首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   487074篇
  免费   4972篇
  国内免费   1656篇
化学   265165篇
晶体学   7148篇
力学   20111篇
综合类   12篇
数学   57062篇
物理学   144204篇
  2020年   3744篇
  2019年   4024篇
  2018年   4952篇
  2017年   4765篇
  2016年   7675篇
  2015年   5260篇
  2014年   7747篇
  2013年   21694篇
  2012年   16281篇
  2011年   20065篇
  2010年   13404篇
  2009年   13267篇
  2008年   18765篇
  2007年   19071篇
  2006年   18106篇
  2005年   16418篇
  2004年   14755篇
  2003年   13252篇
  2002年   13027篇
  2001年   14393篇
  2000年   11171篇
  1999年   8684篇
  1998年   7230篇
  1997年   7105篇
  1996年   6953篇
  1995年   6162篇
  1994年   5996篇
  1993年   5845篇
  1992年   6382篇
  1991年   6336篇
  1990年   6019篇
  1989年   5786篇
  1988年   6012篇
  1987年   5703篇
  1986年   5459篇
  1985年   7619篇
  1984年   7828篇
  1983年   6380篇
  1982年   6937篇
  1981年   6882篇
  1980年   6504篇
  1979年   6772篇
  1978年   6898篇
  1977年   6876篇
  1976年   6848篇
  1975年   6590篇
  1974年   6461篇
  1973年   6750篇
  1972年   4136篇
  1971年   3332篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
21.
22.
A three-dimensional examination of blood vessels is provided using MR data from seven cases. The vascular surfaces are constructed with an algorithm that automatically follows the selected artery or vein and generates a projected three-dimensional gradient shaded image. Fast 3DFT pulse sequences were optimized to enhance the time-of-flight contrast of the intravascular region. By increasing the surface threshold value in a three-dimensional head study, the flesh of a patient's face was peeled away to demonstrate the superfacial temporal artery. Gated cardiac images show the great vessels and cardiac chambers. A three-dimensional view of the aorta shows an irregular surface in the vicinity of an adrenal tumor. 3D MR exams provide a non-invasive technique for assessing vascular morphology in a clinical setting.  相似文献   
23.
    
The diversity of products in the reaction of diethyl azodicarboxylate (DEAD)/diisopropyl azodicarboxylate (DIAD) and activated acetylenes with PIII compounds bearing oxygen or nitrogen substituents is discussed. New findings that are useful in understanding the nature of intermediates involved in the Mitsunobu reaction are highlighted. X-ray structures of two new compounds (2-t-Bu-4-MeC6H3O)P (μ-N-t-Bu)2P+[(NH-t-Bu)N[(CO2]-i-Pr)(HNCO2-i-Pr)]](Cl-)(2-t-Bu-4-MeC6H3OH)(23)and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)C(CO2Me)C-(CO2Me)CClNC(O)Cl] (33) are also reported. The structure of23 is close to one of the intermediates proposed in the Mitsunobu reaction.  相似文献   
24.
Summary The adsorption of gaseous molecular iodine on clean silver surfaces proceeds in the first stage by dissociative chemisorption. After the formation of half a monolayer of chemisorbed iodine atoms the formation of silver iodide begins, which forms a very regular overlayer on top of the substrate. Both iodine species can be distinguished due to a difference in chemical shift of the M4N4, 5N4, 5-Auger transitions. After completion of this overlayer further iodine uptake is slowed down significantly. Above an overlayer thickness of about 10 nm a further progress of the reaction cannot be followed anymore due to the limited information depth of XPS.  相似文献   
25.
26.
27.
The development of the poly(3‐hydroxybutyrate) (PHB) morphology in the presence of already existent poly(vinylidene fluoride) (PVDF) spherulites was studied by two‐stage solidification with two separate crystallization temperatures. PVDF formed irregular dendrites at lower temperatures and regular, banded spherulites at elevated temperatures. The transition temperature of the spherulitic morphology from dendrites to regular, banded spherulites increased with increasing PVDF content. A remarkable amount of PHB was included in the PVDF dendrites, whereas PHB was rejected into the remaining melt from the banded spherulites. When PVDF crystallized as banded spherulites, PHB could consequently crystallize only around them, if at all. In contrast, PHB crystallized with a common growth front, starting from a defined site in the interfibrillar regions of volume‐filling PVDF dendrites. It formed by itself dendritic spherulites that included a large number of PVDF spherulites. For blends with a PHB content of more than 80 wt %, for which the PVDF dendrites were not volume‐filling, PHB first formed regular spherulites. Their growth started from outside the PVDF dendrites but could later interpenetrate them, and this made their own morphology dendritic. These PHB spherulites melted stepwise because the lamellae inside the PVDF dendrites melted at a lower temperature than those from outside. This reflected the regularity of the two fractions of the lamellae because that of those inside the dendrites of PVDF was controlled by the intraspherulitic order of PVDF, whereas that from outside was only controlled by the temperature and the melt composition. The described morphologies developed without mutual nucleating efficiency of the components. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 873–882, 2003  相似文献   
28.
A one-dimensional bulk reaction model for the oxidation of nickeltitanium is formulated, with preferential oxidation of titaniumbeing included. The modelling is directed at the better understandingof the dominant mechanisms involved in the oxidation processand their significance for the biocompatibility of the alloy.Two different regimes for the relative diffusivities of oxygenand the metals are investigated. By assuming fast bulk reactions,different asymptotic structures emerge in different parameterregimes and the resulting models take the form of moving boundaryproblems. Different profiles of nickel concentration are obtained:in particular a nickel-rich layer (observed in practice) ispresent below the oxide/metal interface for the case when oxygenand the metals diffuse at comparable rates.  相似文献   
29.
Microwave nonresonant dissipation observed around zero field makes a powerful method in characterizing superconducting state (to determineT C,H C1,H CJ parameters). This review shows several successful applications of magnetically modulated microwave absorption (MMMA). MMMA enables to study MgB2 superconducting nanoregions embedded in the Mg host structure. Application of MMMA to study intercalation of fullerence enabled the observation of a new superconducting phase. The pressure effect dT C/dp has been studied below the percolation threshold in YBaCuO/PST composites. The local temperature of the Josephson junction measured by the MMMA technique showed that a granular superconductor consists of two phases: host phase and Josephson junction system. MMMA has been applied lately to separate the giant magnetoresistance from the magnetization effect in differential hysteresis loops.  相似文献   
30.
We show that if G is a definably compact, definably connected definable group defined in an arbitrary o‐minimal structure, then G is divisible. Furthermore, if G is defined in an o‐minimal expansion of a field, k ∈ ? and pk : GG is the definable map given by pk (x ) = xk for all xG , then we have |(pk )–1(x )| ≥ kr for all xG , where r > 0 is the maximal dimension of abelian definable subgroups of G . (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号