煤颗粒热解的传热传质分析

采用分布活化能模型及能量守恒方程对煤颗粒热解的传热传质过程建立数学模型,模型考虑煤热解的吸热效应及挥发分逸出时对流换热的影响.与有关煤粉和大颗粒煤热解的实验数据对比,对模型进行验证.针对煤颗粒的温度变化过程和煤热解过程进行数值分析,研究煤热解的吸热效应、挥发分气体逸出的对流效应、颗粒尺寸等参数的影响.     

New application of human eye model in the verification of spot diagram with refractive diopter

In response to the rapid advancement of auto-refractor technology, most optometry shops provide refraction services. Despite their speed and convenience, the measurement values provided by auto-refractors include a significant degree of error due to psychological and physical factors. Therefore, there is a need for repetitive testing to obtain a smaller mean error value. However, even repetitive testing itself might not be sufficient to ensure accurate measurements. Therefore, research on a method of measurement that can complement auto-refractor measurements and provide confirmation of refraction results needs to be conducted. The customized optometry model described herein can satisfy the above requirements. From the existing optical technologies, using human eye measurement devices to obtain individual relevant optical feature parameters is no longer difficult. These parameters allow us to construct an optometry model for individual eyeballs. They also allow us to compute spot diagrams produced from the optometry model using the CODE V macro programming language before recognizing the geometrical spot diagram with the back-propagation neural network algorithm to obtain the accurate refractive diopter. Results show that the accuracy achieved was above 98% and that this application could significantly enhance the service quality of refraction.     

Dimer Coverings on the Sierpinski Gasket

We present the number of dimer coverings N _d (n) on the Sierpinski gasket SG _d (n) at stage n with dimension d equal to two, three, four or five. When the number of vertices, denoted as v(n), of the Sierpinski gasket is an even number, N _d (n) is the number of close-packed dimers. When the number of vertices is an odd number, no close-packed configurations are possible and we allow one of the outmost vertices uncovered. The entropy of absorption of diatomic molecules per site, defined as , is calculated to be ln (2)/3 exactly for SG ₂. The numbers of dimers on the generalized Sierpinski gasket SG _d,b (n) with d=2 and b=3,4,5 are also obtained exactly with entropies equal to ln (6)/7, ln (28)/12, ln (200)/18, respectively. The number of dimer coverings for SG ₃ is given by an exact product expression, such that its entropy is given by an exact summation expression. The upper and lower bounds for the entropy are derived in terms of the results at a certain stage for SG _d (n) with d=3,4,5. As the difference between these bounds converges quickly to zero as the calculated stage increases, the numerical value of with d=3,4,5 can be evaluated with more than a hundred significant figures accurate. This paper is written during the Lung-Chi Chen visit to PIMS, University of British Columbia. The author thanks the institute for the hospitality.     

Facile controlled synthesis of micro/nanostructure MCrO4 (M = Ba, Pb) by using Gemini surfactant C12-PEG-C12 as a soft template

Gemini surfactants, double sodium α-sulfonic polyethylene glycol laurate (abbreviated C₁₂-PEG-C₁₂), were prepared and applied as soft templates in the controlled synthesis of BaCrO₄ and PbCrO₄ micro/nanocrystals. The template effects were investigated by adjusting the length of the spacer, using PEG400 and PEG4000, of the Gemini surfactant. The results indicated that the size and morphology of BaCrO₄ and PbCrO₄ micro/nanocrystals varied with the change in spacer length of C₁₂-PEG-C₁₂, suggesting that the different lengths of the polyethylene glycol group spacers in the Gemini surfactants played a key role in determining the size and shape of the MCrO₄ micro/nanoparticles. The dynamic process of the formation of the novel morphology BaCrO₄ crystals showed that the morphology grew from a round-bar polyhedron, to regular polyhedron, to approximate octahedron to a uniform pistachio nut shape. The growth mechanism of the BaCrO₄ micro/nanocrystals was explained that C₁₂-PEG-C₁₂ had a greater interfacial adsorption and would effectively control the shape evolution during the crystal growth, while PbCrO₄ could be explained that the Gemini surfactants can undergo liquid-crystalline phase transitions with long channels providing a soft template effect and derived the nanorods formation. Room temperature fluorescence spectra were studied and these showed that the pistachio-shaped BaCrO₄ microcrystals and PbCrO₄ nanorods possess photoactive luminescence properties with emission peaks at 470 and 549 nm, respectively.     

反射面形状对光纤位移传感器光强调制特性的影响

为了分析反射面形状对单模光纤照射的光纤位移传感器光强调制特性的影响,建立了反射面不为平面时的光强调制特性函数模型.该模型基于单模光纤出射光场为修正近似高斯分布假设,通过引入反射面形状因子,分析了反射面形状因子对光强调制特性的影响规律.仿真结果表明,随着凹形反射面曲率半径值的增大,传感器特性曲线的前坡无显著变化,而后坡灵敏度增大,线性范围减小;随着凸形反射面曲率半径值的增大,传感器特性曲线的前坡仍无显著变化,而后坡灵敏度减小,线性范围增大;当曲率半径增大的一定值时,反射面的非平面性影响较小,其作用趋近于平面.     

First measurement of inclusive B→Xsη decays

We report a first measurement of inclusive B→Xsη decays, where Xs is a charmless state with unit strangeness. The measurement is based on a pseudoinclusive reconstruction technique and uses a sample of 657×10(6)BB pairs accumulated with the Belle detector at the KEKB e+e- collider. For MXs < 2.6 GeV/c2, we measure a branching fraction of [26.1±3.0(stat)-2.1+1.9(syst)-7.1+4.0(model)]×10(-5) and a direct CP asymmetry of ACP=-0.13±0.04-0.03+0.02. Over half of the signal occurs in the range MXs > 1.8 GeV/c2.     

Anomalies in the Fermi surface and band dispersion of quasi-one-dimensional CuO chains in the high-temperature superconductor YBa2Cu4O8

We have investigated the electronic states in quasi-one-dimensional CuO chains by microprobe angle resolved photoemission spectroscopy. We find that the quasiparticle Fermi surface consists of six disconnected segments, consistent with recent theoretical calculations that predict the formation of narrow, elongated Fermi surface pockets for coupled CuO chains. In addition, we find a strong renormalization effect with a significant kink structure in the band dispersion. The properties of this latter effect [energy scale (～40 meV), temperature dependence, and behavior with Zn-doping] are identical to those of the bosonic mode observed in CuO2 planes of high-temperature superconductors, indicating they have a common origin.     

A plane wave generation method by wave number domain point focusing

A method for generation of a wave-field that is a plane wave is described. This method uses an array of loudspeakers phased so that the field in the wave-number domain is nearly concentrated at a point, this point being at the wave-number vector of the desired plane wave. The method described here for such a wave-number concentration makes use of an expansion in spherical harmonics, and requires a relatively small number of measurement points for a good approximate achievement of a plane wave. The measurement points are on a spherical surface surrounding the array of loudspeakers. The input signals for the individual loudspeakers can be derived without a matrix inversion or without explicit assumptions about the loudspeakers. The mathematical development involves spherical harmonics and three-dimensional Fourier transforms. Some numerical examples are given, with various assumptions concerning the nature of the loudspeakers, that support the premise that the method described in the present paper may be useful in applications.     

The design of a peptide linker group to enhance the SERS signal intensity of an atto680 dye‐nanoparticle system

The Surface enhanced resonance Raman spectroscopy (SERRS) spectra of three modified atto680 dyes were recorded using Au nanoparticles and an excitation laser operating at 670 nm. The dyes were modified with linker groups based on the small peptides, Cys, Cys–Gly and Cys–Gly–Gly. The Cys thiol group acted as the coupling point to the Au surface and the Gly  NH₂ group used to attach the dye. The maximum signal was recorded for the Cys–Gly linker. This gave a signal intensity for the 577 cm⁻¹ Raman peak of the atto680 dye that was more than 27 times greater than the unmodified dye. The Au nanoparticles used had a diameter of 49.8 ± 1.2 nm and were synthesised by the citrate reduction method. The Raman dye‐AuNP probes were also used in an immunoassay to detect mouse IgG in the femto mole range. Copyright © 2010 John Wiley & Sons, Ltd.     

CO_2亚临界压力区物性的快速计算——基于马丁-侯方程的显式快速计算模型

基于马丁-侯方程,提出二氧化碳亚临界压力区具有统一形式的热力性质和传输特性的显式计算模型。显式形式保证了热物理性质计算的高速性和稳定性;同时所有热物性的计算模型形式统一,便于系统仿真的调用。以REFPROP7的计算结果作为数据源,对环保制冷剂中重要的工质二氧化碳的热物性在压力为三相点压力至临界压力,过热度0—200K,过冷度0—100K的数据范围内进行拟合,并将该计算模型与REFPROP7相应公式的计算结果和计算速度进行对比。对比结果表明,所有快速计算模型的总平均偏差小于0.7%,最大偏差小于12.928%;计算速度较REFPROP7提高了2个数量级。。