A novel method of measuring electrophoretic mobility of gas bubbles

Accurate measurement of electrophoretic mobility for gas bubbles is a challenging task as it requires the creation of a desired number of very small air bubbles to ensure negligible rise velocities during the course of the measurement. Here, we report a simple and reliable method for generating stable dispersions of "nano-bubbles." Preparation of such dispersions relies on the nucleation of nano-bubbles in solutions supersaturated with gas. Electrophoretic mobility of these nano-bubbles is determined by the ZetaPALS technique (Brookhaven Instruments) using Uzgiris electrodes coated with palladium. The Smoluchowski limit is assumed in the calculation of zeta potentials. In regard to reproducibility and reliability, this novel method shows a clear advantage over other existing techniques of zeta potential measurement for bubbles.     

Morphological aspects of the traumatic chronic subdural hematoma capsule: SEM studies.

The morphology of the outer and inner membranes of traumatic chronic subdural hematomas (CSDHs) surgically removed from eight patients was investigated by scanning electron microscopy (SEM). Hematomas were divided into three groups based on time that had passed from the initiation of trauma to surgery. Structure of the CSDHs showed gradual morphological changes of the developing hematoma capsule. They initially included angiogenic and aseptic inflammatory reactions followed by progressive involvement of fibroblasts-proliferating and producing collagen fibrils. Numerous capillaries suggesting formation of new blood vessels were observed mainly in young hematomas removed between 15 and 21 days after trauma. In "older" hematomas (40 days after trauma), more numerous capillaries and thin-walled sinusoids were accompanied by patent, larger diameter blood vessels. Within the fibrotic outer membrane of the "oldest" hematoma capsules (60 or more days after trauma), especially in the area over the hematoma cavity, blood vessels were frequently occluded by clots. The results suggest dynamic changes in cellular and vascular organization of traumatic CSDH capsules paralleling the progression in hematoma age.     

On the spectral radius of a directed graph

We provide upper estimates on the spectral radius of a directed graph. In particular we prove that the spectral radius is bounded by the maximum of the geometric mean of in-degree and out-degree taken over all vertices. © 1996 John Wiley & Sons, Inc.     

Numerical analysis of chip formation during machining for different value of failure strain

Grinding is a very complicated processing. To increase quality of product and minimize the cost of abrasive machining, we should know physical phenomena which exist during the process. The first step to solution of this problem is analysis of machining process with a single abrasive grain. In the papers [1, 2] the thermo-mechanical models of this process are presented, but in this work attention is concentrated on chip formation and his separation from object. The influence of failure strain ε_f on states of strain and stress in surface layer during machining is explained. The phenomena on a typical incremental step were described using step-by-step incremental procedure, with updated Lagrangian formulation. Then, the Finite Element Method (FEM) and Dynamic Explicit Method (DEM) were used to obtain the solution. Application was developed in the ANSYS system, which makes possible a complex time analysis of the physical phenomena: states of displacements, strains and stress. Numerical computations of the strain have been conducted with the use of two methodologies. The first one requires an introduction of boundary conditions for displacements in the contact area determined in modeling investigation, while the second – a proper definition of the contact zone through the introduction of finite elements of TARGET and CONTACT types, without the necessity to introduce boundary conditions. This model includes variational equations of the object's motion and deformation. Examples of calculations for the displacement, strain and stress field in the surface layer zones were presented. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Formation of GeO2 under Graphene on Ge(001)/Si(001) Substrates Using Water Vapor

The problem of graphene protection of Ge surfaces against oxidation is investigated. Raman, X-Ray diffraction (XRD), atomic force microscopy (AFM) and scanning electron microscopy (SEM) measurements of graphene epitaxially grown on Ge(001)/Si(001) substrates are presented. It is shown that the penetration of water vapor through graphene defects on Gr/Ge(001)/Si(001) samples leads to the oxidation of germanium, forming GeO₂. The presence of trigonal GeO₂ under graphene was identified by Raman and XRD measurements. The oxidation of Ge leads to the formation of blisters under the graphene layer. It is suggested that oxidation of Ge is connected with the dissociation of water molecules and penetration of OH molecules or O to the Ge surface. It has also been found that the formation of blisters of GeO₂ leads to a dramatic increase in the intensity of the graphene Raman spectrum. The increase in the Raman signal intensity is most likely due to the screening of graphene by GeO₂ from the Ge(001) surface.     

Dynamic Supramolecular Ruthenium-Based Gels Responsive to Visible/NIR Light and Heat

A simple supramolecular crosslinked gel is reported with a photosensitive ruthenium bipyridine complex functioning as a crosslinker and poly(4-vinylpyridine) (P4VP) as a macromolecular ligand. Irradiation of the organogels in H₂O/MeOH with visible and NIR light (in a multiphoton process) leads to cleavage of pyridine moieties from the ruthenium complex breaking the cross-links and causing degelation and hence solubilization of the P4VP chains. Real-time (RT) photorheology experiments of thin films showed a rapid degelation in several seconds, whereas larger bulk samples could also be photocleaved. Furthermore, the gels could be reformed or healed by simple heating of the system and restoration of the metal–ligand crosslinks. The relatively simple dynamic system with a high sensitivity towards light in the visible and NIR region make them interesting positive photoresists for nano/micropatterning applications, as was demonstrated by writing, erasing, and rewriting of the gels by single- and multiphoton lithography.     

Interactions of endoglucanases with amorphous cellulose films resolved by neutron reflectometry and quartz crystal microbalance with dissipation monitoring

A study of the interaction of four endoglucanases with amorphous cellulose films by neutron reflectometry (NR) and quartz crystal microbalance with dissipation monitoring (QCM-D) is reported. The endoglucanases include a mesophilic fungal endoglucanase (Cel45A from H. insolens), a processive endoglucanase from a marine bacterium (Cel5H from S. degradans ), and two from thermophilic bacteria (Cel9A from A. acidocaldarius and Cel5A from T. maritima ). The use of amorphous cellulose is motivated by the promise of ionic liquid pretreatment as a second generation technology that disrupts the native crystalline structure of cellulose. The endoglucanases displayed highly diverse behavior. Cel45A and Cel5H, which possess carbohydrate-binding modules (CBMs), penetrated and digested within the bulk of the films to a far greater extent than Cel9A and Cel5A, which lack CBMs. While both Cel45A and Cel5H were active within the bulk of the films, striking differences were observed. With Cel45A, substantial film expansion and interfacial broadening were observed, whereas for Cel5H the film thickness decreased with little interfacial broadening. These results are consistent with Cel45A digesting within the interior of cellulose chains as a classic endoglucanase, and Cel5H digesting predominantly at chain ends consistent with its designation as a processive endoglucanase.     

Differential Evolution algorithm with Separated Groups for multi-dimensional optimization problems

The classical Differential Evolution (DE) algorithm, one of population-based Evolutionary Computation methods, proved to be a successful approach for relatively simple problems, but does not perform well for difficult multi-dimensional non-convex functions. A number of significant modifications of DE have been proposed in recent years, including very few approaches referring to the idea of distributed Evolutionary Algorithms. The present paper presents a new algorithm to improve optimization performance, namely DE with Separated Groups (DE-SG), which distributes population into small groups, defines rules of exchange of information and individuals between the groups and uses two different strategies to keep balance between exploration and exploitation capabilities. The performance of DE-SG is compared to that of eight algorithms belonging to the class of Evolutionary Strategies (Covariance Matrix Adaptation ES), Particle Swarm Optimization (Comprehensive Learning PSO and Efficient Population Utilization Strategy PSO), Differential Evolution (Distributed DE with explorative-exploitative population families, Self-adaptive DE, DE with global and local neighbours and Grouping Differential Evolution) and multi-algorithms (AMALGAM). The comparison is carried out for a set of 10-, 30- and 50-dimensional rotated test problems of varying difficulty, including 10- and 30-dimensional composition functions from CEC2005. Although slow for simple functions, the proposed DE-SG algorithm achieves a great success rate for more difficult 30- and 50-dimensional problems.