Prognostication of aging of polymeric composite materials

Experimental data demonstrate that a study of accelerated aging can enable prognostication of the working capacity and storage life of polymeric formulations used in aircraft components on the basis of changes in thermogravimetric constants of these polymeric formulations.     

Fundamental aspects of initiated oxidation of tridecane and polyethylene in solutions

Specific features of the initiated oxidation of polyethylene and its low-molecular-weight analogue tridecane, associated with the occurrence of the process in the short-chain mode, were studied.     

Thermodynamic properties of ternary systems: Calculation of standard enthalpies of solvation of triols, diols, and a series of their ethers in water-methanol mixed solvent

An equation for the standard enthalpy of solvation of a compound in a binary solvent is derived. The enthalpies of solvation in water-methanol mixtures are estimated for 1,3-propane-and 1,6-hexanediols, 1,2,4-butane-and 1,3,5-pentanetriols, 2-methoxy-and 2-propoxyethanols, and diethylene glycol. The enthalpy of solvation of 1,2-dimethoxyethane in the water-methanol mixed solvent is determined experimentally.     

Influence of the counterion size on swelling and collapse of polyelectrolyte gel

A theory that predicts the effect of the counterion size on the swelling and collapse of a weakly charged polyelectrolyte gel was developed. In addition to excluded-volume interactions between monomer units of the gel, the theory involves the counterion-monomer unit and counterion-counterion interactions in terms of the virial approximation. The character of interactions between different units in the system varies from repulsion to attraction depending on the type of solvent, counterion, and dielectric permittivity of the solvent. For solvents with a low permittivity, the effect of condensation of counterions resulting in the formation of ion pairs is taken into account.     

Coagulation in lipid- and protein-containing systems

The behavior of real disperse systems with organic impurities was examined under conditions of destabilization by inorganic coagulants. A number of physicochemical methods of analysis and a simulation method were used to identify the character and type of the complexes formed and to calculate their stability constants.