Liquid-like structure of vapour quenched SnAu- and SnCu-films

SnAu- and SnCu-alloys are vapour quenched at cryogenic temperatures. Resistivity and electron diffraction patterns were recorded in situ. The scattered intensities have been normalized to interference functions. The overall agreement with those of the corresponding liquid systems is quite well. The average interatomic distances obtained from the atomic distribution functions show a concentration dependence which corresponds closely to that found in liquid SnAu and SnCu respectively. This gives evidence to the statement that the nearest neighbour organisations of the films are very similar to those of the corresponding liquids. Furthermore it turned out that the local structures in the Sn-rich SnAu-system are substantial different from those in the Sn-rich SnCu-system, except in the vicinity of a minimum amount of noble metals (8–10 at.%), which is necessary to stabilize the amorphous state.     

Continuous time collocation methods for Volterra-Fredholm integral equations

Summary Integral equations of mixed Volterra-Fredholm type arise in various physical and biological problems. In the present paper we study continuous time collocation, time discretization and their global and discrete convergence properties.     

Observation of hydrogen induced intermediate borides in PrFeB based alloys by Mössbauer effect spectroscopy

In the present work, a quantitative analysis of the phase compositions by Mössbauer effect spectroscopy of solid and conventional hydrogen disproportionated Pr_13.7Fe_80.3B_6.0 and Pr_13.7Fe_63.5Co_16.7Zr_0.1B_6.0 alloys was carried out. Significant amounts of intermediate borides t-Fe₃B and Pr(Fe, Co)₁₂B₆ were detected after solid hydrogen disproportionation treatment in Pr_13.7Fe_80.3B_6.0 and Pr_13.7Fe_63.5Co_16.7Zr_0.1B_6.0 alloys, respectively. After conventional hydrogenation–disproportionation–desorption–recombination treatment these phases were not detected and in no case residual Pr₂Fe₁₄B-phase was found. It was observed that the amount of intermediate borides after disproportionation can be correlated with the degree of texture after recombination at various temperatures.     

Detailed Description of Mixed Symmetry States in 94Mo Using Interacting Boson Model

We have investigated the low-lying collective states and electromagnetic transitions in 94Mo within the framework of the interacting boson model. The influence of model parameters on the energy levels and electromagnetic properties has been investigated. The analysis of the obtained results and the parameter values predict that the 23+state is the lowest mixed symmetry state with pure F = Fmax - 1 in this nucleus. The calculated results predicate that the 25+ (two-Q-phonon) mixed symmetry state is closed to the J = 2+ at 2.870 MeV in the experimental data, and the 2.965 MeV state is the lowest mixed symmetry with J = 3+.     

The role of water vapour on the oxidation of two Ln-Si-Al-O-N glasses (Ln=Y, La)

The oxidation behaviour of LnSiAlON (Ln=Y, La) glasses was studied at different temperatures (990-1150 °C) and under different water vapour pressures (360-2690 Pa). These results were also compared with those obtained under O₂, N₂/H₂O or O₂/H₂O mixtures. When glasses are treated under a N₂/H₂O mixture, optical and SEM observations show porous scales. Transformations of the reaction rate data and a kinetic model show that there is only one limiting process occurring during oxidation. This rate limiting step is the progress of the chemical reaction at the internal interface. Determination of the pressure law dependence and thermodynamics calculations of water vapour molecules dissociation at the investigated temperatures allow us to suggest that the mechanism of oxidation corresponds to decomposition of water molecules on the oxynitride glass surface.     

Design and Experimental Characterization of Low‐Volume PM10/2.5/1.0 Trichotomous Sampler Inlet

This paper presents the development and laboratory evaluation of a PM10/2.5/1.0 trichotomous sampling inlet that consists of two main parts: a previously designed PM10 size‐selective inlet part and a PM2.5/1.0 two‐stage virtual impactor, which was newly fabricated and attached serially to the PM10 size selective inlet part. Particles are collected in three locations through the trichotomous sampling inlet to provide for not only particle concentration measurements of PM10, PM2.5 and PM1.0, but also those of PM2.5–10 and PM1.0–2.5.     

Improved bounds for sampling contingency tables

We study the problem of sampling contingency tables (nonnegative integer matrices with specified row and column sums) uniformly at random. We give an algorithm which runs in polynomial time provided that the row sums r_i and the column sums c_j satisfy r_i = Ω(n^3/2m log m), and c_j = Ω(m^3/2n log n). This algorithm is based on a reduction to continuous sampling from a convex set. The same approach was taken by Dyer, Kannan, and Mount in previous work. However, the algorithm we present is simpler and has weaker requirements on the row and column sums. © 2002 Wiley Periodicals, Inc. Random Struct. Alg., 21: 135–146, 2002