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881.
Ioana Varduca Enache Lucia Mutihac Amel Ben Othman Jacques Vicens 《Journal of inclusion phenomena and macrocyclic chemistry》2011,71(3-4):537-543
The native and methyl ester amino acids have been extracted by calix[4]azacrowns 1 (1,3-[ethylene-bis-aminocarbonylmethoxy)]-p-tert-butylcalix[4]arene) and 2 (1,3-[propylene-bis-aminocarbonylmethoxy)]-p-tert-butyl-calix[4]arene) from an aqueous phase into a chloroform phase and transported through a chloroform liquid membrane as ion pairs in the presence of picrate or tropaeolin 00 as counter ions aiming their separation. The amino acids under study exhibited good extractability by calix[4]azacrowns 1 and 2. Both receptors 1 and 2 showed good extractability towards amino acids under study. The results are discussed in term of correlation of structural properties of amino acids and calix[4]azacrowns involved in experiments. In this respect, the influence of chain length of receptors upon extraction and transport of amino acids, and the nature of anions used as counter ions are evaluated. 相似文献
882.
Mourad Hidouri Alain Wattiaux Léopold Fournés Jacques Darriet Mongi B. Amara 《Comptes Rendus Chimie》2011,14(10):904-910
Na2Mn2(1 − x)Cd2xFe(PO4)3 (0 ≤ x ≤ 1) phosphates were prepared by solid state reaction and characterized by powder X-ray diffraction, magnetic susceptibility and Mössbauer spectroscopy. The X-ray diffraction patterns indicated the formation of a continuous solid solution which crystallizes in the alluaudite structural type characterized by the general formula X(2)X(1)M(1)M(2)2(PO4)3. The cation distribution, deduced from a structure refinement of the x = 0, 0.5 and 1 compositions, is ordered in the X(2) sites and disordered in the remaining X(1), M(1) and M(2) sites. The magnetic susceptibility study revealed an antiferromagnetic behaviour of the studied compounds. The 57Fe Mössbauer spectroscopy confirmed the structural results and proved the exclusive presence of Fe3+ ions. 相似文献
883.
Elastic and quasielastic neutron scattering experiments have been used to investigate the hydrogen bonding network dynamics of hydration water on hydrophilic and hydrophobic sites. To this end the evolution of hydration water dynamics of a prototypical hydrophobic amino acid with polar backbone, N-acetyl-leucine-methylamide (NALMA), and hydrophilic amino acid, N-acetyl-glycine-methylamide (NAGMA), has been investigated as a function of the molecular ratio water : peptide. The results suggest that the dynamical contribution of the intrinsic and low hydration molecules of water is characteristic of pure librational/rotational movement. The water molecule remains attached to the hydrophilic site with only the possibility of hindered rotations that eventually break the bond with the peptide and reform it immediately after. A gradual evolution from librational motions to hindered rotations is observed as a function of temperature. When the hydration increases, we observe (together with the hindered rotations of hydrogen bonds) a slow diffusion of water molecules on the surface of the peptides. 相似文献
884.
Martin G Mansion F Houbart V Paquet P Rorive A Chiap P Crommen J Servais AC Fillet M 《Talanta》2011,84(2):280-286
The incidence of malignant melanona has increased over the past decades, particularly in Caucasian population. This disease presents defavourable prognosis in terms of survey, especially when detection occurs at the metastatic phase. Reliable analytical methods for biomarker determination are thus an interesting tool in pathology detection and follow-up. In this context, a method using SPE-LC-ESI-MS-MS for the determination of 5-S-cysteinyldopa (5-SCD) in human plasma was optimized. The presence of matrix effect was investigated in details while 5-SCD stability was studied according to FDA requirements for the validation of bioanalytical methods. Pre-study and in-study validations of the entire method were then successfully performed by applying the approach based on total measurement error and accuracy profiles over a concentration ranges from 1.6 to 200 ng/ml. Good results with respect to accuracy, trueness and precision were obtained. The maximum risk of observing future measurements falling outside the acceptance limits during routine analysis was also estimated. 相似文献
885.
Density functional theory is used to carry out a systematic study of zero-temperature structural and energy properties of endohedrally confined hydrogen clusters as a function of pressure and the cluster size. At low pressures, the most stable structural forms of (H(2))(n) possess rotational symmetry that changes from C(4) through C(5) to C(6) as the cluster grows in size from n=8 through n=12 to n=15. The equilibrium configurational energy of the clusters increases with an increase of the pressure. The rate of this increase, however, as gauged on the per atom basis is different for different clusters sizes. As a consequence, the size dependencies of the configurational energies per atom at different fixed values of pressure are nonmonotonic functions. At high pressures, the molecular (H(2))(n) clusters gradually become atomic or dominantly atomic. The pressure-induced changes in the HOMO-LUMO gap of the clusters indicate a finite-size analog of the pressure-driven metallization of the bulk hydrogen. The ionization potentials of the clusters decrease with the increase of pressure on them. 相似文献
886.
887.
Kiss A Jacquet AL Paisse O Flament-Waton MM de Ceaurriz J Bordes C Gauvrit JY Lantéri P Cren-Olivé C 《Talanta》2011,83(5):155-1773
A metabonomic strategy based on LC-MS was employed to investigate the metabolic profile of urine samples from 20 athletes who had been tested positive for corticoids and anabolic steroids and 29 controls. In this aim, different sample preparations and chromatographic conditions were compared. The acquired LC-MS data of doped athletes and controls were subjected to analysis of variance (ANOVA) and principal component analysis (PCA). Using this approach, molecular signature of human urine was obtained showing that metabonomics could be a complementary tool to discriminate different urinary profiles and to track down metabolic changes in humans. 相似文献
888.
Didier Arl Frédéric Aubriet Jean‐Jacques Gaumet 《Journal of mass spectrometry : JMS》2009,44(5):763-771
[M4(SC6H5)10][(CH3)N]2, [M10L4(SC6H5)16][(CH3)N]4 and [Cd17S4(SC6H5)28][(CH3)N]2(M = Cd or Zn, and L = S or Se) zinc and cadmium thiophenolates have been studied by electrospray ionization (ESI) Fourier transform ion cyclotron resonance (FTICR) mass spectrometry (ESI‐FTICRMS) and tandem ESI‐FTICRMS (ESI‐FTICRMSn). ESI‐FTICRMS demonstrated its ability to characterize and study such compounds, which may be used as precursors of II–VI nanomaterials. The obtained mass spectrum has been found to be highly relevant of the investigated thiophenolate and the fragmentation behavior of some of the detected ions is indicative of its stability. More specifically, it has been demonstrated that ESI in‐source activation or fragmentation experiments conducted in the Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS) cell induced the formation of a very stable entity, which corresponds to the general formula M4L4 (M = Zn or Cd and L = S or Se). The elimination of SC6H5? and/or M(SC6H5)2 moieties by various activation processes from the studied thiophenolates led systematically to this structure. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
889.
Sigolène Canaguier Loredana Vaccaro Dr. Vincent Artero Dr. Rainer Ostermann Jacques Pécaut Dr. Martin J. Field Dr. Marc Fontecave Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(37):9350-9364
The new dinuclear nickel–ruthenium complexes [Ni(xbsms)RuCp(L)][PF6] (H2xbsms=1,2‐bis(4‐mercapto‐3,3‐dimethyl‐2‐thiabutyl)benzene; Cp?=cyclopentadienyl; L=DMSO, CO, PPh3, and PCy3) are reported and are bioinspired mimics of NiFe hydrogenases. These compounds were characterized by X‐ray diffraction techniques and display novel structural motifs. Interestingly, [Ni(xbsms)RuCpCO][PF6] is stereochemically nonrigid in solution and an isomerization mechanism was derived with the help of density functional theory (DFT) calculations. Because of an increased electron density on the metal centers [Eur. J. Inorg. Chem. 2007 , 18 , 2613–2626] with respect to the previously described [Ni(xbsms)Ru(CO)2Cl2] and [Ni(xbsms)Ru(p‐cymene)Cl]+ complexes, [Ni(xbsms)RuCp(dmso)][PF6] catalyzes hydrogen evolution from Et3NH+ in DMF with an overpotential reduced by 180 mV and thus represents the most efficient NiFe hydrogenase functional mimic. DFT calculations were carried out with several methods to investigate the catalytic cycle and, coupled with electrochemical measurements, allowed a mechanism to be proposed. A terminal or bridging hydride derivative was identified as the active intermediate, with the structure of the bridging form similar to that of the Ni? C active state of NiFe hydrogenases. 相似文献
890.
Eugen S. Andreiadis Dr. Renaud Demadrille Dr. Daniel Imbert Dr. Jacques Pécaut Dr. Marinella Mazzanti Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(37):9458-9476
A series of seven new tetrazole‐based ligands (L1, L3–L8) containing terpyridine or bipyridine chromophores suited to the formation of luminescent complexes of lanthanides have been synthesized. All ligands were prepared from the respective carbonitriles by thermal cycloaddition of sodium azide. The crystal structures of the homoleptic terpyridine–tetrazolate complexes [Ln(Li)2]NHEt3 (Ln=Nd, Eu, Tb for i=1, 2; Ln=Eu for i=3, 4) and of the monoaquo bypyridine–tetrazolate complex [Eu(H2O)(L7)2]NHEt3 were determined. The tetradentate bipyridine–tetrazolate ligand forms nonhelical complexes that can contain a water molecule coordinated to the metal. Conversely, the pentadentate terpyridine–tetrazolate ligands wrap around the metal, thereby preventing solvent coordination and forming chiral double‐helical complexes similarly to the analogue terpyridine–carboxylate. Proton NMR spectroscopy studies show that the solid‐state structures of these complexes are retained in solution and indicate the kinetic stability of the hydrophobic complexes of terpyridine–tetrazolates. UV spectroscopy results suggest that terpyridine–tetrazolate complexes have a similar stability to their carboxylate analogues, which is sufficient for their isolation in aerobic conditions. The replacement of the carboxylate group with tetrazolate extends the absorption window of the corresponding terpyridine‐ (≈20 nm) and bipyridine‐based (25 nm) complexes towards the visible region (up to 440 nm). Moreover, the substitution of the terpyridine–tetrazolate system with different groups in the ligand series L3–L6 has a very important effect on both absorption spectra and luminescence efficiency of their lanthanide complexes. The tetrazole‐based ligands L1 and L3–L8 sensitize efficiently the luminescent emission of lanthanide ions in the visible and near‐IR regions with quantum yields ranging from 5 to 53 % for EuIII complexes, 6 to 35 % for TbIII complexes, and 0.1 to 0.3 % for NdIII complexes, which is among the highest reported for a neodymium complex. The luminescence efficiency could be related to the energy of the ligand triplet states, which are strongly correlated to the ligand structures. 相似文献