraya Khoubani Narges Negintaji Fatemeh Nouri Rezvan Parvizi 《Chemistry of Natural Compounds》2009,45(6):824-828
A unicellular microalga, Chlorella vulgaris, was isolated from rice field and applied in the biotransformation experiment
of hydrocortisone (1). This strain has not been previously tested for hydrocortisone bioconversion. Fermentation was carried out in BG-11 medium
supplemented with 0.05% substrate at 25°C for 14 days incubation. The products obtained were chromatographically purified
followed by their characterization using spectroscopic methods. 11β,17α,20β,21-Tetrahydroxypregn-4-en-3-one (2), 11β,17β-dihydroxyandrost-4-en-3-one (3), and 11β-hydroxyandrost-4-ene-3,17-dione (4) were the main bioproducts in the hydrocortisone bioconversion. Bioreaction characteristics observed were 20-ketone reduction
for accumulation of compound 2 and side chain degradation of the substrate to prepare compounds 3 and 4. Time course study showed the accumulation of the product 2 from the second day of the fermentation and 3 as well as 4 from the third day. All the metabolites reached their maximum concentration in seven days. Microalgal 18S rRNA gene was also
amplified by PCR. PCR products were sequenced to confirm their authenticity as 18S rRNA gene of microalgae. The result of
PCR blasted with other sequenced microalgae in NCBI showed 100% homology to the 18S small subunit rRNA of six strains of Chlorella
vulgaris. 相似文献
107.
Seyyed Javad Sabounchei Parisa Shahriary Zabiholla Bolboli Nojini Hamid Reza Khavasi Cengiz Arici Hakan Dal 《Heteroatom Chemistry》2010,21(7):475-485
Stable phosphoranes, Ar3P = CHCOR (R = C6H5, C6H4NO2, C6H4OCH3, CH3, OCH2C6H5; Ar = p‐tolyl or phenyl), have been C‐acylated by acetic anhydride to obtain new types of phosphorus ylides. Synthesis and characterization of six phosphorus ylides of the type Ar3PC(COCH3)(COR) are reported. The reaction of {(p‐tolyl)3PCHCOC6H5} ( I ), {(p‐ tolyl)3PCHCOC6H4NO2} ( II ), {Ph3PCHCOC6H4NO2} ( III ), {Ph3PCHCOC6H4OCH3} ( IV ), {(p‐tolyl)3PCHCOCH3} ( V ), and {Ph3PCHCOOCH2C6H5} ( VI ) with acetic anhydride in dry chloroform as solvent gives (p‐tolyl)3PC(COMe)(COC6H5), α‐acetyl‐α‐benzoylmethy‐lenetriphenylphosphorane ( 1 ), {(p‐tolyl)3PC(COMe) (COC6H4NO2)} ( 2 ), {Ph3PC(COMe)(COC6H4NO2)} ( 3 ), {Ph3PC(COMe)(COC6H4OCH3)} ( 4 ), {(p‐tolyl)3 PC(COCH3)2} ( 5 ), and {Ph3PC(COMe)(COOCH2 C6H5)} ( 6 ). Single crystal X‐ray analyses for ylides 2 , 5 , and 6 reveal the monoclinic ( 2, 5 ) and triclinic ( 6 ) crystal systems. Characterization of the obtained compounds was also performed by elemental analysis, IR, 1H, 31P, and 13C NMR. The geometries of these compounds have been investigated using density functional theory (DFT). In addition, electronic parameters of these compounds such as HOMO and LUMO energy, Mulliken partial charge, and dipole moment were obtained. In this paper, the reactivity of these ylides is discussed in regard to the aforementioned data. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:475–485, 2010; View this article online at wileyonlinelibrary.com . DOI 10.1002/hc.20633 相似文献
108.
This paper presents an output-feedback adaptive controller for a class of linear systems with unknown time-varying state delay
and in the presence of actuator failures. We consider a common type of actuator failure in which some unknown system inputs
may be stuck at some unknown fixed values and at unknown time instants. The adaptive controller is designed based on SPR–Lyapunov
approach for relative degree one and two cases. Closed-loop system stability and asymptotic output tracking are proved using
suitable Lyapunov–Krasovskii functional for each case. Simulation results are provided to demonstrate the effectiveness of
the proposed results. 相似文献
109.
In this paper, a novel scheme for nonlinear displacement-dependent (NDD) damper is introduced. The damper is attached to a simple mass-spring-damper vibration system. The vibration system equipped with a NDD damper is mathematically modeled and the nonlinear governing differential equation of the system is derived. To obtain the displacement of the system, the approximate analytical solution of the governing equation is elaborated using the multiple scales method. The advised approximate analytical algorithm is performed for several case studies and is also verified by the numerical fourth-order Runge?CKutta method. In addition, the performance of the NDD damper is analyzed and compared with the performance of the traditional linear damper. It is found that the proposed NDD damper scheme along with the multiple scales method is not only feasible for vibration reduction but also yields satisfactory response performance rather than the existing traditional linear damper. 相似文献
110.
This paper deals with the synchronization of uncertain unified chaotic system in the presence of two kinds of disturbances,
white noise and bounded power signal. A sliding mode controller (SMC) is established to guarantee the sliding motion. Moreover,
a proportional-integral (PI) switching surface is used to determine the performance of the system in the sliding motion. Also,
by using a mixed H
2/H
∞ approach, the effect of external disturbances on the sliding motion is reduced. The necessary parameters of constructing
controller and switching surface are found via semidefinite programming (SDP) which can be solved effectively by a standard
software. Finally, a numerical simulation is presented to show the effectiveness of the proposed method. 相似文献