首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   555957篇
  免费   5379篇
  国内免费   1435篇
化学   291553篇
晶体学   8206篇
力学   26120篇
综合类   20篇
数学   66984篇
物理学   169888篇
  2021年   4878篇
  2020年   5324篇
  2019年   5950篇
  2018年   7963篇
  2017年   7969篇
  2016年   11436篇
  2015年   6714篇
  2014年   10846篇
  2013年   24876篇
  2012年   19220篇
  2011年   23469篇
  2010年   17114篇
  2009年   17109篇
  2008年   21788篇
  2007年   21615篇
  2006年   19932篇
  2005年   17796篇
  2004年   16600篇
  2003年   14737篇
  2002年   14741篇
  2001年   16652篇
  2000年   12545篇
  1999年   9831篇
  1998年   8311篇
  1997年   7954篇
  1996年   7630篇
  1995年   6903篇
  1994年   6820篇
  1993年   6651篇
  1992年   7215篇
  1991年   7555篇
  1990年   7208篇
  1989年   7088篇
  1988年   6987篇
  1987年   6876篇
  1986年   6528篇
  1985年   8422篇
  1984年   8504篇
  1983年   6874篇
  1982年   7036篇
  1981年   6924篇
  1980年   6411篇
  1979年   7008篇
  1978年   7238篇
  1977年   7231篇
  1976年   7247篇
  1975年   6676篇
  1974年   6642篇
  1973年   6771篇
  1972年   4942篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
101.
The Liouville operator for an infinite-particle Hamiltonian dynamics corresponding to interaction potentialU is used to introduce the concept of a locally weakly invariant measure on the phase space and to show that if a Gibbs measure with potential of general form is locally weakly invariant then its Hamiltonian is asymptotically an additive integral of the motion of the particles with the interactionU.Moscow State University. Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 90, No. 3, pp. 424–459, March, 1992.  相似文献   
102.
TheSU(2) rotation matricesD (j), specified in terms of axis and angle of rotation, are expressed as linear combination of normalized irreducible tensorial matricces (NITM) of rankl = 0 to 2j rotated to the polar angles of the axis. The rotated NITM are constructed from spherical harmonics of the same rank. Since this formulation requires no matrix products, it may be computationally more efficient than Euler angle formulas, particularly for largej. Rotated NITM and formulas for theD (j) withj = 1/2 andj = 1 are written out explicitly. A formula for the structure constants of the products of conformable NITM is also given in terms of 3-j and 6-j symbols.  相似文献   
103.
We examine the influence of relativistic and QED effects on the existence of the 1,3P o H- resonances between n = 2 and 3 hydrogen thresholds, the relativistic and QED corrections and the coupling effects between the high singlet and triplet states are considered as first-order perturbations. We firstly obtain accurate non-relativistic resonant energies and widths of fifteen 1P o resonances, and fifteen 3P o resonances. The fifteen 1P o resonances are classified to be 3 (2, 0) - n ( 4 ? n ? 12) and 3 (1, 1) + n ( 3 ? n ? 8). The fifteen 3P o resonances are classified to be 3 (2, 0) + n ( 3 ? n ? 12) and 3 (1, 1) - n ( 4 ? n ? 8). We found there exist six Feshbach resonances for 3 (2, 0) - n (1P o ) series, four Feshbach resonances for 3 (1, 1) + n (1P o ) series, seven Feshbach resonances for 3 (2, 0) + n (3P o ) series, and three Feshbach resonances for 3 (1, 1) - n (1P o ) series. Received 22 February 2002 Published online 24 September 2002  相似文献   
104.
    
AAS as a highly sensitive and specific single element technique is ideally suited as a detector for speciation analysis. The combinations of chromatographic separation with element specific detectors (flame AAS, electrothermal AAS (ETAAS), hydride generation AAS (HGAAS)) provide powerful approaches to the determination of all species. Sample stabilisation is the area that requires most attention as it still represents the main source of problems encountered in speciation work. The correct speciation depends on how the sample is handled prior to analysis. Unfortunately, no universal procedure has been found. Anything that changes redox conditions, pH or complexation equilibrium is clearly unacceptable.  相似文献   
105.
This work is devoted to the numerical solution of the Navier–Stokes equations for compressible viscous fluids. Finite element approximations and stabilization techniques are addressed. We present methods to implement discontinuous approximations for the pressure and the density. An upwinding methodology is being investigated which combines the ideas behind the stream line Petrov–Galerkin method and the flux limiter methods aiming to introduce numerical diffusion only where it is necessary.  相似文献   
106.
The interaction between trivalent lanthanide ions and poly(1,4,7,10,13‐pentaoxacyclopentadecan‐2‐yl‐methyl methacrylate), PCR5, in aqueous solution and in the solid state have been studied. In aqueous solution, evidence of a weak interaction between the lanthanides and PCR5 comes from the small red shift of the Ce(III) emission spectra and the slight broadening of the Gd(III) EPR spectra. From the Tb(III) lifetimes in the presence of H2O and D2O the loss of one or two water coordinated molecules is confirmed when Tb(III) is bound to PCR5. An association constant of the order of 200 M?1 was obtained for a 1:1 (lanthanide:15‐crown‐5) complex from the shift of the polymer NMR signals induced by Tb(III). A similar association constant is obtained from the differences of the molar conductivity of Ce(III) solution at various concentrations in presence and absence of PCR5. When Tb(III) is adsorbed on PCR5 membranes, lifetime experiments in H2O and D2O confirm the loss of 5 or 6 water coordinated molecules indicating that in solid state the lanthanide(III)‐PCR5 interaction is stronger than in solution. The adsorption of Ce(III) in PCR5 membranes shows a Langmuir type isotherm, from which an equilibrium constant of 39 M?1 has been calculated. SEM shows that the membrane morphology is not much affected by lanthanide adsorption. Support for lanthanide ion–crown interactions comes from ab initio calculations on 15‐crown‐5/La(III) complex. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1788–1799, 2007  相似文献   
107.
108.
We investigate the existence and stability of solutions for higher-order two-point boundary value problems in case the differential operator is not necessarily positive definite, i.e. with superlinear nonlinearities. We write an abstract realization of the Dirichlet problem and provide abstract existence and stability results which are further applied to concrete problems.  相似文献   
109.
We show how methods for estimating the concentration function of the sum of independent random variables can be used to obtain estimates of the concentration function for the values of additive functions under suitable conditions. Previously obtained estimates of the concentration function are consequences of the estimate obtained in the present paper for functions from of the class under consideration.  相似文献   
110.
Analysis of stochastic processes governed by the Langevin equation is discussed. The analysis is based on a general method for non-parametric estimation of deterministic and random terms of the Langevin equation directly from given data. Separate estimation of the terms corresponds to the decomposition of process dynamics into deterministic and random components. Part I of the paper presented several possibilities for qualitative and quantitative analysis of process dynamics based on such decomposition. In Part II, some of these analysis possibilities are applied to experimental datasets from metal cutting and laser-beam welding.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号